Cu—Co—Si alloy material and manufacturing method thereof
View Patent ↗A copper alloy material suitable for materials for electronic and electrical equipments such as movable connectors having excellent bending workability and being able to show high electrical conductivity was achieved by a Cu—Co—Si alloy material containing 1.5 to 2.5 wt % of Co and 0.3 to 0.7 wt % of Si, having a Co/Si element ratio of 3.5 to 5.0, containing 3,000 to 150,000 second phase particles per mm 2 having diameters of from 0.20 μm or more to less than 1.00 μm, having a grain size of 10 μm or less, an electrical conductivity of 60% IACS or more, and good bending workability. The above alloy material contains 10 to 1,000 second phase particles per mm 2 having diameters of from 1.00 to 5.00 μm, the 0.2% yield strength may be 600 MPa or more, the temperature of hot heating performed after casting and before solution treatment is a temperature that is 45° C. or more higher than the solution treatment temperature selected below, the cooling rate from the temperature at the start of hot rolling to 600° C. is 100° C./min or lower, the solution treatment temperature is selected from (50×Co wt %+775)° C. or more to (50×Co wt %+825)° C. or less, and can be manufactured employing aging treatment after solution treatment preferably at 450 to 650° C. for 1 to 20 hours.
1. A Cu—Co—Si alloy material consisting of 1.5 to 2.5 wt % of Co and 0.3 to 0.7 wt % of Si and the balance of Cu and unavoidable impurities, having a Co/Si element ratio of 3.5 to 5.0, wherein the said alloy material contains 3,000 to 150,000 second phase particles per mm 2 having diameters of from 0.20 μm or more to less than 1.00 μm, and has an electrical conductivity EC of 60% IACS or more, a grain size of 10 μm or less, and good bending workability.
2. The Cu—Co—Si alloy material according to claim 1 , wherein the alloy material contains 10 to 1,000 second phase particles per mm 2 having diameters of from 1.00 μm or more to 5.00 μm or less.
3. The Cu—Co—Si alloy material according to claim 1 , wherein the 0.2% yield strength YS is 600 MPa or more.
4. A method of manufacturing the Cu—Co—Si alloy material according to any one of claims 1 to 3 comprising the steps of casting, hot rolling and solution treatment, wherein a temperature of hot heating performed after casting and before solution treatment is 45° C. or more higher than the solution treatment temperature selected below, a cooling rate from the temperature at the start of hot rolling to 600° C. is 100° C./min or lower, and the solution treatment temperature is selected from the range of from (50×Co wt %+775)° C. or more to (50×Co wt %+825)° C. or less.
5. The method of manufacturing the Cu-Co-Si alloy material according to claim 4 , comprising performing a step of ageing treatment after solution treatment wherein the aging treatment is conducted at 450 to 650° C. for 1 to 20 hours.