Luminescent particles, methods and light emitting devices including the same
View Patent ↗A luminescent particle includes an interior portion of the luminescent particle comprising a luminescent compound that reacts with atmospherically present components and a passivating layer on an outer surface of the luminescent particle that is operable to inhibit the reaction between the luminescent compound and the atmospherically present components.
1. A luminescent particle comprising:
an interior portion comprising a luminescent compound comprising Ca 1-x-y Sr x Eu y AlSiN 3 , where 0≦x<1 and 0<y<1; and
a passivating region proximate an outer surface of the interior portion and operable to inhibit reactions involving the luminescent compound,
wherein the passivating region comprises nitrogen, the nitrogen being present at a reduced percentage compared to the interior portion of the luminescent particle.
2. The luminescent particle of claim 1 , wherein the passivating region comprises an oxide.
3. The luminescent particle of claim 1 , wherein the passivating region comprises a greater percentage of oxygen than the interior portion of the luminescent particle.
4. The luminescent particle of claim 1 comprising a color shift of about 0.003 or less after 504 hours in a high humidity and high temperature environment.
5. The luminescent particle of claim 4 wherein the color shift is about 0.001 after 504 hours.
6. A light emitting device comprising:
the luminescent particle of claim 1 ; and
a light emitting source.
7. The light emitting device of claim 6 , wherein the luminescent particle is dispersed within a silicone encapsulant.
8. The light emitting device of claim 7 , wherein the light emitting source emits radiation with a maximum emission at a wavelength in a range of from about 380 to about 470 nm, and wherein the luminescent particle absorbs at least some of the light emitted from the light emitting source and emits light having a maximum emission at a wavelength in a range of from about 500 to about 700 nm.
9. A luminescent particle comprising:
an interior portion comprising a luminescent compound comprising Ca 1-x-y Sr x Eu y AlSiN 3 , where 0≦x<1 and 0<y<1; and
a H 2 O-stabilized or an acid-stabilized passivating region proximate an outer surface of the interior portion and operable to inhibit reactions involving the luminescent compound.
10. The luminescent particle of claim 9 , wherein the color shift is about 0.003 or less after 504 hours.
11. The luminescent particle of claim 9 , wherein the passivating region comprises nitrogen, the nitrogen being present at a reduced percentage of nitrogen compared to the interior portion of the luminescent particle.
12. The luminescent particle of claim 11 , wherein the passivating region comprises an oxide.
13. The luminescent particle of claim 9 , wherein the passivating region is formed during exposure of the interior portion to a heated liquid medium comprising water.
14. The luminescent particle of claim 13 , wherein a thickness of the passivating region is regulated by adjusting a time duration of the exposure of the luminescent particle to the heated liquid medium.
15. A method of preparing a luminescent particle, the method comprising:
providing a luminescent particle comprising: a host compound selected from the group including Ca 1-x Sr x AlSiN 3 , Ca 2 Si 5 N 8 , Sr 2 Si 5 N 8 , Ba 2 Si 5 N 8 , Ba 2 Si 7 N 10 , BaYSi 4 N 7 , Y 5 (SiO 4 ) 3 N, Y 4 Si 2 O 7 N 2 , YSiO 2 N, Y 2 Si 3 O 3 N 4 , Ca 1.5 Si 9 Al 3 N 16 , Y 0.5 Si 9 Al 3 O 1.5 N 14.5 , CaSiN 2 , Y 2 Si 4 N 6 C, and/or Y 6 Si 11 N 20 O, wherein 0≦x<1; and at least one activator comprising Ce, Eu, Sm, Yb, Gd and/or Tb;
exposing the luminescent particle to a heated liquid medium comprising water; and
forming a passivating region on an outer surface of the luminescent particle, wherein a thickness of the passivating region is regulated by adjusting a time duration of the exposure of the luminescent particle to the heated liquid medium.
16. The method of claim 15 , wherein the heated liquid medium is heated to a boiling point thereof, and wherein the time duration of the exposure is from about 1 minute to about 60 minutes.
17. The method of claim 16 , wherein the time duration of the exposure is from about 10 minutes to about 50 minutes.
18. The method of claim 15 , wherein the heated liquid medium is heated to a boiling point thereof.
19. The method of claim 15 , wherein the heated liquid medium further comprises nitric acid at a concentration of less than about 0.1 mole/liter.
20. The method of claim 15 , wherein the luminescent particle comprises Ca 1-x-y Sr x Eu y AlSiN 3 , wherein 0<y<1.