Methods of determining and making red nitride compositions
View Patent ↗Provided according to embodiments of the invention are methods of making a Ca 1-x-y Sr x Eu y AlSiN 3 phosphor composition that include selecting a relative color point; determining Eu and Sr concentrations based on predetermined values to obtain the selected relative color point; and making the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor having the determined Eu and Sr concentrations. Also provided are methods for determining concentrations of Sr and Eu in a Ca 1-x-y Sr x Eu y AlSiN 3 phosphor that will achieve a relative color point. Related computer products are also disclosed.
1. A method of making a Ca 1-x-y Sr x Eu y AlSiN 3 phosphor composition comprising:
selecting a relative color point in a three-dimensional space comprising a relative color axis, a relative brightness axis and a third axis comprising one of: a Sr/Eu axis, a Sr concentration axis or a Eu concentration axis;
determining, based on a predetermined region in the three-dimensional space, a range of Sr to Eu ratios, a range of Sr concentrations, and/or a range of Eu concentrations to obtain the selected relative color point; and
making a Ca 1-x-y Sr x Eu y AlSiN 3 phosphor composition having one of the Sr to Eu ratios, one of the Sr concentrations, and/or one of the Eu concentrations.
2. The method of claim 1 , further comprising selecting a relative brightness in the three-dimensional space before determining the range of Sr to Eu ratios, the range of Sr concentrations, or the range of Eu concentrations, and wherein the determining comprises obtaining the selected relative color point and the selected relative brightness.
3. The method of claim 2 , wherein the selected relative color point is in a range of −0.005 to 0.02.
4. The method of claim 2 , wherein the selected relative brightness is in a range of 0.75 to 1.75.
5. The method of claim 2 , wherein the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor composition absorbs light at a wavelength in a range of 350 nm and 530 nm and emits peak frequencies at a wavelength in a range of 620 nm to 660 nm.
6. The method of claim 2 , wherein the Sr to Eu ratio in the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor is in a range of 25 to 300.
7. The method of claim 2 , wherein for the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor, x is in a range of 0.50 to 0.99 and y is in a range of 0.001 to 0.025.
8. The method of claim 2 , wherein for the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor, x is in a range of 0.70 to 0.99 and y is in a range of 0.001 to 0.025.
9. The method of claim 2 , wherein for the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor, x is in a range of 0.50 to 0.99 and y is less than 0.013.
10. The method of claim 2 , wherein the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor composition is present in particulate form and at least 50% of the particles are elongated.
11. The method of claim 1 , wherein the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor comprises at least 1% by weight of silicon aluminum oxynitride.
12. The method of claim 1 , wherein the third axis is the Sr/Eu axis, and the predetermined region in the three-dimensional space spans Sr to Eu ratios of from 25 to 300 along the Sr/Eu axis.
13. The method of claim 1 , wherein the third axis is the Sr concentration axis, and the predetermined region in the three-dimensional space spans Sr concentrations of from 0.5 to 0.99.
14. The method of claim 1 , wherein the third axis is the Eu concentration axis, and the predetermined region in the three-dimensional space spans Eu concentrations of from 0.001 to 0.025.
15. A method for determining concentrations of Sr and Eu in a Ca 1-x-y Sr x Eu y AlSiN 3 phosphor that will achieve a relative color point, the method comprising:
selecting a relative color point in a three-dimensional space comprising a relative color axis, a relative brightness axis and a third axis comprising one of: a Sr/Eu axis, a Sr concentration axis or a Eu concentration axis; and
determining, based on a predetermined region in the three-dimensional space, a range of Sr to Eu ratios, a range of Sr concentrations, and/or a range of Eu concentrations to obtain the selected relative color point for a Ca 1-x-y Sr x Eu y AlSiN 3 phosphor.
16. The method of claim 15 , further comprising selecting a relative brightness in the three-dimensional space before determining the range of Sr to Eu ratios, the range of Sr concentrations, or the range of Eu concentrations, and wherein the determining comprises obtaining the selected relative color point and the selected relative brightness.
17. The method of claim 16 , wherein the selected relative color point is in a range of −0.005 to 0.02.
18. The method of claim 16 , wherein the selected relative brightness is in a range of 0.75 to 1.75.
19. The method of claim 16 , wherein the Sr to Eu ratio in the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor is in a range of 25 to 300.
20. The method of claim 16 , wherein for the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor, x is in a range of 0.50 to 0.99 and y is in a range of 0.001 to 0.025.
21. The method of claim 16 , wherein for the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor, x is in a range of 0.70 to 0.99 and y is in a range of 0.001 to 0.025.
22. The method of claim 16 , wherein for the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor, x is in a range of 0.50 to 0.99 and y is less than 0.013.
23. The method of claim 16 , wherein the Ca 1-x-y Sr x Eu y AlSiN 3 phosphor comprises at least 1% by weight of silicon aluminum oxynitride.
24. The method of claim 15 , wherein the third axis is the Sr/Eu axis, and the predetermined region in the three-dimensional space spans Sr to Eu ratios of from 25 to 300 along the Sr/Eu axis.
25. The method of claim 15 , wherein the third axis is the Sr concentration axis, and the predetermined region in the three-dimensional space spans Sr concentrations of from 0.5 to 0.99.
26. The method of claim 15 , wherein the third axis is the Eu concentration axis, and the predetermined region in the three-dimensional space spans Eu concentrations of from 0.001 to 0.025.