Calcium sulfate hemihydrate treatment process
A process for treating beta calcium sulfate hemihydrate is disclosed. The process comprises exposing beta calcium sulfate hemihydrate to steam at a pressure above atmospheric pressure.
1. A process for treating beta calcium sulfate hemihydrate comprising:
a. providing powdered beta calcium sulfate hemihydrate to a pressure chamber;
b. within the pressure chamber, exposing the beta calcium sulfate hemihydrate to steam at a pressure above atmospheric pressure; and
c. removing the treated product from the pressure chamber.
2. The process of claim 1 , wherein step b. comprises:
i. providing steam to the pressure chamber to reach the pressure.
3. The process of claim 2 , further comprising:
ii. maintaining the pressure in the pressure chamber above atmospheric for a residence time of at least 5 seconds.
4. The process of claim 3 , further comprising:
iii. releasing the pressure and cooling the beta calcium sulfate hemihydrate to a temperature below 60° C.
5. The process of claim 3 , wherein:
a. the beta calcium sulfate hemihydrate is provided to the pressure chamber at an initial plaster temperature, and the steam is provided to the pressure chamber at an initial steam temperature, and
b. the initial plaster temperature is between 60° C. and 200° C., the initial steam temperature is between 100° C. and 200° C., the pressure is between 0.1 psi g and 210 psi g , and the residence time is between 5 seconds and 900 seconds.
6. The process of claim 3 , wherein:
a. the beta calcium sulfate hemihydrate is provided to the pressure chamber at an initial plaster temperature, the steam is provided to the pressure chamber at an initial steam temperature, the pressure chamber is heated to a chamber temperature, and the steam is heated in the pressure chamber to a final steam temperature higher than the initial temperature, and
b. the chamber temperature is between 115° C. and 200° C., the initial plaster temperature is between 60° C. and 200° C., the initial steam temperature is between 100° C. and 115° C., the final steam temperature is between 115° C. and 200° C., the pressure is between 0.1 psi g and 210 psi g , and the residence time is between 5 seconds and 900 seconds.
7. The process of claim 2 , wherein the steam has a dew point temperature at the pressure, and the steam is provided to the pressure chamber at an initial steam temperature within +/−5° C. of the dew point temperature.
8. The process of claim 2 , wherein the steam has a dew point temperature at the pressure, and the steam is provided to the pressure chamber at an initial steam temperature less than the dew point temperature, and is heated in the pressure chamber to a final steam temperature within +/−5° C. of the dew point temperature.
9. The process of claim 2 , wherein the steam is provided at an initial steam temperature of between 100° C. and 200° C.
10. The process of claim 2 , wherein the steam has a dew point temperature at the pressure, and the beta calcium sulfate hemihydrate is provided to the pressure chamber at a plaster temperature within +/−5° C. of the dew point temperature.
11. The process of claim 1 , wherein the pressure is between 0.1 psi g and 210 psi g .
12. The process of claim 3 , wherein residence time is between 5 seconds and 900 seconds.
13. The process of claim 3 , wherein the residence time is between 5 seconds and 600 seconds.
14. The process of claim 3 , wherein during step ii. additional steam is provided to the pressure chamber.
15. The process of claim 3 , wherein during steps i. to ii. the pressure chamber is heated.
16. A process for utilizing the product of the process of claim 1 , comprising mixing the treated product with water to form a pourable slurry, wherein 10 parts of the treated product are mixed with less than 7.5 parts water by weight to form the pourable slurry.
17. The process of claim 1 , wherein the process is a continuous process.
18. The process of claim 1 , wherein the process is a batch process.
19. The process of claim 1 , wherein step a. comprises forming a loosely packed bed of powdered beta calcium sulfate hemihydrate in the pressure chamber.
20. The process of claim 1 , wherein the steam is superheated.
21. The process of claim 1 , further comprising feeding the beta calcium sulfate hemihydrate to the pressure chamber directly from a calcining process.
22. The process of claim 21 , wherein the beta calcium sulfate hemihydrate is fed to the pressure chamber at an initial plaster temperature of between about 120° C. to 190° C.
23. The process of claim 1 , wherein the beta calcium sulfate hemihydrate is fed to the pressure chamber at an initial plaster temperature of between about 120° C. to 190° C.