IP Library Granted Patent US 9,337,627
Granted Patent B2
US 9,337,627 · App. 14/710,039 · Granted May 10, 2016

Method of applying a coating to a spark plug insulator

Inventors: Jing Zheng (Findlay, OH); Prabhu Megharaj (Findlay, OH); Jeffrey T. Boehler (Holland, OH)
Assignee: Fram Group IP LLC
H01T21/02F02P15/00H01T13/14H01T13/20
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,337,627
App. No.
14/710,039
Granted
May 10, 2016
Kind
B2
Abstract

A method of applying a coating to a spark plug insulator comprises the steps of forming a slurry solution and applying the slurry solution as a first coating to an insulative sleeve configured for use in a spark plug. The method further includes the step of heat treating the insulative sleeve to a temperature of between about 500 degrees Celsius and about 1000 degrees Celsius for between about 10 minutes and about 2 hour(s). Still further, the method includes the step of applying a second coating overlying at least a portion of the first coating, wherein the second coating comprises an organic binder.

Claims (37)

1. A method of applying a coating to a spark plug insulator, the method comprising the steps of:

forming a slurry solution;

applying the slurry solution as a first coating to an insulative sleeve configured for use in a spark plug;

heat treating the insulative sleeve at a temperature of between about 500 degrees Celsius and about 1000 degrees Celsius for between about 10 minutes and about 2 hours; and

applying a second coating overlying at least a portion of the first coating, wherein the second coating comprises an organic binder.

2. The method of claim 1 , wherein the heat treating step includes heating the insulative sleeve at a temperature of about 650 degrees Celsius for about 1 hour.

3. The method of claim 1 , wherein the organic binder of the second coating has a burn out temperature of between about 200 degrees Celsius and about 450 degrees Celsius.

4. The method of claim 1 , wherein the organic binder is selected from the group consisting of polyoxyethylene, polyvinyl alcohol (PVA), polyethylene oxide (PEO), polyvinyl butyral (PVB), acrylic, Paraffin wax, and cellulose.

5. The method of claim 1 , further including the steps of:

assembling the insulative sleeve having the first and second coatings applied thereto into a spark plug;

installing the spark plug within an engine head of a vehicle such that the spark plug is in communication with a combustion engine of the vehicle;

operating the vehicle such that the combustion reaches a temperature of at least 300 degrees Celsius but less than 400 degrees Celsius; and

burning off carbon deposits within the spark plug.

6. The method of claim 1 , wherein the slurry solution is formed of a transition metal compound or a combination of transition metal compounds, and an alkali metal compound.

7. The method of claim 6 , wherein the transition metal compound is selected from the group consisting of copper nitrate, copper chloride, copper oxide, copper carbonate, ammonium heptamolybdate 4 hydrate, molybdenum chloride, potassium paramolybdate, and combinations of two or more of the foregoing compounds.

8. The method of claim 6 , wherein the transition metal compound comprises a transition metal selected from the group consisting of chromium, iron, zirconium, lead, molybdenum, tungsten, vanadium, niobium, tantalum, copper, silver, gold, nickel, platinum, and palladium.

9. The method of claim 6 , wherein the alkali metal compound is selected from the group consisting of lithium, sodium, potassium, cesium, and a combination of two or more of the foregoing alkali metals.

10. A method of applying a coating to a spark plug insulator, the method comprising the steps of:

forming a slurry solution;

drying the slurry solution to form a solid mixture;

heat treating the solid mixture at a temperature of between about 500 degrees Celsius and about 1000 degrees Celsius for between about 10 minutes and about 2 hours;

grinding the heated solid mixture into a powder;

dispersing the powder into an aqueous suspension; and

applying the aqueous suspension to a spark plug insulator.

11. The method of claim 10 , wherein the slurry solution is formed of a transition metal compound or a combination of transition metal compounds, and an alkali metal compound.

12. The method of claim 11 , wherein the heat treating step converts the solid mixture into an amorphous metal complex.

13. The method of claim 10 , further including the step drying the aqueous solution.

14. The method of claim 13 , wherein the aqueous suspension is not heat treated after being applied to the spark plug insulator.

15. A method of applying a coating to a spark plug insulator, the method comprising the steps of:

dry mixing two or more tri-metal salts to form a dry mixture;

heat treating the dry mixture at a temperature of between about 500 degrees Celsius and about 1000 degrees Celsius for between about 10 minutes and about 2 hours;

grinding the heated solid mixture into a powder;

dispersing the powder into an aqueous suspension; and

applying the aqueous suspension to a spark plug insulator.

