Printable compositions useful in electronic applications and methods relating thereto
View Patent ↗A printable ink for electronic applications is disclosed. The ink contains at least one non-interactive solvent, a binder, optionally one or more particulate fillers that may be conductive, semi-conductive or non-conductive, optionally a co-solvent and optionally other additives.
1. A printable ink for use in the production of an electronic device, comprising:
a. one or more non-interacting solvents,
b. a binding resin, which is a polymer or copolymer of polyethylene, polypropylene, halogenated polyethylene, halogenated polypropylene, halogenated polyolefin and any combination thereof, with the proviso that at least 50 weight percent of the polymer is polyethylene, polypropylene, halogenated polyethylene or halogenated polypropylene or any combination thereof, and wherein the binding resin is soluble in the non-interacting solvent; and
c. a filler.
2. A printable ink in accordance with claim 1 , wherein the binding resin is a copolymer comprising an alpha olefin where the pendant alkyl group has more than one carbon atom.
3. A printable ink in accordance with claim 1 , wherein the binding resin comprises a haloalkane or a copolymer where at least one of the repeat units is a haloalkane.
4. A printable ink in accordance with claim 1 , wherein the filler comprises one or more of the following: carbon, graphite, graphene, silver, gold, platinum, and silver coated base metal.
5. A printable ink in accordance with claim 1 , wherein the filler comprises one or more of the following: aluminum nitride, boron nitride, titanium dioxide, barium titanate, talc, industrial diamond, alumina.
6. A printable ink in accordance with claim 1 , wherein the non-interacting solvent comprises one or more of the following: decalin, bicyclohexyl, decane, undecane, and dodecane.
7. A printable ink in accordance with claim 1 , where the binding resin is selected from one or more of the following: polyethylene, polypropylene, halogenated polyolefins, and copolymers and derivatives thereof.
8. A method of printing an electrode on a solvent sensitive substrate comprising the step of place a printable ink on the substrate, where the ink composition is in accordance with the ink of claim 1 .
9. A method in accordance with claim 8 , where the solvent sensitive substrate is a member of the group consisting of: a polymeric OLED substrate layer, an amorphous silica based solar cell substrate layer, a polycarbonate and combinations thereof.
10. A method in accordance with claim 8 , wherein the placing of the ink is done by screen printing, flexographic printing, gravure coating, stenciling, ink jetting or spraying.