Method and composition for chemical mechanical planarization of a metal
View Patent ↗A composition and associated method for chemical mechanical planarization of a metal-containing substrate (e.g., a copper substrate) are described herein which afford high and tunable rates of metal removal as well as low within a wafer non-uniformity values and low residue levels remaining after polishing.
1. A method for chemical mechanical planarization of a surface having at least one feature thereon comprising a metal, said method comprising the steps of:
A) placing a substrate having the surface having the at least one feature thereon comprising the metal in contact with a polishing pad;
B) delivering a polishing slurry comprising:
a) an abrasive ranging from 10 ppm to about 100 ppm;
b) an ionic liquid compound; and
c) an oxidizing agent;
and
C) polishing the substrate with the polishing slurry, wherein the polishing comprises polishing metal;
wherein the ionic liquid compound comprises an imidazolium salt having the general molecular structure:
where R 1 is selected from H, normal-alkyl, branched alkyl, alkoxy, and alkyl thioether groups; R 2 is selected from H, normal-alkyl, branched alkyl, alkoxy, and alkyl thioether groups; R 3 is selected from normal-alkyl, branched alkyl, alkoxy, alkyl thioether, cyclic and non-aromatic rings, heterocyclic non-aromatic rings and other suitable organic groups; and anion is selected from a univalent and a multivalent anion.
2. The method of claim 1 wherein the ionic liquid compound is present in the slurry in an amount that ranges from about 5 ppm to about 5000 ppm.
3. The method of claim 1 wherein the anion is selected from the group consisting of sulfate, bisulfate, nitrate, trifluoroacetate, and fluorosulfonate.
4. The method of claim 1 wherein the metal is copper.
5. The method of claim 1 wherein the oxidizing agent is selected from the group consisting of hydrogen peroxide, periodic acid, potassium iodate, potassium permanganate, ammonium persulfate, ammonium molybdate, ferric nitrate, nitric acid, potassium nitrate, ammonia, amine compounds, and mixtures thereof.
6. The method of claim 5 wherein the oxidizing agent comprises hydrogen peroxide.
7. The method of claim 1 wherein the abrasive is colloidal silica.
8. The method of claim 1 wherein the polishing slurry has a pH from about 4 to about 10.
9. The method of claim 1 wherein the polishing slurry has a pH from about 5 to about 8.