Cleaning method, method of manufacturing semiconductor device, substrate processing apparatus, and recording medium

1. A method for cleaning an interior of a process chamber, the method comprising:

performing a set a first predetermined number of times, wherein an iteration of the set includes:

supplying a precursor gas and a first catalytic gas to a substrate in the process chamber, wherein the precursor gas contains silicon, carbon and a hydrogen element, and the precursor gas has an Si—C bonding,

supplying an oxidizing gas and a second catalytic gas to the substrate to form an oxide film containing carbon; and

performing a cycle a second predetermined number of times, wherein an iteration of the cycle comprises:

supplying a modifying gas into the process chamber to modify deposits including the oxide film containing carbon; and

supplying an etching gas into the process chamber to remove the modified deposits through a thermochemical reaction.

2. The method of claim 1 , wherein, in the act of supplying the modifying gas, at least a portion of carbon contained in the deposits is desorbed from the deposits, and

in the act of supplying the etching gas, the deposits from which at least the portion of the carbon is desorbed is removed through the thermochemical reaction.

3. The method of claim 1 , wherein, in the act of supplying the modifying gas, the deposits are not removed, and at least a portion of carbon included in the deposits is desorbed from the deposits.

4. The method of claim 1 , wherein the act of supplying the modifying gas is performed by supplying the modifying gas excited to a plasma state, and

the act of supplying the etching gas is performed under a non-plasma atmosphere.

5. The method of claim 1 , wherein, in the act of supplying the modifying gas, the deposits are modified through a plasma chemical reaction.

6. The method of claim 1 , wherein the oxide film containing carbon is a film having an oxide film as a main agent, and at least a portion of oxygen in the oxide film is substituted with carbon.

7. The method of claim 1 , wherein

in the act of supplying the modifying gas, the oxide film containing the carbon included in the deposits is modified into an oxide film without containing carbon or an oxide film containing carbon having carbon concentration lower than that of the oxide film containing the carbon included in the deposits.

8. The method of claim 1 , wherein the precursor gas contains at least one selected from the group consisting of an alkyl group and an alkylene group.

9. The method of claim 1 , wherein the precursor gas contains at least one selected from the group consisting of an Si—C—Si bonding and an Si—C—C—Si bonding.

10. The method of claim 1 , wherein each of the first catalytic gas and second catalytic gas each comprises at least one selected from the group consisting of an amine-based catalytic gas and a non-amine-based catalytic gas.

11. The method of claim 1 , wherein the oxide film containing carbon is formed by setting a temperature of the substrate to fall within a range from room temperature to 200 degrees C.

12. The method of claim 1 , wherein the oxide film containing carbon is obtained by thermal treatment.

13. The method of claim 1 , wherein the modifying gas comprises at least one selected from the group consisting of an oxygen-containing gas, a hydrogen-containing gas and an inert gas, and

the etching gas comprises a fluorine-containing gas.

14. The method of claim 1 , wherein the modifying gas comprises at least one selected from the group consisting of an O 2 gas, a CO gas, a CO 2 gas, an NO gas, an N 2 O gas, an O 3 gas, an H 2 O 2 gas, an H 2 gas, a D 2 gas, an NH 3 gas, an N 2 gas, an Ar gas, a He gas, a Ne gas and a Xe gas, and

the etching gas comprises at least one selected from the group consisting of an HF gas, an F 2 gas, an NF 3 gas and a C 1 F 3 gas.

15. A method of manufacturing a semiconductor device, comprising:

performing a process of forming an oxide film containing carbon; wherein the act of forming an oxide film containing carbon comprises:

performing a set a first predetermined number of times, an iteration of the set including:

supplying a precursor gas containing silicon, carbon and a halogen element and having an Si—C bonding, and a first catalytic gas to a substrate in a process chamber; and

supplying an oxidizing gas and a second catalytic gas to the substrate to form an oxide film containing carbon; and

cleaning an interior of the process chamber wherein the act of cleaning the interior of the process chamber comprises performing a cycle a second predetermined number of times, an iteration of the cycle comprising:

supplying a modifying gas into the process chamber to modify deposits including the oxide film containing carbon; and

supplying an etching gas into the process chamber to remove the modified deposits through a thermochemical reaction.

16. A non-transitory computer-readable recording medium storing a program that causes a computer to perform a process of cleaning an interior of a process chamber, wherein the process comprises:

performing a set a first predetermined number of times, one iteration of the set including:

supplying a precursor gas containing silicon, carbon, and a halogen element and having an Si—C bonding, and a first catalytic gas to a substrate in the process chamber; and

supplying an oxidizing gas and a second catalytic gas to the substrate to form an oxide film containing carbon; and

performing a cycle a second predetermined number of times, one iteration of the cycle comprising:

supplying a modifying gas into the process chamber to modify deposits including the oxide film containing carbon; and

supplying an etching gas into the process chamber to remove the modified deposits through a thermochemical reaction.