Silver particles and a process for making them
View Patent ↗Silver powders containing particles with a different morphology are disclosed. The silver particles are spherically-shaped with an open structure surface. The majority of the spherically-shaped silver particles have one or more silver plates attached to each of the majority of the spherically-shaped silver particles. Also provided is a process for making these silver particles. The silver particles formed are particularly useful in electronic applications.
1. A process for making a silver powder comprising spherically-shaped silver particles, said process comprising:
a. preparing an acidic aqueous silver salt solution comprising a water soluble silver salt dissolved in deionized water;
b. preparing an acidic reducing and surface morphology modifier solution comprising:
i. a reducing agent selected from the group consisting of an ascorbic acid, an ascorbate and mixtures thereof dissolved in deionized water;
ii. nitric acid;
iii. a first surface morphology modifier selected from the group consisting of citric acid, citrate salts and mixtures thereof; and
iv. a second surface morphology modifier selected from the group consisting of water soluble copper compounds that are sources of Cu 2+ ions when dissolved in water;
c. maintaining the acidic aqueous silver salt solution and the acidic reducing and surface morphology modifier solution at the same temperature, wherein that temperature is in the range of about 20° C. to about 65° C., while stirring each solution; and
d. mixing the acidic aqueous silver salt solution and the acidic reducing and surface morphology modifier solution over a period of less than 10 seconds with no stirring to make a reaction mixture, maintaining the reaction mixture at the temperature of (c) and after 3 to 7 minutes stifling the reaction mixture for 2 to 5 minutes to produce the silver powder particles in a final aqueous solution.
2. The process of claim 1 , further comprising:
a. separating said silver powder particles from said final aqueous solution;
b. washing said silver powder particles with deionized water; and
c. drying said silver powder particles.
3. The process of claim 1 , wherein said first surface morphology modifier is sodium citrate.
4. The process of claim 1 , wherein said second surface morphology modifier is copper nitrate.
5. The process of claim 1 , wherein said water soluble silver salt is silver nitrate, said reducing agent is ascorbic acid, said first surface morphology modifier is sodium citrate and said second surface morphology modifier is copper nitrate and wherein the amount of said first surface morphology modifier used ranges from about 0.02 to about 0.25 gram of said first surface morphology modifier per gram of silver and the amount of said second surface morphology modifier used ranges from about 0.0006 to about 0.0024 gram of said second surface modifier per gram of silver.
6. The process of claim 1 , said acidic reducing and surface morphology modifier solution further comprising a dispersing agent selected from the group consisting of ammonium stearate, stearate salts, polyethylene glycol with molecular weight ranging from 200 to 8000, and mixtures thereof.