Cleaning composition and method for cleaning a semiconductor device substrate after chemical mechanical polishing
View Patent ↗An aqueous cleaning composition and method for post-CMP cleaning of a semiconductor device which contains a copper interconnect wherein the cleaning composition contains (A) N,N,N′-trimethyl-N′-(2-hydroxyethyl)ethylenediamine; and (B) at least one corrosion inhibitor selected from the group consisting essentially of uric acid, xanthine, theophyline, paraxanthine, theobromine, caffeine, guanine, hypoxanthine, adenine, and combinations thereof.
1. An alkaline post-CMP aqueous cleaning composition for semiconductor devices having a copper interconnect thereon comprising at least:
(A) from about 0.1 wt % to about 20 wt % N,N,N′-trimethyl-N′-(2-hydroxyethyl)ethylenediamine; and
(B) from about 0.1 wt % to about 10 wt % of at least one corrosion inhibitor selected from the group consisting essentially of xanthine, theophyline, paraxanthine, theobromine, caffeine, guanine, hypoxanthine, adenine, and combinations thereof.
2. The cleaning composition of claim 1 further comprising from 0.01 wt % up to 20 wt % of tris(2-hydroxyethyl)methylammonium hydroxide.
3. The cleaning composition of claim 2 wherein said corrosion inhibitor is xanthine.
4. The cleaning composition of claim 3 wherein the pH is in the range of from about 8.5 to 13.