IP Library Granted Patent US 8,735,733
Granted Patent B2
US 8,735,733 · App. 13/352,819 · Granted May 27, 2014

Resin composition, prepreg laminate obtained with the same and printed-wiring board

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Quick Facts
Patent No.
US 8,735,733
App. No.
13/352,819
Granted
May 27, 2014
Kind
B2
Abstract

Disclosed are a resin composition containing (a) a maleimide compound having at least two N-substituted maleimide groups in a molecular structure and (b) a silicone compound having at least one reactive organic group in a molecular structure thereof; and a prepreg using the same, a laminate, and a printed wiring board. A resin composition having excellent heat resistance and low thermal expansion properties; and a prepreg, a laminate, and a printed wiring board using the same can be provided.

Claims (23)

1. A resin composition comprising (a) a maleimide compound having at least two N-substituted maleimide groups in a molecular structure and (b) a silicone compound having at least one reactive organic group in a molecular structure,

wherein the reactive organic group of the (b) silicone compound is at least one selected from an epoxy group, an amino group, a hydroxyl group, a methacryl group, a mercapto group, a carboxyl group, and an alkoxy group,

wherein the (b) silicone compound is a silicone compound containing a structure represented by general formula (II):

wherein each of R 3 and R 4 independently represents an alkyl group, a phenyl group, or a substituted phenyl group; and n represents an integer of 1 to 100, and

further comprising (d) an amine compound having an acidic substituent represented by general formula (I):

each R 1 independently represents a hydroxyl group, a carboxyl group, or a sulfonic acid group as an acidic substituent; each R 2 represents a hydrogen atom, an aliphatic hydrocarbon group having a carbon number of 1 to 5, or a halogen atom; and x represents an integer of 1 to 5 and y represents an integer of 0 to 4, with the proviso that x+y=5.

2. The resin composition according to claim 1 , further comprising (c) a thermosetting resin.

3. The resin composition according to claim 2 , wherein the component (c) is a thermosetting resin having an epoxy group and/or a cyanate group in a molecular structure.

4. The resin composition according to claim 2 , further comprising (f) an inorganic filler.

5. The resin composition according to claim 1 , wherein the silicone compound has at least two reactive organic groups in a molecular structure.

6. The resin composition according to claim 1 , wherein the silicone compound has a reactive organic group on both ends.

7. The resin composition according to claim 1 , wherein the silicone compound has a reactive organic group on either end.

8. The resin composition according to claim 1 , wherein the silicone compound has a reactive organic group in the side chain.

9. The resin composition according to claim 1 , wherein the silicone compound has a reactive organic group in the side chain and on at least one end.

10. The resin composition according to claim 1 , further comprising (e) a curing accelerator represented by formula (III) or (IV):

wherein each of R 6 , R 7 , R 8 , and R 9 independently represents a hydrogen atom, an aliphatic hydrocarbon group having a carbon number of 1 to 5, or a phenyl group; and D represents an alkylene group or an aromatic hydrocarbon group; and

wherein each of R 6 , R 7 , R 8 , and R 9 independently represents a hydrogen atom, an aliphatic hydrocarbon group having a carbon number of 1 to 5, or a phenyl group; and B represents single bond or any one of an alkylene group, an alkylidene group, an ether group, and a sulfonyl group.

11. The resin composition according to claim 1 , further comprising (f) an inorganic filler.

12. A prepreg manufactured by impregnating or coating a substrate with the resin composition according to claim 1 , followed by semi-curing (B-staging) by heating.

13. A laminate plate obtained by laminating and molding the prepreg according to claim 12 .

14. A printed wiring board manufactured by forming a circuit on a surface of the laminate plate according to claim 13 .

15. The resin composition according to claim 1 , which includes 1 to 100 parts by mass of said silicone compound based on 100 parts by mass of said maleimide compound.

16. The resin composition according to claim 15 , which includes 0.1 to 20 parts by mass of said amine compound based on 100 parts by mass of said maleimide compound.

Assignments (4)
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CHANGE OF NAME Recorded Mar 3, 2023
From: SHOWA DENKO MATERIALS CO., LTD.
To: RESONAC CORPORATION
Reel/Frame 062946/0125 →
CHANGE OF NAME Recorded Mar 2, 2023
From: HITACHI CHEMICAL COMPANY, LTD.
To: SHOWA DENKO MATERIALS CO., LTD.
Reel/Frame 062917/0865 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 4, 2012
From: MIYATAKE, MASATO; KOTAKE, TOMOHIKO; NAGAI, SHUNSUKE; HASHIMOTO, SHINTARO; INOUE, YASUO; TAKANEZAWA, SHIN; MURAI, HIKARI
To: HITACHI CHEMICAL COMPANY, LTD.
Reel/Frame 028312/0217 →