IP Library Granted Patent US 9,658,350
Granted Patent B2
US 9,658,350 · App. 14/729,715 · Granted May 23, 2017

Rechargeable solid state neutron detector and visible radiation indicator

Inventors: Ashley C. Stowe (Knoxville, TN); Brenden Wiggins (Oak Ridge, TN); Arnold Burger (Nashville, TN)
Assignees: CONSOLIDATED NUCLEAR SECURITY, LLC; FISK UNIVERSITY
G01T3/00C30B11/12C30B29/46C30B33/02H01L21/67098
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Quick Facts
Patent No.
US 9,658,350
App. No.
14/729,715
Granted
May 23, 2017
Kind
B2
Abstract

A radiation detection device, including: a support structure; and a chalcopyrite crystal coupled to the support structure; wherein, when the chalcopyrite crystal is exposed to radiation, a visible spectrum of the chalcopyrite crystal changes from an initial color to a modified color. The visible spectrum of the chalcopyrite crystal is changed back from the modified color to the initial color by annealing the chalcopyrite crystal at an elevated temperature below a melting point of the chalcopyrite crystal over time. The chalcopyrite crystal is optionally a 6 LiInSe 2 crystal. The radiation is comprised of neutrons that decrease the 6 Li concentration of the chalcopyrite crystal via a 6 Li(n,α) reaction. The initial color is yellow and the modified color is one of orange and red. The annealing temperature is between about 450 degrees C. and about 650 degrees C. and the annealing time is between about 12 hrs and about 36 hrs.

Claims (33)

1. A passive radiation detection device, comprising:

a support structure; and

a chalcopyrite crystal coupled to the support structure;

wherein, when the chalcopyrite crystal coupled to the support structure is subsequently exposed to radiation, a visible spectrum of the chalcopyrite crystal coupled to the support structure changes from an initial color to a modified color.

2. The radiation detection device of claim 1 , wherein the visible spectrum of the chalcopyrite crystal is changed back from the modified color to the initial color by annealing the chalcopyrite crystal at an elevated temperature below the melting point of the chalcopyrite crystal over time.

3. The radiation detection device of claim 2 , wherein the annealing temperature is between about 450 degrees C. and about 650 degrees C. and the annealing time is between about 12 hrs and about 36 hrs.

4. The radiation detection device of claim 1 , wherein the chalcopyrite crystal comprises a 6 LiInSe 2 crystal.

5. The radiation detection device of claim 4 , wherein neutrons in the radiation decrease the 6 Li concentration of the chalcopyrite crystal via a 6 Li(n,α) reaction.

6. The radiation detection device of claim 4 , wherein the initial color is yellow and the modified color is one of orange and red.

7. A passive radiation detection method, comprising:

providing a support structure; and

coupling a chalcopyrite crystal to the support structure;

wherein, when the chalcopyrite crystal coupled to the support structure is subsequently exposed to radiation, a visible spectrum of the chalcopyrite crystal coupled to the support structure changes from an initial color to a modified color.

8. The radiation detection method of claim 7 , wherein the visible spectrum of the chalcopyrite crystal is configured to be changed back from the modified color to the initial color by annealing the chalcopyrite crystal at an elevated temperature below the melting point of the chalcopyrite crystal over time.

9. The radiation detection method of claim 8 , wherein the annealing temperature is between about 450 degrees C. and about 650 degrees C. and the annealing time is between about 12 hrs and about 36 hrs.

10. The radiation detection method of claim 7 , wherein the chalcopyrite crystal comprises a 6 LiInSe 2 crystal.

11. The radiation detection method of claim 10 wherein neutrons in the radiation decrease the 6 Li concentration of the chalcopyrite crystal via a 6 Li(n,α) reaction.

12. The radiation detection method of claim 10 , wherein the initial color is yellow and the modified color is one of orange and red.

13. A method for using a passive radiation detection device, comprising:

providing a support structure;

providing a chalcopyrite crystal coupled to the support structure;

subsequently exposing the chalcopyrite crystal coupled to the support structure to radiation such that a visible spectrum of the chalcopyrite crystal coupled to the support structure changes from an initial color to a modified color; and

changing the visible spectrum of the chalcopyrite crystal back from the modified color to the initial color by annealing the chalcopyrite crystal at an elevated temperature below a melting point of the chalcopyrite crystal over time.

14. The method of claim 13 , wherein the chalcopyrite crystal comprises a 6 LiInSe 2 crystal.

15. The method of claim 14 , wherein neutrons in the radiation decrease the 6 Li concentration of the chalcopyrite crystal via a 6 Li(n,α) reaction.

16. The method of claim 14 , wherein the initial color is yellow and the modified color is one of orange and red.

17. The method of claim 13 , wherein the annealing temperature is between about 450 degrees C. and about 650 degrees C. and the annealing time is between about 12 hrs and about 36 hrs.

18. A method for recharging a passive radiation detection device comprising a chalcopyrite crystal coupled to a support structure that has subsequently been exposed to radiation such that a visible spectrum of the chalcopyrite crystal coupled to the support structure has changed from an initial color to a modified color, the method comprising:

changing the visible spectrum of the chalcopyrite crystal back from the modified color to the initial color by annealing the chalcopyrite crystal at an elevated temperature below a melting point of the chalcopyrite crystal over time.

19. The method of claim 18 , wherein the chalcopyrite crystal comprises a 6 LiInSe 2 crystal.

20. The method of claim 19 , wherein neutrons in the radiation decrease the 6 Li concentration of the chalcopyrite crystal via a 6 Li(n,α) reaction.

21. The method of claim 19 , wherein the initial color is yellow and the modified color is one of orange and red.

22. The method of claim 18 , wherein the annealing temperature is between about 450 degrees C. and about 650 degrees C. and the annealing time is between about 12 hrs and about 36 hrs.

Assignments (2)
CONFIRMATORY LICENSE Recorded Mar 3, 2016
From: ALLIANT TECHYSTEMS, INC.
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 037878/0584 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2015
From: STOWE, ASHLEY C.; WIGGINS, BRENDEN; BURGER, ARNOLD
To: CONSOLIDATED NUCLEAR SECURITY, LLC; FISK UNIVERSITY
Reel/Frame 035779/0016 →
Continuity (2)
Continuation In Part 13658591 · Oct 23, 2012
Related Publication 20150285924A1 · Oct 8, 2015