High-purity copper sputtering target
View Patent ↗A high-purity copper sputtering target, wherein a Vickers hardness of a flange part of the target is in a range of 90 to 100 Hv, a Vickers hardness of an erosion part in the central area of the target is in a range of 55 to 70 Hv, and a crystal grain size of the erosion part is 80 μm or less. This invention relates to a high-purity copper sputtering target that does not need to be bonded to a backing plate (BP), and aims to provide a high-purity copper sputtering target capable of forming a thin film having superior uniformity by enhancing a strength (hardness) of the flange part of the target, and reducing an amount of warpage of the target. Moreover, the uniformity of the film thickness is improved by adjusting the (111) orientation ratio of the erosion part and the flange part in the target. The present invention thereby aims to provide a high-purity copper sputtering target, which is capable of improving the yield and reliability of semiconductor products that are being subject to further miniaturization and higher integration, and useful for forming a copper alloy wiring for semiconductors.
1. A high-purity copper sputtering target, the target being plate-shaped and consisting of copper having a purity of 99.999% (5N) or higher and having an erosion part in a central area of the target and a flange part forming an outer periphery of the target, wherein a (111) orientation ratio of the flange part of the target is 20 to 30%, and a (111) orientation ratio of the erosion part of the target is 57 to 68%, wherein a Vickers hardness of the flange part of the target is in a range of 90 to 100 Hv, a Vickers hardness of the erosion part of the target is in a range of 55 to 70 Hv, and a crystal grain size of the erosion part is 80 pm or less.
2. The high-purity copper sputtering target according to claim 1 , wherein an amount of warpage of the target, after the target is used, is 2.0 mm or less.
3. The high-purity copper sputtering target according to claim 2 , wherein the flange part of the target is a cold worked structure.
4. The high-purity copper sputtering target according to claim 3 , wherein the flange part extends 20 mm to 50 mm from an outer peripheral edge of the target toward the erosion part of the target.
5. The high-purity copper sputtering target according to claim 1 , wherein the flange part is a cold worked structure.
6. The high-purity copper sputtering target according to claim 1 , wherein the flange part extends 20 mm to 50 mm from an outer peripheral edge of the target toward the erosion part of the target.
7. The high-purity copper sputtering target according to claim 1 , wherein the Vickers hardness of the erosion part of the target is in the range of 55 to less than 70 Hv.
8. The high-purity copper sputtering target according to claim 1 , wherein the Vickers hardness of the erosion part of the target is in the range of 55 to 67 Hv.
9. The high-purity copper sputtering target according to claim 1 , wherein the Vickers hardness of the erosion part of the target is in the range of 61 to 67 Hv.