IP Library Granted Patent US 8,877,568
Granted Patent B2
US 8,877,568 · App. 13/781,727 · Granted Nov 4, 2014

Methods of making logic transistors and non-volatile memory cells

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Quick Facts
Patent No.
US 8,877,568
App. No.
13/781,727
Granted
Nov 4, 2014
Kind
B2
Abstract

Methods of making a logic transistor in a logic region and an NVM cell in an NVM region of a substrate include forming a conductive layer on a gate dielectric, patterning the conductive layer over the NVM region, removing the conductive layer over the logic region, forming a dielectric layer over the NVM region, forming a protective layer over the dielectric layer, removing the dielectric layer and the protective layer from the logic region, forming a high-k dielectric layer over the logic region and a remaining portion of the protective layer, and forming a first metal layer over the high-k dielectric layer. The first metal layer, the high-k dielectric, and the remaining portion of the protective layer are removed over the NVM region. A conductive layer is deposited over the remaining portions of the dielectric layer and over the first metal layer, and the conductive layer is patterned.

Claims (50)

1. A method of making a logic transistor in a logic region of a substrate and a non-volatile memory cell in an NVM region of the substrate, comprising:

forming a gate dielectric layer on the substrate;

forming a first conductive layer on the gate dielectric;

patterning the first conductive layer over the NVM region and removing the first conductive layer over the logic region;

forming a dielectric layer over the NVM region including the first conductive layer and over the logic region;

forming a protective layer over the dielectric layer;

removing the dielectric layer and the protective layer from the logic region to leave a remaining portion of the dielectric layer and a remaining portion of the protective layer over the NVM region;

forming a high-k dielectric layer over the logic region and the remaining portion of the protective layer;

forming a first metal layer over the high-k dielectric layer;

removing the first metal layer, the high-k dielectric, and the remaining portion of the protective layer over the NVM region to leave a remaining portion of the first metal layer and a remaining portion of the high-k dielectric layer over the logic region;

forming a second conductive layer over the remaining portion of the dielectric layer and over the first metal layer; and

forming the NVM cell and the logic transistor including patterning the second conductive layer to leave a first portion of the second conductive layer over the remaining portion of the first metal layer and a second portion of the second conductive layer over the remaining portion of the dielectric layer.

2. The method of claim 1 , wherein the step of forming the first conductive layer comprises forming a first polysilicon layer and the step of forming the second conductive layer comprises forming a second polysilicon layer.

3. The method of claim 1 , wherein the step of forming the second conductive layer comprises forming a second metal layer.

4. The method of claim 3 , wherein the step of forming the second conductive layer further comprises forming a first polysilicon layer over the second metal layer.

5. The method of claim 3 , wherein the step of forming the second conductive layer is further characterized by the second metal layer being thicker than the first metal layer.

6. The method of claim 5 , wherein the step of forming the second conductive layer is further characterized by the first metal and the second metal layer having a same work function.

7. The method of claim 1 , wherein the step of forming the dielectric layer comprises forming a charge storage layer comprising a first insulating layer, a plurality of nanocrystals over the first insulating layer, and a second insulating layer around and over the plurality of nanocrystals.

8. The method of claim 1 , wherein the step of forming the NVM cell and the logic transistor further comprises patterning the remaining portion of the first conductive layer to form a floating gate.

9. The method of claim 1 , further comprising removing the gate dielectric from the logic region prior to forming the high-k dielectric.

10. A method of forming a logic transistor and a non-volatile memory cell, comprising:

forming a gate dielectric layer on the substrate;

depositing a first conductive layer over the gate dielectric layer;

patterning the first conductive layer to leave a portion of the first conductive layer;

forming a dielectric layer over the substrate after patterning the first conductive layer wherein the dielectric layer has a top insulating layer comprising silicon dioxide;

forming a silicon nitride layer over the dielectric layer;

patterning the silicon nitride layer and the dielectric layer to leave a portion of the dielectric layer and a portion of the silicon nitride layer over and extending around the portion of the first conductive layer;

depositing a high-k dielectric layer over the substrate after patterning the silicon nitride layer and the dielectric layer;

depositing a first metal layer over the high-k dielectric layer;

removing the first metal layer, the high-k dielectric layer, and the silicon nitride layer from over the dielectric layer to leave a portion of the dielectric layer and a portion of the first metal layer over the portion of the dielectric layer;

forming a second conductive layer over the substrate after removing the first metal layer, the high-k dielectric layer, and the silicon nitride layer from over the dielectric layer; and

forming the non-volatile memory cell and logic transistor including patterning the second conductive layer to leave a first portion of the second conductive layer over the portion of the first metal layer and a second portion of the second conductive layer over the portion of the dielectric layer.

11. The method of claim 10 , wherein the step of forming the first conductive layer comprises forming a first polysilicon layer and the step of forming the second conductive layer comprises depositing a second metal layer and depositing a second polysilicon layer directly on the second metal layer.

12. The method of claim 10 , wherein the step of forming the second conductive layer comprises depositing a polysilicon layer over the substrate including directly on the portion of the first metal layer and directly on the portion of the dielectric layer.

13. The method of claim 10 , wherein the step of forming the non-volatile memory comprises etching the portion of the first conductive layer to form a select gate and the step of forming the dielectric layer comprises forming a layer of nanocrystals.

14. A method of making a non-volatile memory cell and a logic transistor on a substrate, comprising:

forming a first gate dielectric comprising silicon oxide over the substrate;

forming a second gate dielectric of high-k material over the substrate spaced from the first gate dielectric;

forming a first portion of a first conductive layer over the first gate dielectric;

forming a first portion of a first metal layer on the second gate dielectric;

forming a dielectric layer over the first portion of the first conductive layer;

forming a first portion of a second metal layer over the first portion of the first metal layer;

forming a second portion of the second metal layer over the dielectric layer;

forming a first portion of a second conductive layer over the first portion of the second metal layer; and

forming a second portion of the second conductive layer over the second portion of the second metal layer.

15. The method of claim 14 , wherein the first metal layer and the second metal layer have the same work function.

16. The method of claim 14 , wherein the dielectric layer comprises a charge storage layer comprising a first insulating layer, a plurality of nanocrystals over the first insulating layer, and a second insulating layer around and over the plurality of nanocrystals.

17. The method of claim 14 , wherein the dielectric layer comprises a first oxide insulating layer, a silicon nitride insulating layer over the first oxide insulating layer, and a second oxide insulating layer over the silicon nitride insulating layer.

18. The method of claim 14 , wherein the first portion of the first conductive layer is a floating gate comprising polysilicon.

19. The method of claim 14 , wherein the second conductive layer comprises polysilicon.

Assignments (26)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
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From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
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RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
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To: NXP B.V.
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To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
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