Method of producing lower alcohols from glycerol
View Patent ↗A reactive-separation process converts glycerin into lower alcohols, having boiling points less than 200° C., at high yields. Conversion of natural glycerin to propylene glycol through an acetol intermediate is achieved at temperatures from 150° to 250° C. at a pressure ranging from 1 and 25 bar. The preferred applications of the propylene glycol are as an antifreeze, deicing compound, or anti-icing compound. The preferred catalyst for this process in a copper-chromium powder.
1. A process for converting glycerol to propylene glycol with high selectivity, comprising the steps of:
heating a glycerol-containing feedstock material in presence of a catalyst that is capable of dehydrating glycerol at a temperature from 170° C. to 270° C. and a pressure from 0.2 to 25 atmospheres with hydrogen as a limiting reagent to prevent formation of propylene glycol such that there is resultant formation of acetol in the feedstock material;
liberating the acetol in vapor phase from the feedstock material; and
reacting the acetol in vapor phase with hydrogen in the presence of a catalyst that is capable of hydrogenating acetol at a hydrogen partial pressure ranging from 0.2 to 50 bars to form propylene glycol.
2. The process of claim 1 , wherein the glycerol-containing feedstock used in the step of heating contains from 5% to 15% water by weight.
3. The process of claim 1 , wherein the catalyst used in the step of heating is a heterogeneous catalyst selected from the group consisting of palladium, nickel, rhodium, copper, zinc, chromium and combinations thereof.
4. The process of claim 1 , wherein the step of liberating the acetol includes stripping the acetol by the action of a gas.
5. The process of claim 4 , wherein the gas is primarily hydrogen.
6. The process of claim 5 , wherein the temperature used in the heating step ranges from 180° C. to 220° C.
7. The process of claim 6 , wherein the pressure used in the heating step ranges from 5 to 18 atmospheres.
8. The process of claim 5 , wherein the step of condensing occurs using a condenser operating at a temperature ranging from 25° C. to 150° C.
9. The process of claim 7 , wherein the condenser operates at a temperature ranging from 25° C. to 60° C.
10. The process of claim 6 , comprising a step of adding a hydrogen co-reagent to promote conversion of acetol to propylene glycol.
11. The process of claim 10 , comprising a step of recycling unused hydrogen from the condenser back to the reaction mixture.
12. The process of claim 1 , wherein the reaction time of the heating step ranges from 4 to 46 hours.
13. The process of claim 1 , wherein the reaction time of the heating step ranges from 4 to 28 hours.