IP Library Granted Patent US 10,795,032
Granted Patent B2
US 10,795,032 · App. 14/731,302 · Granted Oct 6, 2020

Lanthanide doped barium mixed halide scintillators

Inventors: Gregory A. Bizarri (Berkeley, CA); Edith D. Bourret-Courchesne (Berkeley, CA); Stephen E. Derenzo (Pinole, CA); Gautam Gundiah (Berkeley, CA); Stephen M. Hanrahan (Berkeley, CA)
Assignee: The Regents of the University of California
G01T1/2023C09K11/7733G21K4/00G21K2004/06
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Quick Facts
Patent No.
US 10,795,032
App. No.
14/731,302
Granted
Oct 6, 2020
Kind
B2
Abstract

The present invention provides for a composition comprising an inorganic scintillator comprising an optionally lanthanide-doped barium mixed halide, useful for detecting nuclear material.

Claims (18)

1. An inorganic scintillator having the formula: Ba 1-y X 1 x X 2 2-x :Ln 1 y (VIf); wherein X 1 is CI, Br, or I, X 2 is CI, Br, or I, X 1 and X 2 are not the same halogen element, Ln 1 is a lanthanide with a valence of 2+, x has a value having the range 0.1≤x<2, and y has a value having the range 0<y≤1 wherein the inorganic scintillator is a single crystal having at least one dimension of a length of at least 1 mm, or a length at least sufficient to stop or absorb gamma-radiation.

2. The inorganic scintillator of claim 1 , wherein y has a value having the range 0.001≤y≤1.

3. The inorganic scintillator of claim 2 , wherein y has a value having the range 0.01≤y≤1.

4. The inorganic scintillator of claim 3 , wherein y has a value having the range 0.1≤y≤1.

5. The inorganic scintillator of claim 2 , wherein y has a value having the range 0.001≤y≤0.5.

6. The inorganic scintillator of claim 5 , wherein y has a value having the range 0.01≤y≤0.5.

7. The inorganic scintillator of claim 6 , wherein y has a value having the range 0.1≤y≤0.5.

8. The inorganic scintillator of claim 1 , wherein the Ln 1 is Eu 2+ .

9. The inorganic scintillator of claim 1 , wherein the X 1 is Br, and X 2 is I or Cl.

10. The inorganic scintillator of claim 9 , wherein the X 1 is Br, and X 2 is Cl.

11. The inorganic scintillator of claim 9 , wherein the X 1 is Br, and X 2 is I.

12. The inorganic scintillator of claim 10 , wherein Ln 1 is Eu 2+ .

13. The inorganic scintillator of claim 12 , wherein x has a value having the range 0.3≤x≤1.7.

14. The inorganic scintillator of claim 13 , wherein x has a value having the range 0.5≤x≤1.5.

15. The inorganic scintillator of claim 14 , wherein x has a value having the range 0.7≤x≤1.3.

16. The inorganic scintillator of claim 15 , wherein x has a value having the range 0.9≤x≤1.1.

17. The inorganic scintillator of claim 16 , wherein x is 1.

18. A gamma ray detector comprising the inorganic scintillator of claim 1 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2020
From: BIZARRI, GREGORY A.; BOURRET-COURCHESNE, EDITH D.; DERENZO, STEPHEN E.; GUNDIAH, GAUTAM; HANRAHAN, STEPHEN M.
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 052321/0396 →
CONFIRMATORY LICENSE Recorded Jun 29, 2015
From: REGENTS OF THE UNIVERSITY OF CALIFORNIA, THE
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 036039/0889 →
Continuity (10)
Continuation 13272152 · Oct 12, 2011
Continuation In Part PCTUS2010034130 · May 7, 2010
Continuation In Part 14731302
Continuation In Part PCTUS2010029719 · Apr 1, 2010
Continuation In Part 12986103 · Jan 6, 2011
Provisional Application 61176454 · May 7, 2009
Provisional Application 61232371 · Aug 7, 2009
Provisional Application 61292796 · Jan 6, 2010
Provisional Application 61392438 · Oct 12, 2010
Related Publication 20150268359A1 · Sep 24, 2015