THREE DIMENSIONAL LIGHT EMITTING DIODE SYSTEMS, AND COMPOSITIONS AND METHODS RELATING THERETO

1 . A method of making an LED lighting assembly comprising:

a) pulling a flexible layered structure from a reel or from a stack of panels or sheets, the flexible layered structure comprising:

i. a flexible top conductive layer comprising a first conductive metal, the flexible top conductive layer having a thickness from 4 to 200 microns;

ii. a flexible bottom heat sink layer comprising a second conductive metal and the flexible bottom heat sink layer having a thickness of at least 50 microns;

iii. a flexible dielectric middle layer comprising a polymer, the flexible dielectric middle layer having a thickness from 4 to 100 microns and providing electrical insulation between the flexible top conductive layer and the flexible bottom heat sink layer;

iv. a heat sink adhesive layer; and

v. a release liner

wherein the first conductive metal of the flexible top conductive layer being the same or different from the second conductive metal of the flexible bottom heat sink layer, and

the flexible layered structure has a longitudinal axis and a plurality of defined positions spaced along the longitudinal axis, the flexible layered structure being bendable at least 10 degrees proximate at least one of the plurality of defined positions spaced along the longitudinal axis and the flexible layered structure also being twistable relative to the longitudinal axis,

b) removing the release liner thereby exposing a the heat sink adhesive layer,

c) applying the heat sink adhesive layer to a secondary heat sink, thereby adhering at least a portion of the flexible layered structure to the secondary heat sink;

d) configuring the flexible layered structure with the release liner removed into a three dimensional configuration;

wherein at any time before, during or after during the above method steps, the flexible top conductive layer is circuitized and thereafter at least two LEDs are applied to the flexible top conductive layer of the flexible layered structure.

2 . The method in accordance with claim 1 , wherein the flexible layered structure is bent into a light bulb replacement configuration sufficient for the LED lighting assembly to be a replacement for one or more of the following: down lights A-lamp bulbs, PAR-lamp bulbs, R-lamp bulbs, MR16-lamp bulbs, candelabra lamp bulbs and linear fluorescent bulbs.

3 . The method in accordance with claim 1 , wherein the flexible layered structure is bent into a configuration sufficient to provide one or more of the following types of lights:

cove lights;

residential overhead lights;

linear lights;

rope lights;

accent lights;

projector lights;

stage bar lights;

par lamp lights;

color changer lights;

display case lights;

undercabinet lights;

backdrop lights;

refrigerated display case lights;

hazardous lights;

industrial fixture lights;

functional office lights;

down lights;

recessed lights;

roadway lights;

canopy lights;

area lights;

pole top lights;

solar flood lights;

lantern lights;

decorative suspended lights;

task lights;

flash light;

headlamps;

work lights; and

exit sign lights.

4 . The method in accordance with claim 1 , wherein at least 50 weight percent of the flexible dielectric middle layer is a polyimide derived from at least 30 mole percent aromatic dianhydride based upon total dianhydride content of the polyimide and at least 30 mole percent aromatic diamine based upon total diamine content of the polyimide.

5 . The method in accordance with claim 1 , wherein the flexible dielectric middle layer comprises 1 to 50 weight percent thermally conductive filler, the thermally conductive filler comprising one or more members of the group consisting of carbides, nitrides, borides and oxides.