Superhydrophobic nanostructures
Condensation can be an important process in both emerging and traditional power generation and water desalination technologies. Superhydrophobic nanostructures can promise enhanced condensation heat transfer by reducing the characteristic size of departing droplets via a surface-tension-driven mechanism. A superhydrophobic surface can include nanostructures of a metal oxide having further surface modification.
1. A superhydrophobic surface comprising:
a substrate including a substrate metal, wherein the substrate metal is copper;
an intermediate layer including a first oxide of the substrate metal on a surface of the substrate, wherein the first oxide is Cu 2 O;
a plurality of blade-like nanostructures separated from the substrate by the intermediate layer, the plurality of blade-like nanostructures including a second oxide of the substrate metal on the intermediate layer, wherein the second oxide is CuO grown on the Cu 2 O;
a metal coating on the plurality of blade-like nanostructures; and
a surface modifying layer including a fluorinated compound on at least a portion of the metal coating on the plurality of blade-like nanostructures, wherein the surface modifying layer includes a self-assembled monolayer including the fluorinated compound on the metal coating, wherein the plurality of blade-like nanostructures beneath coalescing droplets reduce droplet adhesion to the substrate by minimizing the solid fraction and break symmetry of coalesced droplets, whereby the droplets accelerate and depart perpendicular to the surface, the plurality of blade-like nanostructures having a morphology and a height dimension of ≤10 nm of blade-like morphology that ensures nucleation within the structures and a majority portion of droplet distribution is below 10 μm at supersaturations, S≤1.5.
2. The surface of claim 1 , wherein the surface modifying layer includes a thiol on a surface of the nanostructures.
3. The surface of claim 2 , wherein the thiol is an alkyl thiol.
4. The surface of claim 3 , wherein the alkyl thiol is a fluorinated alkyl thiol.
5. The surface of claim 1 , wherein the surface modifying layer includes a silane on a surface of the nanostructures.
6. The surface of claim 5 , wherein the silane is an alkyl silane.
7. The surface of claim 6 , wherein the alkyl silane is a fluorinated alkyl silane.
8. The surface of claim 1 , wherein a ratio of a coalescence length between nearest neighbor nucleation sites to a spacing between nanostructures is 1.6.