IP Library Granted Patent US 9,112,060
Granted Patent B2
US 9,112,060 · App. 13/070,049 · Granted Aug 18, 2015

Low-leakage, high-capacitance capacitor structures and method of making

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Quick Facts
Patent No.
US 9,112,060
App. No.
13/070,049
Granted
Aug 18, 2015
Kind
B2
Abstract

A process and device structure is provided for increasing capacitance density of a capacitor structure. A sandwich capacitor is provided in which a bottom silicon-containing conductor plate is formed with holes or cavities, upon which an oxide layer and a top silicon-containing layer conductor is formed. The holes or cavities provide additional capacitive area, thereby increasing capacitance per footprint area of the capacitor structure. The holes can form, for example, a line structure or a waffle-like structure in the bottom conductor plate. Etching techniques used to form the holes in the bottom conductor plate can also result in side wall tapering of the holes, thereby increasing the surface area of the silicon-containing layer defined by the holes. In addition, depth of holes can be adjusted through timed etching to further adjust capacitive area.

Claims (43)

1. A method for forming a capacitor structure, the method comprising:

forming a first dielectric layer over a substrate;

forming a first silicon-containing layer over the first dielectric layer;

forming a patterned masking layer over the first silicon-containing layer;

performing an etch using the patterned masking layer to form a plurality of openings in the first silicon-containing layer, wherein after said performing the etch each opening has a depth that does not expose the first dielectric layer;

forming a second dielectric layer over the first silicon-containing layer and within each of the plurality of openings in the first silicon-containing layer, wherein, after forming the second dielectric layer, each of the plurality of openings has an opening top width and an opening height and the opening height is greater than or equal to the opening top width; and

forming a second silicon-containing layer over the second dielectric layer, wherein the second silicon-containing layer fills each of the plurality of openings.

2. The method of claim 1 , wherein the forming the second dielectric layer over the first silicon-containing layer is performed such that, after the forming the second dielectric layer, each of the plurality of openings has an opening height that is greater than or equal to 1.5 times the opening top width.

3. The method of claim 1 , wherein

the first silicon-containing layer, the first dielectric layer, and the substrate form a first capacitance of the capacitor structure, and

the first silicon-containing layer, the second dielectric layer, and the second silicon-containing layer form a second capacitance of the capacitor structure.

4. The method of claim 3 , wherein the first capacitance is in parallel with the second capacitance.

5. The method of claim 1 , wherein the forming the plurality of openings in the first silicon-containing layer is performed such that the plurality of openings form a grid of openings in the first silicon-containing layer.

6. The method of claim 1 , wherein the forming the plurality of openings in the first silicon-containing layer is performed such that each of the plurality of openings has an opening top length that is at least five times greater than the opening top width.

7. The method of claim 6 , wherein the forming the plurality of openings in the first silicon-containing layer is performed such that the plurality of openings are parallel to each other.

8. The method of claim 1 , wherein the forming the second dielectric layer comprises:

forming a first oxide layer over the first silicon-containing layer;

forming a nitride layer over the first oxide layer; and

forming a second oxide layer over the nitride layer.

9. A method for forming a capacitor structure, the method comprising:

forming a first dielectric layer over a substrate;

forming a first silicon-containing layer over the first dielectric layer;

forming a plurality of openings in the first silicon-containing layer, wherein after said forming the plurality of openings, the openings are a depth that does not expose the first dielectric layer;

forming a second dielectric layer over the first silicon-containing layer and within each of the plurality of openings in the first silicon-containing layer, wherein, after forming the second dielectric layer, each of the plurality of openings has an opening top width and an opening height and the opening top width is greater than twice a thickness of the second dielectric layer; and

forming a second silicon-containing layer over the second dielectric layer, wherein the second silicon-containing layer fills each of the plurality of openings.

10. The method of claim 9 , wherein the forming the second dielectric layer over the first silicon-containing layer is performed such that, after the forming the second dielectric layer, each of the plurality of openings has an opening height that is greater than or equal to the opening top width.

11. The method of claim 9 , wherein

the first silicon-containing layer, the first dielectric layer, and the substrate form a first capacitance of the capacitor structure, and

the first silicon-containing layer, the second dielectric layer, and the second silicon-containing layer form a second capacitance of the capacitor structure.

12. The method of claim 11 , wherein the first capacitance is in parallel with the second capacitance.

13. The method of claim 9 , wherein the forming the plurality of openings in the first silicon-containing layer is performed such that the plurality of openings form a grid of openings in the first silicon-containing layer.

14. The method of claim 9 , wherein the forming the plurality of openings in the first silicon-containing layer is performed such that each of the plurality of openings has an opening top length that is at least five times greater than the opening top width.

15. The method of claim 14 , wherein the forming the plurality of openings in the first silicon-containing layer is performed such that the plurality of openings are parallel to each other.

16. The method of claim 9 , wherein the forming the plurality of openings in the first silicon-containing layer comprises:

forming a patterned masking layer over the first silicon-containing layer; and

performing an etch using the patterned masking layer to form the plurality of openings.

17. A capacitor structure, comprising:

a first dielectric layer over a semiconductor substrate;

a first silicon-containing layer over the first dielectric layer, wherein the first silicon-containing layer includes a plurality of openings that have a depth that does not expose the first dielectric layer;

a second dielectric layer over the first silicon-containing layer and within each of the plurality of openings in the first silicon-containing layer, wherein, with the second dielectric layer within each of the plurality of openings, each of the plurality of openings has an opening top width and an opening height and the opening top width is greater than twice a thickness of the second dielectric layer; and

a second silicon-containing layer over the second dielectric layer, wherein the second silicon-containing layer fills each of the plurality of openings, and wherein:

the first silicon-containing layer, the first dielectric layer, and the substrate form a first capacitance of the capacitor structure, and

the first silicon-containing layer, the second dielectric layer, and the second silicon-containing layer form a second capacitance of the capacitor structure which is in parallel with the first capacitance of the capacitor structure.

Assignments (16)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 041144/0363 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0334 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0387 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0285 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →