IP Library Granted Patent US 8,445,969
Granted Patent B2
US 8,445,969 · App. 13/094,873 · Granted May 21, 2013

High pressure deuterium treatment for semiconductor/high-K insulator interface

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Quick Facts
Patent No.
US 8,445,969
App. No.
13/094,873
Granted
May 21, 2013
Kind
B2
Abstract

An integrated circuit structure comprises at least one pair of complementary transistors on a substrate. The pair of complementary transistors includes a first transistor and a second transistor. In addition, only one stress-producing layer is on the first transistor and the second transistor and applies tensile strain force on the first transistor and the second transistor. The first transistor has a first channel region, a gate insulator on the first channel region, and a deuterium region between the first channel region and the gate insulator. The second transistor has a germanium doped channel region, as well as the same gate insulator on the germanium doped channel region, and the same deuterium region between the germanium doped channel region and the gate insulator.

Claims (45)

1. An integrated circuit structure comprising:

a substrate;

at least one pair of complementary transistors on said substrate, said pair of complementary transistors comprising a first transistor and a second transistor; and

only one stress-producing layer on said first transistor and said second transistor applying tensile strain force on said first transistor and said second transistor;

said first transistor comprising a first channel region, a gate insulator on said first channel region, and a deuterium region between said first channel region and said gate insulator, and

said second transistor comprising a germanium doped channel region, said gate insulator on said germanium doped channel region, and said deuterium region between said germanium doped channel region and said gate insulator.

2. The integrated circuit structure according to claim 1 , said pair of complementary transistors comprising complementary metal oxide (CMOS) transistors.

3. The integrated circuit structure according to claim 1 , said first transistor comprising a negative-type (N-type) transistor and said second transistor comprising a positive-type (P-type) transistor.

4. The integrated circuit structure according to claim 1 , said second transistor comprising a silicon germanium channel and said first transistor comprising a silicon channel free of germanium.

5. The integrated circuit structure according to claim 1 , said stress-producing layer comprising silicon-nitride.

6. The integrated circuit structure according to claim 1 , said stress-producing layer comprising the same material on said first transistor and said second transistor.

7. An integrated circuit structure comprising:

a substrate;

at least one pair of complementary transistors on said substrate, said pair of complementary transistors comprising a first transistor and a second transistor; and

only one stress-producing layer on said first transistor and said second transistor applying tensile strain force on said first transistor and said second transistor;

said first transistor comprising a first channel region, a gate insulator on said first channel region, and a deuterium region between said first channel region and said gate insulator,

said first channel region comprising one of gallium arsenide and indium gallium arsenide, and

said second transistor comprising a germanium doped channel region, said gate insulator on said germanium doped channel region, and said deuterium region between said germanium doped channel region and said gate insulator.

8. The integrated circuit structure according to claim 7 , said pair of complementary transistors comprising complementary metal oxide (CMOS) transistors.

9. The integrated circuit structure according to claim 7 , said first transistor comprising a negative-type (N-type) transistor and said second transistor comprising a positive-type (P-type) transistor.

10. The integrated circuit structure according to claim 7 , said second transistor comprising a silicon germanium channel.

11. The integrated circuit structure according to claim 7 , said stress-producing layer comprising silicon-nitride.

12. The integrated circuit structure according to claim 7 , said stress-producing layer comprising the same material on said first transistor and said second transistor.

13. A method of manufacturing an integrated circuit structure, said method comprising:

forming complementary channel regions separated by isolation regions within a substrate, said complementary channel regions comprising a first channel region of a first transistor, and said channel regions further comprising a germanium doped channel region of a second transistor;

simultaneously patterning gate insulators on said complementary channel regions;

simultaneously patterning gate conductors on said gate insulators;

heating said substrate in a pressurized vessel containing deuterium to simultaneously form deuterium regions between said complementary channel regions and said gate insulators; and

simultaneously forming only one stress-producing layer on said first transistor and said second transistor, said stress-producing layer applying tensile strain force on said first transistor and said second transistor.

14. The method according to claim 13 , said first transistor comprising a negative-type (N-type) transistor and said second transistor comprising a positive-type (P-type) transistor.

15. The method according to claim 13 , said second transistor comprising a silicon germanium channel and said first transistor comprising a silicon channel free of germanium.

16. The method according to claim 13 , said heating being performed at a pressure of at least 20 atmospheres.

17. The method according to claim 13 , said forming of said stress-producing layer comprising forming a layer of silicon-nitride.

18. The method according to claim 13 , said stress-producing layer comprising the same material on said first transistor and said second transistor.

19. A method of manufacturing an integrated circuit structure, said method comprising:

forming complementary channel regions separated by isolation regions within a substrate, said complementary channel regions comprising a first channel region of a first transistor, said first channel region comprising one of gallium arsenide and indium gallium arsenide, and said channel regions further comprising a germanium doped channel region of a second transistor;

simultaneously patterning gate insulators on said complementary channel regions;

simultaneously patterning gate conductors on said gate insulators;

heating said substrate in a pressurized vessel containing deuterium to simultaneously form deuterium regions between said complementary channel regions and said gate insulators; and

simultaneously forming only one stress-producing layer on said first transistor and said second transistor, said stress-producing layer applying tensile strain force on said first transistor and said second transistor.

20. The method according to claim 19 , said first transistor comprising a negative-type (N-type) transistor and said second transistor comprising a positive-type (P-type) transistor.

21. The method according to claim 19 , said second transistor comprising a silicon germanium channel and said first transistor comprising a silicon channel free of germanium.

22. The method according to claim 19 , said heating being performed at a pressure of at least 20 atmospheres.

23. The method according to claim 19 , said forming of said stress-producing layer comprising forming a layer of silicon-nitride.

24. The method according to claim 19 , said stress-producing layer comprising the same material on said first transistor and said second transistor.

Assignments (32)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NATURE OF CONVEYANCE PREVIOUSLY RECORDED AT REEL: 040632 FRAME: 0001. ASSIGNOR(S) HEREBY CONFIRMS THE MERGER AND CHANGE OF NAME. Recorded Sep 21, 2017
From: FREESCALE SEMICONDUCTOR INC.
To: NXP USA, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CHANGE OF NAME Recorded Nov 8, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 040632/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0334 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
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SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Jan 31, 2012
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Jan 31, 2012
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
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SECURITY AGREEMENT Recorded Jan 31, 2012
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
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ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 27, 2011
From: KANG, LAEGU
To: FREESCALE SEMICONDUCTOR, INC.
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ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 27, 2011
From: CHEN, XIANGDONG; LI, WEIPENG; PARK, DAE-GYU; SHERONY, MELANIE J.
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
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