Patterning process and resist composition
A pattern is formed by coating a first positive resist composition comprising a copolymer comprising lactone-containing recurring units, acid labile group-containing recurring units and carbamate-containing recurring units, and a photoacid generator onto a substrate to form a first resist film, patternwise exposure, PEB, and development to form a first resist pattern, heating the first resist pattern for inactivation to acid, coating a second positive resist composition comprising a C 3 -C 8 alcohol and an optional C 6 -C 12 ether onto the first resist pattern-bearing substrate to form a second resist film, patternwise exposure, PEB, and development to form a second resist pattern.
1. A resist composition comprising a base resin, a photoacid generator, and an organic solvent, wherein
the base resin is a copolymer comprising recurring units having lactone as an adhesive group, recurring units having an acid labile group, and recurring units selected from the group consisting of the following recurring units: