Metal paste with co-precursors
View Patent ↗A sintering method allows components to be joined to each other in a stable way at a processing temperature of less than 200° C., producing stable contact points having low porosity and high electrical and thermal conductivity. The method includes (a) providing a sandwich arrangement having at least a first component, a second component, and a metal paste located between the first and second components, and (b) sintering the sandwich arrangement. The metal paste includes (A) 75-90 wt. % of at least one metal present in the form of particles having an organic compound-containing coating, (B) 0-12wt % of at least one metal precursor, (C) 6-20wt % of at least one solvent, and (D) 0.1-15 wt % of at least one sintering agent selected from (i) salts of C 1 -C 4 organic acids, (ii) esters of C 1 -C 4 organic acids, and (iii) carbonyl complexes.
1. A metal paste containing:
(A) 75-90 weight percent of at least one metal present in a form of particles having a coating containing at least one organic compound;
(B) 0.1-12 weight percent of at least one metal precursor selected from the group consisting of silver carbonate, silver(I) oxide and silver(II) oxide;
(C) 6-20 weight percent of at least one solvent; and
(D) 0.1-15 weight percent of at least one sintering agent selected from the group consisting of:
(i) salts of organic acids selected from the group consisting of aluminum formate, iron(II) acetate, iron(II) carbonate, iron(II) formate, tin(II) formate, magnesium formate, manganese(III) formate, and cobalt(II) oxalate,
(ii) esters of organic acids, wherein the organic acids have 1-4 carbon atoms, and
(iii) carbonyl complexes.
2. The metal paste according to claim 1 , wherein the at least one sintering agent is selected from esters of the group comprising methyl formate, ethyl formate, propyl formate, and butyl formate.
3. The metal paste according to claim 1 , wherein the at least one sintering agent is selected from carbonyl complexes of the group comprising metal carbonyls.
4. The metal paste according to claim 3 , wherein the metal carbonyl is an iron carbonyl.
5. The metal paste according to claim 1 , wherein the at least one organic compound is selected from the group comprising free fatty acids, fatty acid salts, and fatty acid esters, each of which has 8-24 carbon atoms.
6. The metal paste according to one of claim 1 , wherein a molar ratio of the at least one sintering agent to the at least one organic compound contained in the coating lies in a range of 1:1 to 150:1.
7. A method for joining at least two components, the method comprising:
(a) providing a sandwich arrangement having at least:
(a1) a first component,
(a2) a second component, and
(a3) a metal paste located between the first component and the second component; and
(b) sintering the sandwich arrangement, wherein the metal paste comprises:
(A) 75-90 weight percent of at least one metal present in a form of particles having a coating containing at least one organic compound,
(B) 0.1-12 weight percent of at least one metal precursor;
(C) 6-20 weight percent of at least one solvent; and
(D) 0.1-15 weight percent of at least one sintering agent selected from the group consisting of:
(i) salts of organic acids, selected from the group consisting of aluminum formate, iron(II) acetate, iron(II) carbonate, iron(II) formate, tin(II) formate, magnesium formate, manganese(III) formate, and cobalt(II) oxalate,
(ii) esters of organic acids, wherein the organic acids have 1-4 carbon atoms, and
(iii) carbonyl complexes.
8. The method according to claim 7 , wherein the sintering takes place at a temperature of less than 200° C.
9. The method according to claim 7 , wherein each of the first and second components comprises at least one metallization layer.
10. A sintering paste consisting essentially of:
(A) 75-90 weight percent of silver particles having a coating containing at least one organic compound;
(B) 0.1-12 weight percent of at least one metal precursor selected from the group consisting of silver carbonate, silver(I) oxide and silver(II) oxide;
(C) 6-20 weight percent of at least one solvent; and
(D) 0.1-15 weight percent of at least one sintering agent consisting of aluminum