Method for producing high-purity tungsten powder
View Patent ↗Provided is a method for producing a high-purity tungsten powder having a phosphorus content of less than 1 wtppm; wherein an ammonium tungstate solution containing 1 wtppm or more of phosphorus as an impurity in terms of the inclusion in tungsten is used as a starting material, this solution is neutralized with hydrochloric acid at a temperature of 50° C. or less to adjust the pH at 4 or more and less than 7 so as to precipitate ammonium paratungstate undecahydrate crystals, the resulting solution is heated to 70 to 90° C. and filtered in a high-temperature state so as to obtain ammonium paratungstate pentahydrate crystals, the obtained crystals are calcined so as to form a tungsten oxide, and the tungsten oxide is subject to hydrogen reduction so as to obtain a high-purity tungsten powder. Additionally provided is a method for producing a high-purity tungsten powder having a phosphorus content of 0.4 wtppm or less; wherein the ammonium tungstate solution is neutralized with hydrochloric acid to adjust the pH at 4 or more and 6 or less, and this solution is subject to the same procedure as described above so as to obtain a high-purity tungsten powder. Consequently, the phosphorus content can be efficiently reduced.
1. A method for producing a high-purity tungsten powder having a phosphorus content of less than 1 wtppm; wherein an ammonium tungstate solution is used as a starting material and neutralized with hydrochloric acid at a temperature of 50° C. or less to adjust the pH at 4 or more and less than 7 so as to precipitate ammonium paratungstate undecahydrate crystals, the resulting solution is heated to 70 to 90° C. and filtered while at a temperature of 70 to 90° C. so as to obtain ammonium paratungstate pentahydrate crystals, the obtained crystals are calcined so as to form a tungsten oxide, and the tungsten oxide is subject to hydrogen reduction so as to obtain a high-purity tungsten powder.
2. The method according to claim 1 , wherein the ammonium tungstate solution used as the starting material has a content of phosphorus of 1 wtppm or more.
3. The method according to claim 1 , wherein the ammonium tungstate solution used as the starting material contains phosphorus in an amount of 1 wtppm or more as a content assuming the phosphorus is in tungsten metal.
4. A method for producing a high-purity tungsten powder having a phosphorus content of 0.4 wtppm or less; wherein an ammonium tungstate solution is used as a starting material and neutralized with hydrochloric acid at a temperature of 50° C. or less to adjust the pH at 4 or more and 6 or less so as to precipitate ammonium paratungstate undecahydrate crystals, the resulting solution is heated to 70 to 90° C. and filtered while at a temperature of 70 to 90° C. so as to obtain ammonium paratungstate pentahydrate crystals, the obtained crystals are calcined so as to form a tungsten oxide, and the tungsten oxide is subject to hydrogen reduction so as to obtain a high-purity tungsten powder.