Phase change memory including ovonic threshold switch with layered electrode and methods for forming same
View Patent ↗Erosion of chalcogenides in phase change memories using ovonic threshold switch selectors can be reduced by controlling columnar morphology in electrodes used in the ovonic threshold switch. The columnar morphology may cause cracks to occur which allow etchants used to etch the ovonic threshold switch to sneak through the ovonic threshold switch and to attack chalcogenides, either in the switch or in the memory element. In one embodiment, the electrode may be split into two metal nitride layers separated by an intervening metal layer.
1. A phase change memory comprising:
a phase change memory element including a phase memory material in contact with a first heater having a first cross-sectional area, the first heater adjacent to a second heater having a second cross-sectional area different than the first cross-sectional area such that a ledge is defined between a perimeter of the first heater and a perimeter of the second heater at an interface of the first and second heaters, and wherein the first heater has a third cross-sectional area different than the first and second cross-sectional areas; and
an ovonic threshold switch over the phase change memory element, the ovonic threshold switch including:
a first electrode over the phase memory material;
a chalcogenide layer in contact with the first electrode;
a carbon layer overlaying the chalcogenide layer; and
a second electrode over the carbon layer, the second electrode including at least two metal nitride layers separated by an intervening metal layer.
2. The memory of claim 1 , wherein the at least two metal nitride layers include Titanium Nitride.
3. The memory of claim 2 , wherein the intervening metal layer is formed substantially of the same metal used in the at least two metal nitride layers.
4. The memory of claim 3 , wherein edges of the first electrode, the second electrode, and the chalcogenide layer are aligned.
5. The memory of claim 1 , wherein the intervening metal layer is from 20 to 100 Angstroms thick.
6. The memory of claim 1 , wherein each of the least two metal nitride layers is less than about 350 Angstroms thick.
7. The memory of claim 1 , wherein the phase memory material is a chalcogenide material.
8. The memory of claim 1 , wherein the first electrode includes a plurality of conductive layers separated by an intervening conducive layers of a different material.
9. The memory of claim 1 further comprising an address line below the second heater and wherein the second heater is isolated from the address line using a barrier layer.
10. The memory of claim 1 , wherein the first heater is provided in a first pore and the second heater is provided in a second pore, the first pore comprising a spacer disposed around the first heater.
11. The memory of claim 10 , wherein the spacer includes two different dielectric layers.
12. The memory of claim 1 , wherein the third cross-sectional area of the first heater is the same as a cross-sectional area of the phase memory material at an interface of the first heater and the phase memory material.