Thermal annealing process
View Patent ↗A method for processing a substrate is provided; wherein the method comprises applying a film of a copolymer composition, comprising a poly(styrene)-b-poly(dimethylsiloxane) block copolymer component to a surface of the substrate; optionally, baking the film; subjecting the film to a high temperature annealing process under particularized atmospheric conditions for a specified period of time; followed by a treatment of the annealed film to remove the poly(styrene) from the annealed film and to convert the poly(dimethylsiloxane) in the annealed film to SiO x .
1. A method for processing a substrate, comprising:
providing a substrate having a surface;
providing a copolymer composition, comprising a poly(styrene)-b-poly(dimethylsiloxane) block copolymer component, wherein the number average molecular weight of the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component is 25 to 1,000 kg/mol, and, an optional solvent;
applying a film of the copolymer composition to the surface of the substrate;
baking the film to remove any solvent;
heating the film at 300 to 350° C. under a gaseous atmosphere having an oxygen concentration of ≦7.5 ppm for a period of 1 second to 4 hours to form an annealed film; and,
treating the annealed film to remove the poly(styrene) from the annealed film and to convert the poly(dimethylsiloxane) in the annealed film to SiO x .
2. The method of claim 1 , wherein the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component provided is a single poly(styrene)-b-poly(dimethylsiloxane) diblock copolymer having a number average molecular weight, Ms, of 25 to 1,000 kg/mol; a polydispersity, PD, of 1 to 3; and a poly(dimethylsiloxane) weight fraction, Wf PDMS , of 0.19 to 0.33.
3. The method of claim 2 , wherein the copolymer composition provided further comprises a solvent; wherein the solvent is selected from the group consisting of propylene glycol monomethyl ether acetate (PGMEA), ethoxyethyl propionate, anisole, ethyl lactate, 2-heptanone, cyclohexanone, amyl acetate, γ-butyrolactone (GBL), n-methylpyrrolidone (NMP) and toluene.
4. The method of claim 2 , wherein the copolymer composition provided further comprises an additive; wherein the additive is selected from the group consisting of additional polymers (including homopolymers and random copolymers); surfactants; antioxidants; photoacid generators; thermal acid generators; quenchers; hardeners; adhesion promoters; dissolution rate modifiers; photocuring agents; photosensitizers; acid amplifiers; plasticizers; orientation control agents and cross linking agents.
5. The method of claim 1 , wherein the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component is a blend of at least two different poly(styrene)-b-poly(dimethylsiloxane) block copolymers;
wherein the at least two different poly(styrene)-b-poly(dimethylsiloxane) block copolymers are selected from the group of poly(styrene)-b-poly(dimethylsiloxane) block copolymers having a number average molecular weight, M N , of 1 to 1,000 kg/mol and a polydispersity, PD, of 1 to 3; and,
wherein the blend exhibits a blend number average molecular weight, M N-Blend , of 25 to 1,000 kg/mol.
6. The method of claim 5 , wherein the blend exhibits a blend poly(dimethylsiloxane) weight fraction, Wf PDMS-Blend , of 0.19 to 0.33.
7. The method of claim 6 , wherein the copolymer composition provided further comprises a solvent; wherein the solvent is selected from the group consisting of propylene glycol monomethyl ether acetate (PGMEA), ethoxyethyl propionate, anisole, ethyl lactate, 2-heptanone, cyclohexanone, amyl acetate, γ-butyrolactone (GBL), n-methylpyrrolidone (NMP) and toluene.
8. The method of claim 6 , wherein the copolymer composition provided further comprises a solvent; wherein the solvent is selected from the group consisting of propylene glycol monomethyl ether acetate (PGMEA) and toluene.
9. The method of claim 6 , wherein the copolymer composition provided further comprises an additive; wherein the additive is selected from the group consisting of additional polymers (including homopolymers and random copolymers); surfactants; antioxidants; photoacid generators; thermal acid generators; quenchers; hardeners; adhesion promoters; dissolution rate modifiers; photocuring agents; photosensitizers; acid amplifiers; plasticizers; orientation control agents and cross linking agents.
10. The method of claim 1 , wherein the gaseous atmosphere is selected from the group consisting of nitrogen and argon.
11. The method of claim 1 , wherein the copolymer composition, consists of:
a poly(styrene)-b-poly(dimethylsiloxane) block copolymer component, wherein the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component is selected from the group consisting of (a) a single poly(styrene)-b-poly(dimethylsiloxane) block copolymer; and, (b) a blend of at least two different poly(styrene)-b-poly(dimethylsiloxane) block copolymers; wherein the number average molecular weight of the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component is 25 to 1,000 kg/mol;
an optional solvent; wherein the solvent is selected from the group consisting of propylene glycol monomethyl ether acetate (PGMEA), ethoxyethyl propionate, anisole, ethyl lactate, 2-heptanone, cyclohexanone, amyl acetate, γ-butyrolactone (GBL), n-methylpyrrolidone (NMP) and toluene; and,
an optional additive; wherein the additive is selected from the group consisting of a surfactant and an antioxidant.
12. The method of claim 11 , wherein the gaseous atmosphere is selected from the group consisting of nitrogen and argon.
13. The method of claim 11 , wherein the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component provided is a single poly(styrene)-b-poly(dimethylsiloxane) diblock copolymer having a number average molecular weight, M N , of 25 to 1,000 kg/mol; a polydispersity, PD, of 1 to 3; and a poly(dimethylsiloxane) weight fraction, Wf PDMS , of 0.19 to 0.33.
14. The method of claim 13 , wherein the copolymer composition contains the optional solvent.
15. The method of claim 11 , wherein the poly(styrene)-b-poly(dimethylsiloxane) block copolymer component is a blend of at least two different poly(styrene)-b-poly(dimethylsiloxane) block copolymers;
wherein the at least two different poly(styrene)-b-poly(dimethylsiloxane) block copolymers are selected from the group of poly(styrene)-h-poly(dimethylsiloxane) block copolymers having a number average molecular weight, M N , of 1 to 1,000 kg/mol and a polydispersity, PD, of 1 to 3; and,
wherein the blend exhibits a blend number average molecular weight, M N-Blend , of 25 to 1,000 kg/mol.
16. The method of claim 15 , wherein the blend exhibits a blend poly(dimethylsiloxane) weight fraction, Wf PDMS-Blend , of 0.19 to 0.33.
17. The method of claim 16 , wherein the copolymer composition provided contains the optional solvent.
18. The method of claim 17 , wherein the solvent is selected from the group consisting of propylene glycol monomethyl ether acetate (PGMEA) and toluene.