IP Library › Granted Patent US 9,953,826
Granted Patent B2
US 9,953,826 · App. 14/539,174 · Granted Apr 24, 2018

Substrate cleaning method, substrate cleaning system, and memory medium

Inventors: Miyako Kaneko (Nirasaki, JP); Keiji Tanouchi (Nirasaki, JP); Takehiko Orii (Nirasaki, JP); Itaru Kanno (Minato-ku, JP); Meitoku Aibara (Koshi, JP); Satoru Tanaka (Koshi, JP)
Assignee: TOKYO ELECTRON LIMITED
H01L21/0206H01L21/02052H01L21/02057H01L21/67051
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,953,826
App. No.
14/539,174
Granted
Apr 24, 2018
Kind
B2
Abstract

A method for cleaning a substrate includes supplying to a substrate a film-forming processing liquid which includes a volatile component and forms a film on the substrate, vaporizing the volatile component in the film-forming processing liquid such that the film-forming processing liquid solidifies or cures on the substrate and forms a processing film on the substrate, supplying to the substrate having the processing film a strip-processing liquid which strips the processing film from the substrate, and supplying to the processing film formed on the substrate a dissolving-processing liquid which dissolves the processing film after the supplying of the strip-processing liquid.

Claims (24)

1. A method for cleaning a substrate, comprising:

supplying to a substrate a film-forming processing liquid which includes resin and a volatile component;

vaporizing the volatile component in the film-forming processing liquid such that the film-forming processing liquid solidifies or cures on the substrate and forms a processing film that captures and contains particles adhered to a surface of the substrate on the substrate;

supplying to the substrate having the processing film a strip-processing liquid which strips the processing film containing the particles from the substrate such that the strip-processing liquid infiltrates between the processing film and the substrate without dissolving the processing film into a liquid state; and

supplying to the processing film a dissolving-processing liquid which dissolves the processing film stripped by the strip-processing liquid after the supplying of the strip-processing liquid such that the dissolving-processing liquid dissolves the processing film stripped by the strip-processing liquid,

wherein the substrate is one of a silicon wafer and a compound semiconductor wafer, wherein the substrate has a pattern formed on a surface thereof, wherein the dissolving-processing liquid is a liquid that dissolves the processing film and that is selected from the group consisting of an alkali developing solution having a first alkali concentration that dissolves the processing film into the liquid state and an isopropyl alcohol (IPA) and water solution having a first IPA concentration that dissolves the processing film into the liquid state, and wherein the strip-processing liquid is a liquid that does not dissolve the processing film into the liquid state before the supplying of the dissolving-processing liquid and that is selected from the group consisting of pure water, an alkali developing solution having a second alkali concentration that is lower than the first alkali concentration an IPA and water solution having a second IPA concentration that is lower than the first IPA concentration, and water mixed with CO 2 gas.

2. The method for cleaning a substrate according to claim 1 , wherein the supplying of the film-forming processing liquid comprises supplying the film-forming processing liquid to the substrate without a resist layer on the substrate.

3. The method for cleaning a substrate according to claim 1 , wherein the supplying of the film-forming processing liquid comprises supplying the film-forming processing liquid to the surface having the pattern.

4. The method for cleaning a substrate according to claim 1 , wherein the strip-processing liquid is pure water.

5. The method for cleaning a substrate according to claim 4 , wherein the pure water is heated pure water.

6. The method for cleaning a substrate according to claim 1 , wherein the substrate has a silicon nitride film forming a surface of the substrate.

7. The method for cleaning a substrate according to claim 1 , wherein the strip-processing liquid is a low concentration dissolving-processing liquid which is a lower concentration liquid of the dissolving-processing liquid such that the low concentration dissolving-processing liquid infiltrates between the processing film and the substrate without dissolving the processing film into the liquid state.

8. The method for cleaning a substrate according to claim 7 , wherein the supplying of the strip-processing liquid includes supplying the alkali developing solution having the second alkali concentration, and the supplying of the dissolving-processing liquid includes supplying the alkali developing solution having the first alkali concentration.

9. The method for cleaning a substrate according to claim 1 , wherein the supplying of the dissolving-processing liquid includes changing a concentration of the dissolving-processing liquid from one concentration to a higher concentration.

10. The method for cleaning a substrate according to claim 7 , wherein the dissolving-processing liquid comprises the IPA and water solution having the first IPA concentration, and the strip-processing liquid comprises the IPA and water solution having the second IPA concentration.

11. The method for cleaning a substrate according to claim 1 , wherein the dissolving-processing liquid comprises the alkali developing solution having the first concentration, wherein the first concentration is a concentration of 1.0% or higher, and the strip-processing liquid comprises the dissolving-processing liquid having an alkali concentration of 0.5% or lower.

12. The method for cleaning a substrate according to claim 1 , wherein the dissolving-processing liquid is the alkali developing solution of the first alkali concentration and comprises at least one of a quarternary ammonium hydroxide and choline, and the strip-processing liquid is the alkali developing solution of the second alkali concentration and comprises at least one of a quarternary ammonium hydroxide and choline.

13. The method for cleaning a substrate according to claim 1 , further comprising:

rinsing off the particles and the dissolving-processing liquid from the surface of the substrate.

14. The method for cleaning a substrate according to claim 1 , wherein the pure water is heated pure water having a temperature of 75° C. or lower.

15. The method for cleaning a substrate according to claim 1 , wherein the film-forming processing liquid is a topcoat solution.

16. The method for cleaning a substrate according to claim 1 , wherein the film-forming processing liquid is a topcoat solution, and the resin in the topcoat solution comprises acrylic resin.

17. The method for cleaning a substrate according to claim 4 , wherein the film-forming processing liquid is a topcoat solution, and the resin in the topcoat solution comprises acrylic resin.

18. The method for cleaning a substrate according to claim 8 , wherein the film-forming processing liquid is a topcoat solution, and the resin in the topcoat solution comprises acrylic resin.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 12, 2014
From: KANEKO, MIYAKO; TANOUCHI, KEIJI; ORII, TAKEHIKO; KANNO, ITARU; AIBARA, MEITOKU; TANAKA, SATORU
To: TOKYO ELECTRON LIMITED
Reel/Frame 034157/0455 →
Priority Claims (2)
JP 2013-234843 · Nov 13, 2013 · national
JP 2014-163839 · Aug 11, 2014 · national
Continuity (1)
Related Publication 20150128994A1 · May 14, 2015