Method for producing a-IGZO oxide thin film
View Patent ↗There is provided a method for producing an a-IGZO oxide thin film by sputtering, which can control the carrier density of the film to a given value with high reproducibility. The method is an amorphous In—Ga—Zn—O based oxide thin film production method including: providing a sintered oxide material consisting essentially of indium (In), gallium (Ga), zinc (Zn), and oxygen (O) as constituent elements, wherein the ratio [In]/([In]+[Ga]) of the number of indium atoms to the total number of indium and gallium atoms is from 20% to 80%, the ratio [Zn]/([In]+[Ga]+[Zn]) of the number of zinc atoms to the total number of indium, gallium and zinc atoms is from 10% to 50%, and the sintered oxide material has a specific resistance of 1.0×10 −1 Ωcm or less; and producing a film on a substrate by direct current sputtering at a sputtering power density of 2.5 to 5.5 W/cm 2 using the sintered oxide material as a sputtering target.
1. A method for producing an amorphous In—Ga—Zn—O based oxide thin film, comprising:
providing a sintered oxide material consisting essentially of indium (In), gallium (Ga), zinc (Zn), and oxygen (O) as constituent elements, wherein a ratio [In]/([In]+[Ga]) of the number of indium atoms to a total number of indium and gallium atoms is from 20% to 80%, a ratio [Zn]/([In]+[Ga]+[Zn]) of the number of zinc atoms to a total number of indium, gallium and zinc atoms is from 10% to 50%, and the sintered oxide material has a specific resistance of 5.0×10 −3 Ωcm or less; and
producing a film on a substrate by direct current sputtering at a substrate temperature of 25 to 50° C. and a sputtering power density of 2.7 to 6.6 W/cm 2 using the sintered oxide material as a sputtering target.
2. The method according to claim 1 , wherein the sintered oxide material has a relative density of 95% or more.
3. The method according to claim 1 , wherein the sputtering is performed at a deposition rate of 2.5 Å/minute to 5.5 Å/minute.
4. The method according claim 1 , further comprising annealing the resulting film at a temperature of 200 to 400 C.° in an atmosphere containing oxygen at a specific concentration to reduce carrier density, after the film is produced on the substrate by the direct current sputtering.
5. The method according to claim 4 , wherein the concentration of oxygen in the atmosphere is 100% by volume during the annealing.
6. A method for manufacturing a thin film transistor, comprising the step of forming an active layer using the method according to claim 1 .
7. A method for manufacturing an active matrix driving display panel, comprising the step of forming an active device using the method according to claim 6 .
8. A sintered oxide material for use as a sputtering target in the method according to any one of claims 1 to 6 , consisting essentially of indium (In), gallium (Ga), zinc (Zn), and oxygen (O) as constituent elements, wherein a ratio [In]/([In]+[Ga]) of the number of indium atoms to a total number of indium and gallium atoms is from 20% to 80%, and a ratio [Zn]/([In]+[Ga]+[Zn]) of the number of zinc atoms to a total number of indium, gallium and zinc atoms is from 10% to 50%, the sintered oxide material having a specific resistance of 5.0×10 −3 Ωcm or less.
9. The sintered oxide material according to claim 8 , which has a relative density of 95% or more.
10. The method according to claim 1 , wherein the concentration of oxygen in a sputtering gas is from 1 to 3% during the direct current sputtering.