IP Library Granted Patent US 10,723,955
Granted Patent B2
US 10,723,955 · App. 14/033,134 · Granted Jul 28, 2020

Fuel composition for a diesel engine

Inventors: Juha Jakkula (Kerava, FI); Pekka Aalto (Porvoo, FI); Vesa Niemi (Porvoo, FI); Ulla Kiiski (Hamari, FI); Jouko Nikkonen (Hamari, FI); Seppo Mikkonen (Porvoo, FI); Outi Piirainen (Helsinki, FI)
Assignee: Neste OYJ
C10G3/50C10L1/08C10L1/32Y02P30/20
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Quick Facts
Patent No.
US 10,723,955
App. No.
14/033,134
Granted
Jul 28, 2020
Kind
B2
Abstract

The invention is directed to a fuel composition for diesel engines. The fuel composition comprises 0.1-99% by weight of a component or a mixture of components produced from biological raw material originating from plants and/or animals and/or fish. The fuel composition comprises 0-20% of components containing oxygen. Both components are mixed with diesel components based on crude oil and/or fractions from Fischer-Tropsch process.

Claims (41)

1. A diesel fuel composition comprising at least one isomerized biological component produced by a process comprising

(1) providing a feed stream of fatty acids having saturated or unsaturated C6-C24 hydrocarbon chains, fatty acid esters having saturated or unsaturated C6-C24 hydrocarbon chains, or both, derived from at least one biological raw material;

(2) hydrodeoxygenating the feed stream to form n-paraffins having carbon numbers in the C6-C24 range; and

(3) isomerizing the n-paraffins to form an isomerized biological component comprising isoparaffins,

wherein the isomerized biological component is suitable for use as a diesel fuel for a diesel engine, has a cetane number higher than 60, a turbidity point lower than −30° C., and is free of aromates.

2. A diesel fuel composition according to claim 1 , wherein the isomerized biological component has a density less than crude oil based conventional diesel fuel.

3. A diesel fuel composition according to claim 1 , wherein the isomerized biological component has a density less than rapeseed oil methyl ester based fuel.

4. A diesel fuel composition according to claim 1 , wherein the biological raw material is chosen from animal-based material, plant-based material, fish-based material and mixtures thereof.

5. A diesel fuel composition according to claim 1 , wherein the biological raw material is chosen from vegetable oils, animal fats, fish oils, and mixtures thereof.

6. A diesel fuel composition according to claim 1 , wherein the biological raw material is chosen from animal-based fats, fats contained in milk, recycled fats of the food industry, wood-based fats or oils; non-wood, plant-based fats or oils; fats contained in plants bred by means of gene manipulation; fish oils; and mixtures thereof.

7. A diesel fuel composition according to claim 1 , wherein the diesel fuel composition leaves no impurity residues.

8. A diesel fuel composition comprising at least one hydrodeoxygenated and isomerized biological component wherein the hydrodeoxygenated and isomerized biological component is suitable for use as a diesel fuel for a diesel engine, has a cetane number higher than 60, a turbidity point lower than −30° C., is free of aromates, and is produced by hydrodeoxygenating and isomerizing a feed stream of fatty acids having saturated or unsaturated C6-C24 hydrocarbon chains, fatty acid esters having saturated or unsaturated C6-C24 hydrocarbon chains, or both, derived from at least one biological raw material.

9. A diesel fuel composition according to claim 8 , wherein the hydrodeoxygenated and isomerized biological component has a density less than crude oil based conventional diesel fuel.

10. A diesel fuel composition according to claim 8 , wherein the hydrodeoxygenated and isomerized biological component has a density less than rapeseed oil methyl ester based fuel.

11. A diesel fuel composition according to claim 8 , wherein the biological raw material is chosen from animal-based material, plant-based material, fish-based material and mixtures thereof.

12. A diesel fuel composition according to claim 8 , wherein the biological raw material is chosen from vegetable oils, animal fats, fish oils, and mixtures thereof.

