Nitride semiconductor template and light-emitting diode

1. A nitride semiconductor template, comprising:

a substrate; and

a group III nitride semiconductor layer formed on the substrate and comprising a Si-doped layer doped with Si as an uppermost layer thereof,

wherein the group III nitride semiconductor layer has a total thickness of not less than 4 μm and not more than 10 μm, and

wherein the Si-doped layer comprises a Si concentration gradient layer having a carrier concentration that gradually decreases toward an outermost surface thereof so as to be not less than 1×10 17 cm −3 and not more than 5×10 17 cm −3 at the outermost surface of the group III nitride semiconductor layer.

2. The nitride semiconductor template according to claim 1 , wherein the group III nitride semiconductor layer comprises an O-doped layer doped with O (oxygen) between the substrate and the Si-doped layer.

3. The nitride semiconductor template according to claim 2 , wherein the O-doped layer has an O-impurity concentration of not less than 1×10 16 cm −3 and not more than 3×10 19 cm −3 and an average carrier concentration in a thickness direction of not less than 8×10 17 cm −3 and not more than 1×10 18 cm −3 .

4. The nitride semiconductor template according to claim 1 , wherein the Si-doped layer comprises a high Si concentration layer having a uniform carrier concentration in a thickness direction, and

wherein the Si concentration gradient layer has a carrier concentration that gradually decreases from the high Si concentration layer toward the outermost surface.

5. The nitride semiconductor template according to claim 4 , wherein the carrier concentration of the high Si concentration layer is not less than 1×10 17 cm −3 and not more than 1×10 19 cm −3 .

6. The nitride semiconductor template according to claim 1 , wherein the substrate comprises a PSS (Patterned Sapphire Substrate) comprising a plurality of convex portions on a surface thereof.

7. The nitride semiconductor template according to claim 1 , wherein the template has a surface resistivity of not less than 10 Ω/sq and not more than 30 Ω/sq.

8. The nitride semiconductor template according to claim 1 , wherein the template has a half-value width at a (0004) plane of not more than 100 seconds by X-ray diffraction measurement.

9. A light-emitting diode, comprising:

a sapphire substrate;

an AlN buffer layer formed on the sapphire substrate;

an n-type group III nitride semiconductor layer formed on the AlN buffer layer;

a multiple quantum well layer formed on the n-type group III nitride semiconductor layer;

a p-type nitride semiconductor layer formed on the multiple quantum well layer;

an exposed portion of the n-type group III nitride semiconductor layer formed by etching from the p-type nitride semiconductor layer to the n-type group III nitride semiconductor layer;

an n-type electrode formed on the exposed portion of the n-type group III nitride semiconductor layer; and

a p-type electrode formed on the p-type nitride semiconductor layer,

wherein the n-type group III nitride semiconductor layer comprises a group III nitride semiconductor layer comprising a Si-doped layer doped with Si as an uppermost layer thereof,

wherein the group III nitride semiconductor layer has a total thickness of not less than 4 μm and not more than 10 μm, and

wherein the Si-doped layer comprises a Si concentration gradient layer having a carrier concentration that gradually decreases toward an outermost surface thereof so as to be not less than 1×10 17 cm −3 and not more than 5×10 17 cm −3 at the outermost surface of the group III nitride semiconductor layer.