IP Library Granted Patent US 9,136,129
Granted Patent B2
US 9,136,129 · App. 14/041,591 · Granted Sep 15, 2015

Non-volatile memory (NVM) and high-k and metal gate integration using gate-last methodology

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Quick Facts
Patent No.
US 9,136,129
App. No.
14/041,591
Granted
Sep 15, 2015
Kind
B2
Abstract

A method of making a semiconductor structure uses a substrate and includes a logic device in a logic region and a non-volatile memory (NVM) device in an NVM region. An NVM structure is formed in the NVM region. The NVM structure includes a control gate structure and a select gate structure. A protective layer is formed over the NVM structure. A gate dielectric layer is formed over the substrate in the logic region. The gate dielectric layer includes a high-k dielectric. A sacrificial gate is formed over the gate dielectric layer in the logic region. A first dielectric layer is formed around the sacrificial gate. Chemical mechanical polishing is performed on the NVM region and the logic region after forming the first dielectric layer. The sacrificial gate is replaced with a metal gate structure.

Claims (46)

1. A method of making a semiconductor structure using a substrate, wherein the semiconductor structure comprises a logic device in a logic region and a non-volatile memory (NVM) device in an NVM region, comprising:

forming an NVM structure in the NVM region, wherein the NVM structure comprises a control gate structure and a select gate structure;

forming a protective layer over the NVM structure;

forming a gate dielectric layer over the substrate in the logic region after forming the protective layer over the NVM structure, wherein the gate dielectric layer comprises a high-k dielectric;

forming a sacrificial gate over the gate dielectric layer in the logic region;

forming a first dielectric layer around the sacrificial gate; and

performing chemical mechanical polishing on the NVM region and the logic region after forming the first dielectric layer; and

replacing the sacrificial gate with a metal gate structure.

2. The method of claim 1 wherein the forming the NVM structure is further characterized by the select gate having a top surface and the control gate structure having an upper portion overlapping a portion of the top surface of the select gate.

3. The method of claim 2 , wherein performing chemical mechanical polishing includes depositing a layer of polysilicon over the top of the control gate and then removing the upper portion of the control gate that overlaps the portion of the top surface of the select gate.

4. The method of claim 3 , further comprising performing the source/drain implants in the NVM region and the logic region prior to forming the first dielectric layer.

5. The method of claim 4 , further comprising forming a first sidewall spacer around the sacrificial gate after forming the first sidewall spacer and before forming the first dielectric layer.

6. The method of claim 5 , wherein the replacing the sacrificial gate comprises:

removing the sacrificial gate to leave an opening over the gate dielectric layer; and

forming a work function metal in the opening.

7. The method of claim 6 , wherein the replacing the sacrificial gate further comprises forming a metal gate on the work function metal.

8. The method of claim 1 wherein the forming the NVM structure is further characterized by forming a capping layer on the top surface of the select gate.

9. The method of claim 8 , wherein the forming the capping layer is characterized by the capping layer comprising nitride.

10. The method of claim 9 , wherein the performing the chemical mechanical polishing is further characterized as leaving at least a portion of the capping layer over the select gate structure.

11. The method of claim 1 , wherein the protective layer comprises a first oxide layer, a nitride layer on the first oxide layer, and a second oxide layer on the nitride layer.

12. The method of claim 11 , further comprising:

removing the second oxide layer and the nitride layer; and

anisotropically etching the first oxide layer to form a sidewall spacer around the select gate structure and the control gate structure.

13. The method of claim 12 wherein the forming the NVM structure is further characterized by the control gate structure and the select gate structure comprising polysilicon.

14. A method of making a semiconductor structure using a substrate, wherein the semiconductor structure comprises a logic device in a logic region and a non-volatile memory (NVM) device in an NVM region, comprising:

forming an NVM structure in the NVM region, wherein the NVM structure comprises a control gate structure and a select gate structure in which the control gate structure has an upper portion extending over a portion of a top surface of the select gate structure;

forming a replacement gate structure in the logic region having a sacrificial gate;

performing chemical mechanical polishing on the logic region and the NVM region which removes the upper portion of the control gate structure; and

replacing the sacrificial gate with a metal gate structure.

15. The method of claim 14 , wherein the forming the replacement gate structure comprises forming a gate dielectric comprising a high-k dielectric.

16. The method of claim 15 , wherein the forming the replacement gate structure:

is further characterized by the sacrificial gate comprising polysilicon; and

further comprises forming a barrier layer on the gate dielectric.

17. The method of claim 16 wherein the replacing the sacrificial gate is further characterized by the metal gate structure comprising:

a work function metal on the barrier layer; and

a metal gate on the work function metal.

18. The method of claim 14 further comprising forming a protection layer over the NVM region after forming the NVM structure and before forming the replacement gate structure.

19. The method of claim 18 further comprising:

forming a capping layer over the select gate prior to forming the protection layer; and

removing a portion of the capping layer during the performing the chemical mechanical polishing.

20. A method of making a semiconductor structure using a substrate, wherein the semiconductor structure comprises a logic device in a logic region and a non-volatile memory (NVM) device in an NVM region, comprising:

forming an NVM structure in the NVM region, wherein the NVM structure comprises a control gate structure and a select gate structure in which the control gate structure has an upper portion extending over a portion of a top surface of the select gate structure and the select gate structure has a nitride capping layer on its top surface;

forming a protection layer over the NVM region

forming a replacement gate structure in the logic region having a high-k dielectric, a barrier layer on the high-k dielectric, and a sacrificial gate;

performing chemical mechanical polishing on the logic region and the NVM region which removes the upper portion of the control gate structure and leaves a portion of the nitride capping layer on the top surface of the select gate structure; and

replacing the sacrificial gate with a work function metal on the barrier layer and a metal gate on the barrier layer.

Assignments (26)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042985 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051029/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 039361 FRAME 0212. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 051030/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12298143 PREVIOUSLY RECORDED ON REEL 042762 FRAME 0145. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded Oct 22, 2019
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
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RELEASE OF SECURITY INTEREST Recorded Sep 10, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
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CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
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To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
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From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 12681366 PREVIOUSLY RECORDED ON REEL 038017 FRAME 0058. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT SUPPLEMENT. Recorded May 9, 2017
From: NXP B.V.
To: MORGAN STANLEY SENIOR FUNDING, INC.
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CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
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MERGER Recorded Jan 3, 2017
From: FREESCALE SEMICONDUCTOR, INC.
To: NXP USA, INC.
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RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
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CORRECTIVE ASSIGNMENT TO CORRECT THE INCORRECT PCT NUMBERS IB2013000664, US2013051970, US201305935 PREVIOUSLY RECORDED AT REEL: 037444 FRAME: 0787. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Oct 17, 2016
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To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
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From: NXP B.V.
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