16. The method of claim 15 , wherein the heat treating step converts the solid mixture into an amorphous metal complex.

17. The method of claim 15 , further including the step drying the aqueous solution.

18. The method of claim 17 , wherein the aqueous suspension is not heat treated after being applied to the spark plug insulator.

Assignments (17)
RELEASE OF SECURITY INTEREST Recorded Jul 2, 2026
From: WILMINGTON SAVINGS FUND SOCIETY, FSB
To: JEFFERIES FINANCE LLC
Reel/Frame 075891/0705 →
SECURITY INTEREST Recorded Jun 12, 2026
From: PGI NORTHSTAR LLC
To: FIRST HORIZON BANK
Reel/Frame 075410/0391 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2026
From: FIRST BRANDS GROUP HOLDINGS, LLC; FIRST BRANDS GROUP INTERMEDIATE, LLC; FIRST BRANDS GROUP, LLC; CHAMPION LABORATORIES, INC.; FRAM GROUP IP LLC; PYLON MANUFACTURING CORP.; HEATHERTON HOLDINGS, LLC; TRICO PRODUCTS CORPORATION; STRONGARM, LLC
To: PGI NORTHSTAR LLC
Reel/Frame 075584/0001 →
LIEN Recorded Dec 8, 2025
From: JEFFERIES FINANCE LLC
To: WILMINGTON SAVINGS FUND SOCIETY, FSB
Reel/Frame 073892/0154 →
FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jun 18, 2025
From: AIRTEX INDUSTRIES, LLC; AIRTEX PRODUCTS, LP; APC INTERMEDIATE HOLDINGS, LLC; APC PARENT, LLC; ASC INDUSTRIES, INC.; AUTOLITE OPERATIONS LLC; AVM EXPORT, INC.; BPI ACQUISITION COMPANY, LLC; BPI EC, LLC; BPI HOLDINGS INTERNATIONAL, LLC; BRAKE PARTS INC CHINA LLC; BRAKE PARTS INC INDIA LLC; BRAKE PARTS INC LLC; CARDONE INDUSTRIES, INC.; CARRAND COMPANIES, INC.; CARTER CARBURETOR HOLDINGS, LLC; CARTER CARBURETOR, LLC; CARTER FUEL EXPORT, INC.; CARTER FUEL SYSTEMS, LLC; CHAMPION LABORATORIES, INC.; CWD HOLDING, LLC; CWD INTERMEDIATE HOLDINGS I, LLC; CWD INTERMEDIATE HOLDINGS II, LLC; CWD, LLC; DALTON CORPORATION; DALTON CORPORATION, KENDALLVILLE; MANUFACTURING FACILITY DALTON CORPORATION, ASHLAND; MANUFACTURING FACILITY DALTON CORPORATION, STRYKER MACHINING FACILITY CO.; DALTON CORPORATION, WARSAW MANUFACTURING FACILITY; EAGLE CASTING, LLC; EAGLE MACHINING, LLC; FIRST BRANDS GROUP INTERMEDIATE, LLC; FIRST BRANDS GROUP, LLC; FRAM GROUP IP LLC; FRAM GROUP OPERATIONS LLC; FRAMAUTO HOLDINGS, LLC; FUEL FILTER TECHNOLOGIES, INC.; GLOBAL REMAN VENTURES, LLC; HEATHERTON HOLDINGS, LLC; HOPKINS ACQUISITION, INC.; HOPKINS MANUFACTURING CORPORATION; HORIZON EURO FINANCE LLC; HORIZON GLOBAL AMERICAS INC.; HORIZON GLOBAL COMPANY LLC; HORIZON GLOBAL CORPORATION; HORIZON INTERNATIONAL HOLDINGS LLC; IBI INTERNATIONAL HOLDING COMPANY, INC.; INTERNATIONAL BRAKE INDUSTRIES, INC.; JASPER ACQUISITION CORP.; JASPER RUBBER PRODUCTS, INC.; KTRI HOLDINGS, INC.; KTRI OFFSHORE HOLDINGS, LLC; LONGMAN ENTERPRISES, INC.; PHNX ACQUISITION CORP.; PREMIER MARKETING GROUP, LLC; PYLON MANUFACTURING CORP.; PYLON SOUTH BEND, INC.; QUALIS AUTOMOTIVE, L.L.C.; QUALIS ENTERPRISES, LLC; QUALITOR ACQUISITION INC.; QUALITOR AUTOMOTIVE, LLC; QUALITOR SUBSIDIARY H, INC.; QUALITOR SUBSIDIARY S, INC.; QUALITOR, INC.; REMAN MANAGEMENT INTERNATIONAL LLC; SDC TX, LLC; SMART CHOICE, LLC; SPECIALTY PUMPS GROUP, INC.; STRONGARM, LLC; TAE