Cu—Ni—Si based copper alloy
View Patent ↗A rolled Cu—Ni—Si based copper alloy having excellent strength, electric conductivity, and bending coefficient is provided. The rolled copper alloy comprises 1.2 to 4.5% by mass Ni, 0.25 to 1.0% by mass Si, and the balance Cu with inevitable impurities. In the direction transverse to the rolling direction, the rolled copper alloy has a bending coefficient of 130 GPa or more and an electrical conductivity of 30% ICAS or more.
1. A rolled Cu—Ni—Si based copper alloy, comprising 1.2 to 4.5% by mass of Ni and 0.25 to 1.0% by mass of Si, wherein
I{111}/I 0 {111} is 0.15 or more, I{200}/I 0 {200} is 0.5 or less, and I{111}/(I{111}+I{200}+I{220}+I{311}) is 0.2 or more, wherein I{111} is a X-ray diffraction intensity of a {111} plane of a rolled surface of the rolled Cu—Ni—Si based copper alloy, I 0 {111} is a X-ray diffraction intensity of a {111} plane of a pure copper powder standard specimen, I{200} is a X-ray diffraction intensity of a {200} plane of a rolled surface of the rolled Cu—Ni—Si based copper alloy, I 0 {200} is a X-ray diffraction intensity of a plane {200} of the pure copper powder standard specimen, I{220} is a X-ray diffraction intensity of a {220} plane of a rolled surface of the rolled Cu—Ni—Si based copper alloy, and I{311} is a X-ray diffraction intensity of a plane {311} of a rolled surface of the rolled Cu—Ni—Si based copper alloy,
a bending coefficient in a direction transverse to rolling direction is 130 GPa or more,
a yield strength in MPa, YS (MPa), in the direction transverse to rolling direction satisfies: YS (MPa)≧[−22×(MPa/(mass %) 2 )×(Ni mass %) 2 ]+[215×(MPa/(mass %))×(Ni mass %)]+422 (MPa), and
the electrical conductivity in the direction transverse to rolling direction is 30% IACS or more.
2. The rolled Cu—Ni—Si based copper alloy according to claim 1 , further comprising one or more elements selected from the group consisting of Mg, Mn, Sn, Zn, Co and Cr, wherein the sum of Mg, Mn, Sn, Zn, Co and Cr is 0.005 to 2.5 mass % of the alloy.
3. The rolled Cu—Ni—Si based copper alloy according to claim 1 , further comprising one or more elements selected from the group consisting of P, B, Ti, Zr, Al, Fe and Ag, wherein the sum of P, B, Ti, Zr, Al, Fe, and Ag is 0.005 to 1.0 mass % of the alloy.