Multilayer film

1. A multilayer film comprising:

a. a first polyimide layer from 8 to 130 microns thick comprising: a polyimide derived from at least 50 mole percent of an aromatic dianhydride, based upon a total dianhydride content of the polyimide, and at least 50 mole percent of an aromatic diamine based upon a total diamine content of the polyimide;

b. a second polyimide layer from 0.5 to 25 microns thick in direct contact with the first polyimide layer, the second polyimide layer comprising:

i) 45 to 67 wt % of a polyimide derived from at least 50 mole percent of an aromatic dianhydride, based upon a total dianhydride content of the polyimide, and at least 50 mole percent of an aromatic diamine based upon a total diamine content of the polyimide

ii) greater than 14 wt % of a silica matting agent or a mixture of silica matting agent and at least one additional matting agent; and

iii) at least one submicron carbon black, wherein the total amount of the submicron carbon black and the polyimide is less than 85 wt % and greater than 45 wt %; and

wherein the multilayer film has an L* color less than 30 and a 60 degree gloss value less than 10.

2. The multilayer film in accordance with claim 1 , wherein the polyimide of the second polyimide layer is derived from pyromellitic dianhydride and 4,4′-oxydianiline or derived from pyromellitic dianhydride, 4,4′-oxydianiline and paraphenylenediamine.

3. The multilayer film in accordance with claim 1 , wherein the polyimide of the second polyimide layer is derived from i) blocks of pyromellitic dianhydride and 4,4′-oxydianiline and ii) blocks of pyromellitic dianhydride and paraphenylenediamine.

4. The multilayer film in accordance with claim 1 , wherein the polyimide of the first polyimide layer is derived from pyromellitic dianhydride and 4,4′-oxydianiline.

5. The multilayer film in accordance with claim 1 , wherein the polyimide of the first polyimide layer is derived from pyromellitic dianhydride and 4,4′-oxydianiline, and wherein the polyimide of the second polyimide layer is derived from

i) pyromellitic dianhydride and 4,4′-oxydianiline, or derived from

ii) pyromellitic dianhydride, 4,4′-oxydianiline and paraphenylenediamine, or derived from

iii) blocks of pyromellitic dianhydride and 4,4′-oxydianiline and blocks of pyromellitic dianhydride and paraphenylenediamine.

6. The multilayer film in accordance with claim 1 , the first polyimide layer further comprising:

i.) 1 to 15 wt % low conductivity carbon black, or

ii.) 1 to 40 wt % pigment or dye.

7. The multilayer film in accordance with claim 6 , the first polyimide layer further comprising 1 to 20 wt % of a matting agent selected from silica, alumina, zirconia, boron nitride, barium sulfate, polyimide particles, calcium phosphate, talc or mixtures thereof.

8. The multilayer film in accordance with claim 6 , the first polyimide layer further comprising 1 to 20 wt % of a matting agent that is a carbon black having a mean particle size from 2 to 9 micrometers.

9. The multilayer film in accordance with claim 6 , the first polyimide layer further comprising 1 to 20 wt % of a matting agent, the matting agent being a mixture of

i) carbon black having a mean particle size from 2 to 9 microns; and

ii) silica, alumina, zirconia, boron nitride, barium sulfate, polyimide particles, calcium phosphate, talc or mixtures thereof.

10. The multilayer film in accordance with claim 1 , further comprising an adhesive layer in direct contact with the first polyimide layer opposite the second polyimide layer.

11. The multilayer film in accordance with claim 10 , wherein the adhesive layer is an epoxy resin selected from the group consisting of: Bisphenol A type epoxy resin, cresol novolac type epoxy resin, phosphorus containing epoxy resin, and mixtures thereof.

12. The multilayer film in accordance with claim 1 , further comprising a third polyimide layer from 0.5 to 25 microns thick in direct contact with the first polyimide layer opposite the second polyimide layer, the third polyimide layer comprising:

i) 45 to 67 wt % of a polyimide derived from at least 50 mole percent of an aromatic dianhydride, based upon a total dianhydride content of the polyimide, and at least 50 mole percent of an aromatic diamine based upon a total diamine content of the polyimide

ii) greater than 14 wt % of a matting agent or mixture of matting agents; and

iii) at least one submicron carbon black, wherein the total amount of the submicron carbon black and the polyimide is less than 85 wt % and greater than 45 wt %.

13. The multilayer film in accordance with claim 12 , wherein the matting agent in the third polyimide layer is selected from silica, alumina, zirconia, boron nitride, barium sulfate, polyimide particles, calcium phosphate, talc or mixtures thereof.

14. The multilayer film in accordance with claim 12 , wherein the matting agent in the third polyimide layer is a carbon black having a mean particle size from 2 to 9 microns.

15. The multilayer film in accordance with claim 12 , wherein the matting agent in the third polyimide layer is a mixture of

i) carbon black having a mean particle size from 2 to 9 microns; and

ii) silica, alumina, zirconia, boron nitride, barium sulfate, polyimide particles, calcium phosphate, talc or mixtures thereof.

16. The multilayer film in accordance with claim 12 , further comprising an adhesive layer in direct contact with the second polyimide layer or the third polyimide layer on a surface of the second polyimide layer or the third polyimide layer opposite from the first polyimide layer.

17. The multilayer film in accordance with claim 12 , the first polyimide layer further comprising:

i) 1 to 15 wt % low conductivity carbon black, or

ii) 1 to 40 wt % pigment or dye.

18. The multilayer film in accordance with claim 17 , the first polyimide layer further comprising 1 to 20 wt % of a matting agent selected from silica, alumina, zirconia, boron nitride, barium sulfate, polyimide particles, calcium phosphate, talc or mixtures thereof.

19. The multilayer film in accordance with claim 17 , the first polyimide layer further comprising 1 to 20 wt % of a matting agent that is a carbon black having a mean particle size from 3 to 9 micrometers.

20. The multilayer film in accordance with claim 17 , the first polyimide layer further comprising matting agent mixture of

i) carbon black having a mean particle size from 2 to 9 microns; and

ii) silica, alumina, zirconia, boron nitride, barium sulfate, polyimide particles, calcium phosphate, talc or mixtures thereof.