Method of manufacturing semiconductor device, method of processing substrate and substrate processing apparatus
An insulating film having features such as a low dielectric constant, a low etching rate and a high insulating property is formed. An oxycarbonitride film having a predetermined thickness is formed on a substrate in a process vessel by performing a cycle a predetermined number of times, wherein the cycle includes steps of: (a) performing a set of steps a predetermined number of times to form a carbonitride layer having a predetermined thickness on the substrate; and (b) supplying an oxygen-containing gas into the process vessel to oxidize the carbonitride layer having the predetermined thickness, thereby forming an oxycarbonitride layer, wherein the set of steps includes: (a-1) supplying a gas containing an element into the process vessel accommodating the substrate under a condition where a CVD reaction is caused to form a layer containing the element on the substrate; (a-2) supplying a carbon-containing gas into the process vessel to form a carbon-containing layer on the layer containing the element, thereby forming a layer including the element and a carbon; and (a-3) supplying a nitrogen-containing gas into the process vessel to nitride the layer including the element and the carbon, thereby forming the carbonitride layer.
1. A method of manufacturing a semiconductor device comprising performing a cycle a predetermined number of times to form an oxycarbonitride film having a predetermined thickness on a substrate in a process vessel, wherein the cycle comprises steps of:
(a) performing a set of steps a predetermined number of times to form a carbonitride layer having a predetermined thickness on the substrate; and
(b) supplying an oxygen-containing gas into the process vessel to oxidize the carbonitride layer having the predetermined thickness, thereby forming an oxycarbonitride layer,
wherein the set of steps comprises:
(a-1) supplying a gas containing an element into the process vessel accommodating the substrate under a condition where a CVD reaction is caused to form a layer containing the element on the substrate;
(a-2) supplying a carbon-containing gas into the process vessel to form a carbon-containing layer on the layer containing the element, thereby forming a layer including the element and a carbon; and
(a-3) supplying a nitrogen-containing gas into the process vessel to nitride the layer including the element and the carbon, thereby forming the carbonitride layer.
2. The method according to claim 1 , wherein, in the step (b), the carbonitride layer having the predetermined thickness is thermally oxidized under a condition where an oxidation reaction of the carbonitride layer having the predetermined thickness caused by the oxygen-containing gas is unsaturated.
3. The method according to claim 1 , wherein, in the step (a-2), a discontinuous chemical adsorption layer is formed as the carbon-containing layer on the layer containing the element,
in the step (a-3), the layer including the element and the carbon is thermally nitrided under a condition where a nitridation reaction of the layer including the element and the carbon caused by the nitrogen-containing gas is unsaturated, and
in the step (b), the carbonitride layer having the predetermined thickness is thermally oxidized under a condition where an oxidation reaction of the carbonitride layer having the predetermined thickness caused by the oxygen-containing gas is unsaturated.
4. The method according to claim 1 , wherein, in the step (a-1), a deposition layer of the element is formed as the layer containing the element on the substrate,
in the step (a-2), a discontinuous chemical adsorption layer is formed as the carbon-containing layer on the layer containing the element,
in the step (a-3), the layer including the element and the carbon is thermally nitrided under a condition where a nitridation reaction of the layer including the element and the carbon caused by the nitrogen-containing gas is unsaturated, and
in the step (b), the carbonitride layer having the predetermined thickness is thermally oxidized under a condition where an oxidation reaction of the carbonitride layer having the predetermined thickness caused by the oxygen-containing gas is unsaturated.
5. The method according to claim 1 , wherein a composition of the oxycarbonitride film is adjusted by controlling a pressure in the process vessel, or the pressure and a gas supply time in at least one of the steps.
6. The method according to claim 1 , wherein at least one of concentrations of the element, the carbon, a nitrogen and an oxygen in the oxycarbonitride film is adjusted by controlling a pressure in the process vessel, or the pressure and a gas supply time in at least one of the steps.
7. The method according to claim 1 , wherein the element comprises a semiconductor element or a metal element.
8. The method according to claim 1 , wherein the element is a silicon.
9. A method of processing a substrate comprising performing a cycle a predetermined number of times to form an oxycarbonitride film having a predetermined thickness on a substrate in a process vessel, wherein the cycle comprises steps of:
(a) performing a set of steps a predetermined number of times to form a carbonitride layer having a predetermined thickness on the substrate; and
(b) supplying an oxygen-containing gas into the process vessel to oxidize the carbonitride layer having the predetermined thickness, thereby forming an oxycarbonitride layer,
wherein the set of steps comprises:
(a-1) supplying a gas containing an element into the process vessel accommodating the substrate under a condition where a CVD reaction is caused to form a layer containing the element on the substrate;
(a-2) supplying a carbon-containing gas into the process vessel to form a carbon-containing layer on the layer containing the element, thereby forming a layer including the element and a carbon; and
(a-3) supplying a nitrogen-containing gas into the process vessel to nitride the layer including the element and the carbon, thereby forming the carbonitride layer.