Adhesive film, multilayer printed wiring board using adhesive film, and method for manufacturing multilayer printed wiring board
An adhesive film according to the present invention includes a resin composition layer (layer A) for an interlayer insulating layer, a thermosetting resin composition layer (layer B), and a support film (layer C), and the layer C, the layer A, and the layer B are sequentially arranged in this order. The layer A is a resin composition which contains a thermosetting resin (a1) and an inorganic filler (b1) having a specific surface area of 20 m 2 /g or more, and the mass ratio of the thermosetting resin (a1) to the inorganic filler (b1) is within the range from 30:1 to 2:1. The layer B contains a thermosetting resin composition which is in a solid state at a temperature lower than 40° C. but melts at a temperature of 40° C. or higher but lower than 140° C. Consequently, the adhesive film according to the present invention can solve problems in a laser process and a desmear removal process following the laser process and can form a conductor layer which has a high adhesion strength even on an interlayer insulating layer having a smooth surface-roughened state.
1. An adhesive film comprising a resin composition layer (layer A) for an interlayer insulating layer, a thermosetting resin composition layer (layer B), and a support film (layer C), wherein
the layer C, the layer A, and the layer B are sequentially arranged in this order,
the layer A is a resin composition which contains a thermosetting resin (a1) and an inorganic filler (b1) having a specific surface area of 80 m 2 /g or more,
the mass ratio of the thermosetting resin (a1) to the inorganic filler (b1) is within the range from 30:1 to 2:1,
the layer B contains a thermosetting resin composition which is in a solid state at a temperature lower than 40° C. but is melted at a temperature of 40° C. or higher but lower than 140° C., and the layer B has a thickness from 10 to 100 μm, and the layer A has a composition different than a composition of the layer B.
2. The adhesive film according to claim 1 , wherein the inorganic filler (b1) in the layer A is fumed silica and/or colloidal silica.
3. The adhesive film according to claim 2 , wherein the inorganic filler (b1) in the layer A is a silica filler which has a spherical shape and is surface-treated so that the filler is uniformly dispersed in a solvent and/or an organic resin.
4. The adhesive film according to claim 1 , wherein the layer A is a resin composition further containing a heat-resistant resin (c1), which is at least one resin selected from a polyamide resin, a polyamideimide resin, and a polyimide resin, and dissolves in an organic solvent, and the mass ratio of the thermosetting resin (a1) to the heat-resistant resin (c1) is within the range from 20:1 to 3:1.
5. The adhesive film according to claim 1 , wherein the layer A is a resin composition which further contains a crosslinked organic filler (d1) having an average primary particle diameter of 1 μm or less in an amount such that the mass ratio of the thermosetting resin (a1) to the crosslinked organic filler (d1) is within the range from 20:1 to 3:1.
6. The adhesive film according to claim 1 , wherein the layer B is a resin composition which contains an inorganic filler (b2) in an amount of 10 to 85% by mass.
7. The adhesive film according to claim 6 , wherein the layer B contains spherical silica having an average particle diameter of 1μm or less as the inorganic filler (b2) in an amount of 50% by mass or more of the total inorganic filler in the layer B.
8. The adhesive film according to claim 1 , wherein a polyfunctional epoxy resin is contained as the thermosetting resin (a1) in the layer A.
9. The adhesive film according to claim 1 , wherein a thermosetting resin (a2) is contained in the layer B, and said thermosetting resin (a2) is a polyfunctional epoxy resin.
10. The adhesive film according to claim 1 , wherein the thickness of the layer A is from 1 to 15 μm, and the thickness of the layer C is from 10 to 150 μm.
11. The adhesive film according to claim 1 , wherein a protective film is provided on an outer surface of the layer B.
12. The adhesive film according to claim 1 , wherein the layer A and the layer B are formed separately.