Chemical mechanical polishing of silicon carbide comprising surfaces
Slurry compositions and chemically activated CMP methods for polishing a substrate having a silicon carbide surface using such slurries. In such methods, the silicon carbide surface is contacted with a CMP slurry composition that comprises i) a liquid carrier and ii) a plurality of particles having at least a soft surface portion, wherein the soft surface portion includes a transition metal compound that provides a Mohs hardness ≦6, and optionally iii) an oxidizing agent. The oxidizing agent can include a transition metal. The slurry is moved relative to the silicon carbide comprising surface, wherein at least a portion of the silicon carbide surface is removed.
1. A method of chemically-mechanically polishing a substrate having a silicon carbide comprising surface, comprising:
providing a chemical-mechanical polishing slurry composition, comprising:
a liquid carrier,
a plurality of particles having at least a soft surface portion, said soft surface portion comprising a transition metal compound coating that provides a Mohs hardness ≦6 or a Knoop Hardness less than 900 Kg/mm 2 , and
an oxidizing agent in a concentration from 0.02M to 0.4 M comprising a first transition metal compound,
wherein said oxidizing agent catalytically breaks down within said slurry composition to form at least one of (i) an insoluble compound that provides at least a portion of said transition metal compound coating and (ii) particles consisting of said insoluble compound, and
contacting said silicon carbide comprising surface with said slurry composition, and
moving said slurry composition relative to said silicon carbide comprising surface, wherein at least a portion of said silicon carbide comprising surface is removed.
2. The method of claim 1 , wherein said slurry composition further comprises a second transition metal compound different from said oxidizing agent, said second transition metal compound being water soluble.
3. The method of claim 2 , wherein said oxidizing agent and said second transition metal compound both comprise Mn.
4. The method of claim 3 , wherein said oxidizing agent comprises permanganate.
5. The method of claim 2 , wherein said transition metal compound coating comprises both an insoluble Mn +3 compound and an insoluble Mn +4 compound.
6. The method of claim 5 , wherein said insoluble Mn +4 compound comprises MnO 2 and said insoluble Mn +3 compound comprises MnCl 3 .
7. The method of claim 1 , wherein said plurality of particles comprise composite particles that comprise a core having a first hardness and said transition metal compound coating on said core having a second hardness, said second hardness < said first hardness by at least one (1) Mohs numbers or said second hardness < said first hardness by at least a Knoop hardness of 100 Kg/mm 2 .
8. The method of claim 7 , wherein said plurality of particles comprise soft functionalized particles and said transition metal compound coating is 0.001 monolayers to 10 monolayers thick.
9. The method of claim 1 , wherein said silicon carbide comprising surface consists essentially of a silicon carbide surface, and a polishing rate for said silicon carbide surface is ≧200 nm/hr.
10. A method of chemically-mechanically polishing, comprising:
providing a substrate having a silicon carbide comprising surface,
chemically-mechanically polishing said silicon carbide comprising surface with a chemical-mechanical polishing slurry composition, said slurry composition comprising:
an aqueous liquid carrier;
an oxidizing agent comprising a transition metal compound;
a plurality of particles having at least a soft surface portion comprising a transition metal compound layer that provides a Mohs hardness <6, said transition metal compound layer comprising both an insoluble Mn +3 compound and an insoluble Mn +4 compound;
contacting said silicon carbide comprising surface with said slurry composition, and
moving said slurry composition relative to said silicon carbide comprising surface, wherein at least a portion of said silicon carbide comprising surface is removed.
11. The method of claim 10 , wherein said slurry composition further comprises said oxidizing agent in a concentration from 0.02M to 0.4 M and said transition metal compound comprises a water soluble first transition metal compound.
12. The method of claim 11 , wherein slurry composition further comprises a second transition metal compound different from said oxidizing agent, said second transition metal compound being water soluble.
13. The method of claim 10 , wherein said insoluble Mn +4 compound comprises MnO 2 and said insoluble Mn +3 compound comprises MnCl 3 .
14. The method of claim 10 , wherein said oxidizing agent catalytically breaks down within said slurry composition to form at least one of said insoluble Mn +3 and Mn +4 compounds.
15. A method of chemically-mechanically polishing a substrate having a silicon carbide comprising surface, comprising:
providing a chemical-mechanical polishing slurry composition, comprising:
a liquid carrier,
a plurality of particles having at least a soft surface portion, said soft surface portion comprising a transition metal compound coating that provides a Mohs hardness ≦6 or a Knoop Hardness less than 900 Kg/mm 2 , and
an oxidizing agent in a concentration from 0.02M to 0.4 M comprising a first transition metal compound,
wherein said oxidizing agent catalytically breaks down within said slurry composition to form at least one of (i) an insoluble compound that provides at least a portion of said transition metal compound coating and (ii) particles consisting of said insoluble compound, and
contacting said silicon carbide comprising surface with said slurry composition; and
moving said slurry composition relative to said silicon carbide comprising surface, wherein at least a portion of said silicon carbide comprising surface is removed,
wherein said silicon carbide comprising surface consists essentially of a silicon carbide surface, and a polishing rate for said silicon carbide surface is ≧200 nm/hr.