IP Library Granted Patent US 9,275,864
Granted Patent B2
US 9,275,864 · App. 13/973,433 · Granted Mar 1, 2016

Method to form a polysilicon nanocrystal thin film storage bitcell within a high k metal gate platform technology using a gate last process to form transistor gates

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,275,864
App. No.
13/973,433
Granted
Mar 1, 2016
Kind
B2
Abstract

A process integration is disclosed for fabricating non-volatile memory (NVM) cells ( 105 - 109, 113 - 115 ) on a first flash cell substrate area ( 111 ) which are encapsulated in one or more planar dielectric layers ( 116 ) prior to forming an elevated substrate ( 117 ) on a second CMOS transistor area ( 112 ) on which high-k metal gate electrodes ( 119 - 120, 122 - 126, 132, 134 ) are formed using a gate-last HKMG CMOS process flow without interfering with the operation or reliability of the NVM cells.

Claims (33)

1. A semiconductor fabrication process comprising:

forming a plurality of nonvolatile memory cell gate structures over one or more first substrate areas of a wafer, each nonvolatile memory cell gate structure comprising one or more polysilicon layers;

forming a first dielectric layer over the wafer to protect at least the one or more polysilicon layers in each nonvolatile memory cell gate structure;

epitaxially growing an elevated substrate in one or more openings formed in the first dielectric layer over one or more second substrate areas of the wafer;

forming a plurality of sacrificial transistor gate structures over the elevated substrate while protecting the one or more polysilicon layers in each nonvolatile memory cell gate structure with the first dielectric layer;

forming a second dielectric layer on the first dielectric layer, where the second dielectric layer has a substantially flat upper surface which exposes an upper surface of the plurality of sacrificial transistor gate structures;

selectively removing at least part of the plurality of sacrificial transistor gate structures to form a plurality of gate electrode openings in the second dielectric layer without removing the plurality of non-volatile memory cell gate structures;

forming a plurality of high-k metal gate electrodes in the plurality of gate electrode openings which are elevated above the plurality of nonvolatile memory cell gate structures.

2. The semiconductor fabrication process of claim 1 , where forming the plurality of nonvolatile memory cell gate structures comprises forming a plurality of split-gate bitcells, each comprising a polysilicon control gate formed on a nanocrystal layer that at least partially overlaps a polysilicon select gate.

3. The semiconductor fabrication process of claim 1 , where forming the plurality of nonvolatile memory cell gate structures comprises forming a plurality of split-gate bitcells, each comprising a spacer control gate and a nanocrystal layer formed adjacent to a sidewall of a polysilicon select gate.

4. The semiconductor fabrication process of claim 1 , where forming the plurality of nonvolatile memory cell gate structures comprises forming a plurality of split-gate bitcells, each comprising a polished and recessed control gate formed adjacent to a charge storage layer comprising a plurality of discrete storage elements, where the charge storage layer separates the polished and recessed control gate from an adjacent polysilicon select gate.

5. The semiconductor fabrication process of claim 1 , where forming the plurality of nonvolatile memory cell gate structures comprises forming a plurality of split-gate bitcells, each comprising an in-laid control gate formed adjacent to a nanocrystal layer which separates the in-laid control gate from an adjacent polysilicon select gate.

6. The semiconductor fabrication process of claim 1 , where forming the first dielectric layer comprises:

depositing a conformal oxide layer over the wafer to cover the plurality of non-volatile memory cell gate structures, and

planarizing the conformal oxide layer with a chemical mechanical polish process to form a substantially flat upper surface to protect at least the one or more polysilicon layers in each nonvolatile memory cell gate structure.

7. The semiconductor fabrication process of claim 1 , where epitaxially growing the elevated substrate comprises:

patterning one or more openings in the first dielectric layer to expose one or more second substrate areas of the wafer while leaving other portions of the first dielectric layer over the plurality of nonvolatile memory cell gate structures;

selectively growing an epitaxial semiconductor layer in the one or more openings in the first dielectric layer, and

polishing the epitaxial semiconductor layer to form the elevated substrate having an elevated substrate surface which is at least as high as a top surface of the plurality of nonvolatile memory cell gate structures.

8. The semiconductor fabrication process of claim 1 , where forming the plurality of high-k metal gate electrodes comprises:

forming a metal layer in the plurality of gate electrode openings; and

polishing the metal layer down to be substantially coplanar with the second dielectric layer to define the plurality of high-k metal gate electrodes which are elevated above the plurality of nonvolatile memory cell gate structures.

9. The semiconductor fabrication process of claim 1 , where selectively removing at least part of the plurality of sacrificial transistor gate structures comprises:

applying one or more poly etch processes to remove one or more polysilicon layers from the plurality of sacrificial transistor gate structures without removing the one or more polysilicon layers from the plurality of non-volatile memory cell gate structures.

10. The semiconductor fabrication process of claim 1 , where forming the plurality of sacrificial transistor gate structures comprises:

forming one or more high-k dielectric layers over the elevated substrate using a dielectric material which has a dielectric constant value of 7.0 or greater while protecting the one or more polysilicon layers in each nonvolatile memory cell gate structure;

depositing one or more polysilicon gate electrode layers over the one or more high-k dielectric layers while protecting the one or more polysilicon layers in each nonvolatile memory cell gate structure; and

patterning and etching the one or more polysilicon gate electrode layers and one or more high-k dielectric layers formed over the elevated substrate to form the plurality of sacrificial transistor gate structures.

11. The semiconductor fabrication process of claim 10 , where selectively removing at least part of the plurality of sacrificial transistor gate structures comprises applying one or more poly etch processes to remove the one or more polysilicon gate electrode layers to expose an underlying high-k gate dielectric layer in the plurality of gate electrode openings in the second dielectric layer.

12. The semiconductor fabrication process of claim 11 , where forming the plurality of high-k metal gate electrodes comprises:

depositing a first metal interface layer in the plurality of gate electrode openings to cover an underlying high-k dielectric layer;

depositing one or more metal gate electrode layers in the plurality of gate electrode openings to cover the first metal interface layer; and

applying one or more polish and/or etch steps to form a plurality of planarized high-k metal-gate electrodes that are substantially coplanar with the second dielectric layer.

Assignments (26)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0387 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051145/0184 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050745/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 050744/0097 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042985/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 042762/0145 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
Reel/Frame 041144/0363 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT PCT NUMBERS IB2013000664, US2013051970, US201305935 PREVIOUSLY RECORDED AT REEL: 037444 FRAME: 0787. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Oct 17, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 040450/0715 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12092129 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Jul 14, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039361/0212 →
SUPPLEMENT TO THE SECURITY AGREEMENT Recorded Jun 16, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 039138/0001 →
SECURITY AGREEMENT SUPPLEMENT Recorded Mar 7, 2016
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 038017/0058 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 5, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037444/0787 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0874 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Nov 13, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031627/0201 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Nov 13, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 031627/0158 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 22, 2013
From: PERERA, ASANGA H.; YATER, JANE A.; HONG, CHEONG MIN; KANG, SUNG-TAEG
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 031063/0720 →