Three dimensional light emitting diode systems, and compositions and methods relating thereto

1. A flexible layered structure comprising:

i. a flexible top conductive layer comprising a first conductive metal, the flexible top conductive layer having a thickness from 4 to 200 microns;

ii. a flexible bottom heat sink layer having a top surface and a bottom surface, the flexible bottom heat sink layer comprising a second conductive metal and the flexible bottom heat sink layer having a thickness of at least 50 microns; and

iii. a flexible dielectric middle layer comprising a polymer;

the flexible dielectric middle layer having a thickness from 4 to 100 microns and providing electrical insulation between the flexible top conductive layer and the flexible bottom heat sink layer;

the first conductive metal of the flexible top conductive layer being the same or different from the second conductive metal of the flexible bottom heat sink layer, and

the flexible layered structure having a longitudinal axis and a plurality of defined positions spaced along the longitudinal axis, the flexible layered structure being bendable at least 10 degrees proximate at least one of the defined positions spaced along the longitudinal axis and the flexible layered structure also being twistable relative to the longitudinal axis.

2. The flexible layered structure in accordance with claim 1 further comprising a heat sink adhesive layer having a top surface and a bottom surface, the top surface of the heat sink adhesive layer being bonded to the bottom surface of the flexible bottom heat sink layer and the bottom surface of the heat sink adhesive layer being covered by a release liner.

3. The flexible layered structure in accordance with claim 2 , wherein the flexible layered structure is conformed to at least a portion of a secondary heat sink and bonded to the secondary heat sink by at least a portion of the heat sink adhesive layer.

4. The flexible layered structure in accordance with claim 1 being at least partially bent around a longitudinal axis.

5. The flexible layered structure in accordance with claim 4 , wherein at least a portion of the flexible layered structure is bent by at least 10 degrees.

6. The flexible layered structure in accordance with claim 1 comprising a top adhesive layer bonding the flexible top conductive layer to the flexible dielectric middle layer.

7. The flexible layered structure in accordance with claim 1 comprising a bottom adhesive layer bonding the flexible dielectric middle layer to the flexible bottom heat sink layer.

8. The flexible layered structure in accordance with claim 1 comprising a top adhesive layer bonding the flexible top conductive layer to the flexible dielectric middle layer and a bottom adhesive layer bonding the flexible dielectric middle layer to the flexible bottom heat sink layer.

9. The flexible layered structure in accordance with claim 1 , wherein the flexible top conductive layer comprises at least one LED connected to at least one surface mount technology electrical component by a electrical circuit.

10. The flexible layered structure in accordance with claim 1 , wherein the defined positions comprise a notch on the flexible bottom heat sink layer or the flexible top conductive layer.

11. The flexible layered structure in accordance with claim 1 , wherein at least 50 weight percent of the flexible dielectric middle layer is a polyimide derived from at least 30 mole percent aromatic dianhydride based upon total dianhydride content of the polyimide and at least 30 mole percent aromatic diamine based upon total diamine content of the polyimide.

12. The flexible layered structure in accordance with claim 1 , wherein the flexible dielectric middle layer comprises 1 to 50 weight percent thermally conductive filler, the thermally conductive filler comprising one or more members of the group consisting of carbides, nitrides, borides and oxides.