Positive electrode active material for lithium-ion battery, positive electrode for a lithium-ion battery, lithium-ion battery using same, and precursor to a positive electrode active material for a lithium-ion battery
View Patent ↗The present invention provides a positive electrode active material for lithium ion batteries, which realizes a lithium ion battery that is, while satisfying fundamental characteristics of a battery (capacity, efficiency, load characteristics), low in the resistance and excellent in the lifetime characteristics. In the positive electrode active material for lithium ion batteries, the variation in the composition of transition metal that is a main component inside of particles of or between particles of the positive electrode active material, which is defined as a ratio of the absolute value of the difference between a composition ratio inside of the particles of or in a small area between the particles of the transition metal and a composition ratio in a bulk state to the composition ratio in a bulk state of the transition metal, is 5% or less.
1. A manufacturing method of a positive electrode active material for lithium ion batteries which is composed of at least lithium and transition metal, wherein the variation in the composition of transition metal inside of particles or between particles of the positive electrode active material is 5% or less, wherein the variation is defined as a ratio of the absolute value of the difference between a composition ratio of the transition metal inside of the particles or in a small area between the particles and a composition ratio in a bulk state to the composition ratio of the transition metal; said method comprising:
forming a precursor by adding alkali hydroxide or alkali carbonate to a solution comprising a lithium compound and a salt of one or more transition metals, and by stirring said precursor while applying ultrasonic dispersion;
drying said precursor;
and oxidizing the dried precursor.
2. The manufacturing method of a positive electrode active material for lithium ion batteries of claim 1 , wherein the positive electrode active material is a lithium-containing transition metal oxide.
3. The manufacturing method of a positive electrode active material for lithium ion batteries of claim 2 , wherein the transition metal in the lithium-containing transition metal oxide is at least one or more selected from the group consisting of Ni, Mn, Co and Fe.
4. The manufacturing method of a positive electrode active material for lithium ion batteries of claim 1 , wherein an average particle size of particles of the positive electrode active material is 2 to 8 μm, a specific surface area of the positive electrode active material is 0.3 to 1.8 m 2 /g, and the tap density of the positive electrode active material is 1.5 to 2.1 g/ml.
5. The manufacturing method of a positive electrode active material for lithium ion batteries of claim 2 , wherein an average particle size of particles of the positive electrode active material is 2 to 8 μm, a specific surface area of the positive electrode active material is 0.3 to 1.8 m 2 /g, and the tap density of the positive electrode active material is 1.5 to 2.1 g/ml.
6. The manufacturing method of a positive electrode active material for lithium ion batteries of claim 3 , wherein an average particle size of particles of the positive electrode active material is 2 to 8 μm, a specific surface area of the positive electrode active material is 0.3 to 1.8 m 2 /g, and the tap density of the positive electrode active material is 1.5 to 2.1 g/ml.