Rolled copper foil for producing two-dimensional hexagonal lattice compound and method of producing two-dimensional hexagonal lattice compound
View Patent ↗A rolled copper foil for producing a two-dimensional hexagonal lattice compound, including P: 0.01 to 0.21 wt %, Fe: 0.006 wt % or less, and the balance being Cu and inevitable impurities, and having the following relationship: 2.0<=(I/I 0 ) where I is a (111) diffraction intensity determined by an X ray diffraction of a rolled surface after heating at 1000° C. for 30 minutes and I 0 is a (111) diffraction intensity determined by an X ray diffraction of fine powder copper.
1. A rolled copper foil for producing a two-dimensional hexagonal lattice compound, including 0.01 to 0.21 wt % phosphorous (P) and 0.001 to 0.006 wt % iron (Fe), having a thickness of 5 to 50 μm, and having the following relationship: 2.0≦(I/I 0 ) where I is a (111) diffraction intensity determined by an X ray diffraction of a rolled surface after heating at 1000° C. for 30 minutes and I 0 is a (111) diffraction intensity determined by an X ray diffraction of fine powder copper.
2. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , wherein the average crystal grain size is 1000 μm or more after heating at 1000° C. for 30 minutes measured with a cutting method.
3. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , wherein when 0.003 mm 2 of a section area is observed, 1 to 60 inclusions each having a 0.1 μm or more of a circle conversion diameter are present.
4. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 2 , wherein when 0.015 mm 2 of a section area is observed, 1 to 60 inclusions each having a 0.1 μm or more of a circle conversion diameter are present.
5. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , wherein the two-dimensional hexagonal lattice compound is one of graphene and boron nitride.
6. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 2 , wherein the two-dimensional hexagonal lattice compound is one of graphene and boron nitride.
7. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 3 , wherein the two-dimensional hexagonal lattice compound is one of graphene and boron nitride.
8. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , further comprising 0.01 wt % or less in total of one or more of elements selected from the group consisting of Ni, Sn, Mg, Ti and Zr.
9. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 2 , further comprising 0.01 wt % or less in total of one or more of elements selected from the group consisting of Ni, Sn, Mg, Ti and Zr.
10. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 3 , further comprising 0.01 wt % or less in total of one or more of elements selected from the group consisting of Ni, Sn, Mg, Ti and Zr.
11. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 5 , further comprising 0.01 wt % or less in total of one or more of elements selected from the group consisting of Ni, Sn, Mg, Ti and Zr.
12. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , which is produced by hot rolling an ingot, annealing and cold rolling repeatedly one time or more, recrystallization annealing, and finally cold rolling, wherein reduction ratio η in the final cold rolling is defined as 1.0≦η<4.5.
13. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 2 , which is produced by hot rolling an ingot, annealing and cold rolling repeatedly one time or more, recrystallization annealing, and finally cold rolling, wherein reduction ratio η in the final cold rolling is defined as 1.0≦η<4.5.
14. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 3 , which is produced by hot rolling an ingot, annealing and cold rolling repeatedly one time or more, recrystallization annealing, and finally cold rolling, wherein reduction ratio η in the final cold rolling is defined as 1.0≦η<4.5.
15. A method of producing a two-dimensional hexagonal lattice compound using the rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , comprising the steps of:
providing a raw material gas of the two-dimensional hexagonal lattice compound while placing the heated rolled copper foil for producing a two-dimensional hexagonal lattice compound in a predetermined chamber to form the two-dimensional hexagonal lattice compound on a surface of the rolled copper foil for producing a two-dimensional hexagonal lattice compound; and
laminating a transfer sheet on the surface of the two-dimensional hexagonal lattice compound, and etching and removing the rolled copper foil for producing a two-dimensional hexagonal lattice compound while transferring the two-dimensional hexagonal lattice compound to the transfer sheet.
16. The rolled copper foil for producing a two-dimensional hexagonal lattice compound according to claim 1 , wherein the foil comprises 0.001 to 0.005 wt % Fe.