Molding packaging material and method for producing same
A molding packaging material excellent in interlaminar lamination strength is provided, in which it is possible to prevent deterioration of the interlaminar strength due to influences of electrolytes and also possible to prevent deterioration of the interlaminar strength due to influences of heat generation and/or expansion/contraction of the packaging material caused by repetition of charging/discharging. The molding packaging material of the present invention includes a heat resistant resin layer 2 as an outer layer, a polypropylene layer 3 as an inner layer, a metal foil layer 5 arranged between the heat resistant resin layer and the polypropylene layer, wherein at least an inner side surface of the metal foil layer 4 is subjected to a chemical conversion treatment, and the polypropylene layer 3 is laminated on the chemical conversion treatment surface of the metal foil layer via an adhesive layer 5 , wherein the adhesive layer 5 is formed by applying an adhesive to the chemical conversion treatment surface of the inner side surface of the metal foil layer 4 , the adhesive containing at least an organic solvent, a polyolefin resin having a carboxyl group in which the organic solvent is dissolved and an MFR measured at 130° C. is 5 g/10 min to 42 g/10 min, and a multifunctional isocyanate compound.
1. A molding packaging material comprising:
a heat resistant resin layer as an outer layer;
a polypropylene layer as an inner layer; and
a metal foil layer arranged between the heat resistant resin layer and the polypropylene layer, wherein
a chemical conversion coating film containing chromium is provided on at least an inner side surface of the metal foil layer, and the polypropylene layer is laminated on the chemical conversion coating film of the metal foil layer via an adhesive layer, the adhesive layer is formed by applying an adhesive to the chemical conversion treatment surface of the inner side of the metal foil layer, the adhesive containing at least an organic solvent, a polyolefin resin having a carboxyl group dissolved in the organic solvent and having an MFR of 5 g/10 min to 42 g/10 min measured at 130° C., and a multifunctional isocyanate compound, and
the polypropylene layer as the inner layer is constituted by a copolymer resin containing at least propylene and ethylene as a copolymerization component, having a melting point of 135° C. to 155° C., and having an MFR of 6 g/10 min to 25 g/10 min measured at 230° C.
2. The molding packaging material as recited in claim 1 , wherein the adhesive further contains a polyolefin resin having a carboxyl group and having a melting point of 120° C. to 170° C. in a manner dispersed in the organic solvent.
3. The molding packaging material as recited in claim 1 , wherein the adhesive layer is formed by applying the adhesive on the chemical conversion treatment surface of the inner side of the metal foil layer and thereafter subjecting the applied adhesive to a baking treatment.
4. The molding packaging material as recited in claim 1 , wherein the molding packaging material is a food packaging material or a pharmaceutical packaging material.
5. The molding packaging material as recited in claim 1 , wherein the chemical conversion coating film further contains phosphorus.
6. The molding packaging material as recited in claim 1 , wherein the chemical conversion coating film further contains phosphorus and a metal salt of fluoride.
7. The molding packaging material as recited in claim 1 , wherein the chemical conversion coating film further contains polyacrylic acid.
8. The molding packaging material as recited in claim 1 , wherein the chemical conversion coating film further contains phosphorus and polyacrylic acid.
9. The molding packaging material as recited in claim 1 , wherein the copolymer resin constituting the inner layer has an MFR of 21 g/10 min to 25 g/10 min measured at 230° C.
10. A battery case comprising:
the molding packaging material as recited in claim 1 .
11. A molding packaging material comprising:
a heat resistant resin layer as an outer layer;
a polypropylene layer as an inner layer; and
a metal foil layer arranged between the heat resistant resin layer and the polypropylene layer, wherein
a chemical conversion coating film containing chromium is provided on at least an inner side surface of the metal foil layer, and the polypropylene layer is laminated on the chemical conversion coating film of the metal foil layer via an adhesive layer,
the adhesive layer is formed by applying an adhesive to the chemical conversion treatment surface of the inner side of the metal foil layer, the adhesive containing at least an organic solvent, a polyolefin resin having a carboxyl group dissolved in the organic solvent and having an MFR of 5 g/10 min to 42 g/10 min measured at 130° C., and a multifunctional isocyanate compound, and
the polyolefin resin having a carboxyl group has a melting point of 50° C. to 90° C.
12. A production method of a molding packaging material, comprising:
a step of adhering a heat resistant resin film on one surface of a metal foil with a second adhesive;
a step of forming a chemical conversion coating film containing chromium on another surface of the metal foil;
a step of forming a first adhesive layer by applying a first adhesive on the chemical conversion coating film of the metal foil, wherein the first adhesive contains at least an organic solvent, a polyolefin resin having a carboxyl group dissolved in the organic solvent and having an MFR of 5 g/10 min to 42 g/10 min measured at 130° C., and a multifunctional isocyanate compound; and
a step of laminating a polypropylene layer as an inner layer on a non-laminated surface of the first adhesive layer, wherein
the polypropylene layer as the inner layer is constituted by a copolymer resin containing at least propylene and ethylene as a copolymerization component, having a melting point of 135° C. to 155° C., and having an MFR of 6 g/10 min to 25 g/10 min measured at 230° C.
13. The production method of a molding packaging material as recited in claim 12 , wherein the first adhesive further contains a polyolefin resin having a carboxyl group and having a melting point of 120° C. to 170° C. in a manner dispersed in the organic solvent.
14. The production method of a molding packaging material as recited in claim 12 , wherein after applying the first adhesive, the first adhesive is heated to perform baking to thereby form the first adhesive layer.