Printed wiring board encapsulated by adhesive laminate comprising a di-isoimide, and process for preparing same
View Patent ↗The present invention deals with a flexible printed wiring board in the form of a printed wiring board wherein the conductive elements are fully encapsulated by an epoxy adhesive comprising a novel aromatic di-isoimide chemical compound. The conductive elements are thereby protected. The flexible printed wiring board is readily cured at a temperature in the range of 100 to 250° C. However, before curing, by virtue of the latent cure feature of the epoxy adhesive, the adhesive component of the printed wiring board has an extended shelf life, and avoids premature curing during processing.
1. A printed wiring board comprising in order a first layer of a first dielectric substrate, a second layer of one or more discrete electrically conductive pathways disposed upon said first dielectric substrate, a third layer of a bonding layer in adhesive contact with said discrete electrically conductive pathways, and adheringly disposed upon a fourth layer comprising a second dielectric substrate, said bonding layer comprising a curable composition comprising a solvent having mixed therewithin an epoxy and a di-isoimide represented by Structure I
wherein R 1 is H, halogen, hydrocarbyl, hydrocarbyloxy, hydrocarbylthio, amido, sulfonamido, cyclic amino, acyl, morpholino, piperidino, or NR′R″ wherein R′ and R″ are independently H, alkyl or aromatic, substituted or unsubstituted.
2. The printed wiring board of claim 1 wherein R 1 is NH 2 .
3. The printed wiring board of claim 1 wherein the solvent is methyl ethyl ketone, cyclohexanone, propylene glycol methyl ether acetate, N,N-dimethylformamide, or a mixture thereof.
4. The printed wiring board of claim 1 wherein, the epoxy is a bisphenol A diglycidyl ether.
5. The printed wiring board of claim 1 wherein R 1 is NH 2 ; the solvent is methyl ethyl ketone, cyclohexanone, propylene glycol methyl ether acetate, N,N-dimethylformamide, or a mixture thereof; and, the epoxy is a bisphenol A diglycidyl ether.
6. The printed wiring board of claim 5 herein said curable composition further comprises an elastomer, a thermoplastic polymer, or a combination thereof.
7. The printed wiring board of claim 1 wherein said curable composition further comprises an elastomer, a thermoplastic polymer, or a combination thereof.
8. The printed wiring board of claim 1 wherein said first and second dielectric substrates are films or sheets of a fully aromatic polyimide.
9. The printed wiring board of claim 8 wherein each said film or sheet comprises a polyimide that is the condensation product of PMDA and 4,4′-ODA.
10. A printed wiring board comprising in order a first layer of a first dielectric substrate, a second layer of one or more discrete electrically conductive pathways disposed upon said first dielectric substrate, a third layer of a bonding layer in adhesive contact with said discrete electrically conducting pathways, and adheringly disposed upon a fourth layer comprising a second dielectric substrate, said bonding layer comprising a curable composition consisting essentially of a solvent having mixed therewithin an epoxy and a di-isoimide composition represented by Structure I
wherein R 1 is H, halogen, hydrocarbyl, hydrocarbyloxy, hydrocarbylthio, amido, sulfonamido, cyclic amino, acyl, morpholino, piperidino, or NR′R″ wherein R′ and R″ are independently H, alkyl or aromatic, substituted or unsubstituted.
11. The printed wiring board of claim 10 wherein R 1 is NH 2 ; the solvent is methyl ethyl ketone, cyclohexanone, propylene glycol methyl ether acetate, N,N-dimethylformamide, or a mixture thereof; and, the epoxy is a bisphenol A diglycidyl ether.
12. A printed wiring board comprising in order a first layer of a first dielectric substrate, a second layer of one or more discrete electrically conductive pathways disposed upon said first dielectric substrate, a third layer of a bonding layer in adhesive contact with said discrete electrically conducting pathways, and adheringly disposed upon a fourth layer comprising a second dielectric substrate, said bonding layer comprising a curable composition consisting essentially of a solvent having mixed therewithin an epoxy; an elastomer, a thermoplastic polymer, or a combination thereof; and a di-isoimide represented by Structure I
wherein R 1 is H, halogen, hydrocarbyl, hydrocarbyloxy, hydrocarbylthio, amido, sulfonamido, cyclic amino, acyl, morpholino, piperidino, or NR′R″ wherein R′ and R″ are independently H, alkyl or aromatic, substituted or unsubstituted.
13. The printed wiring board of claim 12 wherein R 1 is NH 2 ; the solvent is methyl ethyl ketone, cyclohexanone, propylene glycol methyl ether acetate, N,N-dimethylformamide, or a mixture thereof; and, the epoxy is a bisphenol A diglycidyl ether.
14. A process of preparing an encapsulated printed wiring board comprising adhesively contacting the coated surface of a laminated article having a surface with a coating disposed thereupon to at least a portion of discrete conductive pathways disposed upon a dielectric substrate thereby forming a printed wiring board comprising in order a first layer of a first dielectric substrate, a second layer of one or more discrete electrically conductive pathways disposed upon said first dielectric substrate, a third layer of a bonding layer in adhesive contact with said discrete electrically conductive pathways, and adheringly disposed upon a fourth layer comprising a second dielectric substrate,
wherein said coating comprises a curable composition comprising a solvent having mixed therewithin an epoxy and a di-isoimide; and, applying pressure to the printed wiring board so formed at a temperature in a range of 100 to 250° C. for a period of time in a range of 5 minutes to 5 hours, thereby forming the encapsulated printed wiring board;
wherein said di-isoimide is represented by Structure I
wherein R 1 is H, halogen, hydrocarbyl, hydrocarbyloxy, hydrocarbylthio, amido, sulfonamido, cyclic amino, acyl, morpholino, piperidino, or NR′R″; and wherein R′ and R″ are independently H, alkyl or aromatic, substituted or unsubstituted.
15. The process of claim 14 further comprising extracting said solvent in said curable composition before applying pressure to said printed wiring board.