BRAKES, LLC; TAE CHINA HOLDINGS, INC.; TMD INTERNATIONAL HOLDINGS LLC; TMD MEXICO LLC; TOLEDO MOLDING & DIE, LLC; TRANSPORTATION AFTERMARKET ENTERPRISE, LLC; TRICO HOLDING CORPORATION; TRICO PRODUCTS CORPORATION; TRICO TECHNOLOGIES CORPORATION; TRIDONEX USA LLC; UCI ACQUISITION HOLDINGS (NO. 4) LLC; UCI INTERNATIONAL HOLDINGS PARENT, INC.; UCI INTERNATIONAL HOLDINGS, INC.; UCI INTERNATIONAL, LLC; UCI PENNSYLVANIA, INC.; UCI-AIRTEX HOLDINGS, INC.; UNITED COMPONENTS, LLC; UNIVERSAL AUTO FILTER LLC; VIPER ACQUISITION I, INC.; VIPER ACQUISITION, INC.; WALBRO LLC; WALBRO MIDCO LLC; WEM US CO.
To: GLAS USA LLC
Reel/Frame 071674/0688 →
CORRECTIVE ASSIGNMENT TO CORRECT THE THE PATENT APPLICATION NUMBERS PREVIOUSLY RECORDED AT REEL: 053377 FRAME: 0596. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 19, 2022
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: JEFFERIES FINANCE LLC
Reel/Frame 062584/0429 →
ASSIGNMENT OF SECURITY INTEREST Recorded Jul 31, 2020
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: JEFFERIES FINANCE LLC
Reel/Frame 053377/0596 →
RELEASE OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded May 25, 2020
From: ACQUIOM AGENCY SERVICES LLC
To: ASC INDUSTRIES, INC.; CARTER FUEL SYSTEMS, LLC; FRAM GROUP IP LLC; STRONGARM, LLC; TRICO PRODUCTS CORPORATION; TRICO GROUP, LLC; TRICO GROUP HOLDINGS, LLC
Reel/Frame 053313/0812 →
SECURITY INTEREST Recorded Apr 23, 2020
From: FRAM GROUP IP LLC
To: ACQUIOM AGENCY SERVICES LLC
Reel/Frame 052481/0586 →
ABL INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 1, 2019
From: FRAM GROUP IP LLC
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 048479/0639 →
RELEASE OF ABL PATENT SECURITY INTEREST Recorded Feb 27, 2019
From: BMO HARRIS BANK N.A., AS COLLATERAL AGENT
To: FRAM GROUP IP LLC
Reel/Frame 048455/0808 →
RELEASE OF TERM LOAN PATENT SECURITY INTEREST Recorded Feb 27, 2019
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: FRAM GROUP IP LLC
Reel/Frame 048455/0869 →
SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Feb 27, 2019
From: ASC INDUSTRIES, INC.; CARTER FUEL SYSTEMS, LLC; FRAM GROUP IP LLC; HEATHERTON HOLDINGS, LLC; STRONGARM, LLC; TRICO PRODUCTS CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 048887/0495 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 16, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS RESIGNING COLLATERAL AGENT
To: BMO HARRIS BANK, N.A., AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 041739/0040 →
SECURITY INTEREST Recorded Dec 27, 2016
From: FRAM GROUP IP LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 041190/0278 →
SECURITY INTEREST Recorded Dec 27, 2016
From: FRAM GROUP IP LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 041190/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2015
From: ZHENG, JING; MEGHARAJ, PRABHU; BOEHLER, JEFFREY T.
To: FRAM GROUP IP LLC
Reel/Frame 036018/0255 →
Continuity (4)
Continuation In Part 14157266 · Jan 16, 2014
Division 13446322 · Apr 13, 2012
Provisional Application 61490219 · May 26, 2011
Related Publication 20150311682A1 · Oct 29, 2015