Light emitting diode (LED) component comprising a phosphor with improved excitation properties
View Patent ↗A light emitting diode (LED) component comprises an LED having a dominant wavelength in a range of from about 425 nm to about 475 nm, and a first phosphor and a second phosphor are in optical communication with the LED. The first phosphor has a peak emission wavelength in the range of from about 600 nm to about 700 nm, and the second phosphor has a peak emission wavelength in the range of from about 500 nm to about 600 nm. An excitation spectrum of the first phosphor includes, at excitation wavelengths longer than 530 nm, no intensities greater than about 60% of a maximum intensity of the excitation spectrum.
1. A light emitting diode (LED) component comprising:
an LED comprising a dominant wavelength in a range of from about 425 nm to about 475 nm;
a first phosphor in optical communication with the LED, the first phosphor comprising:
a host lattice comprising yttrium aluminum garnet;
an activator comprising Ce incorporated in the host lattice;
a first substitutional dopant comprising Si incorporated in the host lattice; and
a second substitutional dopant comprising Mg incorporated in the host lattice, a peak emission wavelength of the first phosphor being in the range of from about 600 nm to about 700 nm; and
a second phosphor in optical communication with the LED, the second phosphor comprising a peak emission wavelength in the range of from about 500 nm to about 600 nm,
wherein an excitation spectrum of the first phosphor comprises, at excitation wavelengths longer than 530 nm, no intensities greater than about 60% of a maximum intensity of the excitation spectrum.
2. The LED component of claim 1 , wherein the excitation spectrum comprises no intensities greater than about 55% of the maximum intensity of the excitation spectrum at excitation wavelengths longer than 530 nm.
3. The LED component of claim 2 , wherein the excitation spectrum comprises no intensities greater than about 50% of the maximum intensity of the excitation spectrum at excitation wavelengths longer than 530 nm.
4. The LED component of claim 1 , wherein the peak emission wavelength of the first phosphor is in the range of from about 600 nm to about 650 nm.
5. The LED component of claim 1 , wherein the first phosphor comprises a chemical formula Y a Ce b Al c Si d Mg d O z , where 0<a<3, 0<b≦0.6, 0<c<5, 0<d<5, and z is nominally 12.
6. The LED component of claim 5 , wherein a+b≦3 and 0.1≦b<0.3.
7. The LED component of claim 5 , wherein b/(a+b)·100=mol. % Ce, and 0<mol. % Ce<15.
8. The LED component of claim 7 , wherein 3≦mol. % Ce≦8.
9. The LED component of claim 5 , wherein d/(c+2d)·100=mol. % Si=mol. % Mg, and wherein 0<mol. % Si<50 and 0<mol. % Mg<50.
10. The LED component of claim 9 , wherein 30<mol. % Si<50 and 30<mol. % Mg<50.
11. The LED component of claim 5 , wherein R=(a+b)/(c+2d), and 0.5<R≦0.6.
12. The LED component of claim 11 , wherein a+b=3 and c+2d>5.
13. The LED component of claim 5 , wherein 0.5≦c≦2.
14. The LED component of claim 13 , wherein 1.0≦c≦1.5.
15. The LED component of claim 1 , wherein the second phosphor comprises:
a host lattice comprising yttrium aluminum garnet; and
an activator comprising Ce incorporated in the host lattice.
16. The LED component of claim 15 , wherein the host lattice of the second phosphor further comprises a substitutional dopant comprising Ga incorporated therein.
17. The LED component of claim 16 , wherein the second phosphor comprises a yellow phosphor having a chemical formula Y a Ce b Gd c Al d Ga e O z , where 0<a<3, 0<b≦0.6, 0<c≦1, 0<d<5, 0<e≦2.5, and z is nominally 12.
18. The LED component of claim 17 , wherein
c/(a+b+c)·100=mol. % Ce, and 3<mol. % Ce<20,
e/(d+e)·100=mol. % Ga, and 5<mol. % Ga<50, and
wherein mol. % Ga≧mol. % Ce.
19. The LED component of claim 18 , wherein 3.3≦mol. % Ce<15 and 12≦mol. % Ga<20.
20. The LED component of claim 1 , wherein the first phosphor and the second phosphor are mixed together in a phosphor layer on the LED.
21. The LED component of claim 1 , wherein the first phosphor and the second phosphor are disposed in separate phosphor layers on the LED, the first phosphor being in a first phosphor layer and the second phosphor being in a second phosphor layer above or below the first phosphor layer.
22. A phosphor with improved excitation properties, the phosphor comprising:
a host lattice comprising yttrium aluminum garnet;
an activator comprising Ce in the host lattice;
a first substitutional dopant comprising Si incorporated in the host lattice; and
a second substitutional dopant comprising Mg incorporated in the host lattice,
wherein the phosphor comprises a peak emission wavelength in the range of from about 600 nm to about 700 nm, and
wherein an excitation spectrum of the phosphor comprises, at excitation wavelengths longer than 530 nm, no intensities greater than about 60% of a maximum intensity of the excitation spectrum.
23. The phosphor of claim 22 , wherein the excitation spectrum comprises no intensities greater than about 50% of the maximum intensity of the excitation spectrum at excitation wavelengths longer than 530 nm.
24. The phosphor of claim 22 , wherein the peak emission wavelength is in the range of from about 600 nm to about 650 nm.
25. The phosphor of claim 22 , wherein the phosphor comprises a chemical formula Y a Ce b Al c Si d Mg d O z , where 0<a<3, 0<b≦0.6, 0<c<5, 0<d<5, and z is nominally 12.