13. A diesel fuel composition according to claim 8 , wherein the biological raw material is chosen from animal-based fats; fats contained in milk; recycled fats of the food industry; wood-based fats or oils; non-wood, plant-based fats or oils; fats contained in plants bred by means of gene manipulation; fish oils; and mixtures thereof.

14. A diesel fuel composition according to claim 8 , wherein the fuel composition leaves no impurity residues.

15. An isomerized biological component for diesel fuel produced by a process comprising

(1) providing a feed stream of fatty acids having saturated or unsaturated C6-C24 hydrocarbon chains, fatty acid esters having saturated or unsaturated C6-C24 hydrocarbon chains, or both, derived from at least one biological raw material;

(2) hydrodeoxygenating the feed stream to form n-paraffins having carbon numbers in the C6-C24 range; and

(3) isomerizing the n-paraffins to form an isomerized biological component comprising isoparaffins,

wherein the at least one biological raw material is chosen from animal-based material, plant-based material, fish-based material or mixtures thereof,

and wherein the isomerized biological component is suitable for use as a diesel fuel for a diesel engine, has a cetane number higher than 60, a turbidity point lower than −30° C., is free of aromates, has a density less than rapeseed oil methyl ester based fuel, and leaves no impurity residues.

16. An isomerized biological component according to claim 15 , having a density less than crude oil based conventional diesel fuel.

17. An isomerized biological component for diesel fuel produced by a process comprising

(1) providing a feed stream of fatty acids having saturated or unsaturated C6-C24 hydrocarbon chains, fatty acid esters having saturated or unsaturated C6-C24 hydrocarbon chains, or both, derived from at least one biological raw material;

(2) hydrodeoxygenating the feed stream to form n-paraffins having carbon numbers in the C6-C24 range; and

(3) isomerizing the n-paraffins to form an isomerized biological component comprising isoparaffins,

wherein the isomerized biological component is suitable for use as a diesel fuel for a diesel engine has a cetane number higher than 60 and a turbidity point lower than −30° C.

18. An isomerized biological component according to claim 17 , wherein the isomerized biological component is free of aromates.

19. An isomerized biological component according to claim 17 , wherein the isomerized biological component has a density less than crude oil based conventional diesel fuel.

20. An isomerized biological component according to claim 17 , wherein the isomerized biological component has a density less than rapeseed oil methyl ester based fuel.

21. An isomerized biological component according to claim 17 , wherein the biological raw material is chosen from animal-based material, plant-based material, fish-based material and mixtures thereof.

22. An isomerized biological component according to claim 17 , wherein the biological raw material is chosen from vegetable oils, animal fats, fish oils, and mixtures thereof.

23. An isomerized biological component according to claim 17 , wherein the biological raw material is chosen from animal-based fats; fats contained in milk; recycled fats of the food industry; wood-based fats or oils; non-wood, plant-based fats or oils; fats contained in plants bred by means of gene manipulation; fish oils; and mixtures thereof.

24. An isomerized biological component according to claim 17 , wherein the isomerized biological component leaves no impurity residues.

25. A diesel fuel composition according to claim 1 , comprising a measurable amount of 14 C.

26. A diesel fuel composition according to claim 8 , comprising a measurable amount of 14 C.

27. An isomerized biological component according to claim 15 , comprising a measurable amount of 14 C.

28. An isomerized biological component according to claim 17 , comprising a measurable amount of 14 C.

Assignments (1)
CHANGE OF NAME Recorded May 29, 2020
From: NESTE OIL OYJ
To: NESTE OYJ
Reel/Frame 052796/0835 →
Continuity (6)
Continuation 13480562 · May 25, 2012
Continuation 12354634 · Jan 15, 2009
Division 11852096 · Sep 7, 2007
Continuation 10655798 · Sep 5, 2003
Provisional Application 60408302 · Sep 6, 2002
Related Publication 20140024865A1 · Jan 23, 2014