Nanoparticles with multiple attached polymer assemblies and use thereof in polymer composites
Methods of synthesizing a binary polymer functionalized nanoparticle are generally provided. In one embodiment, a first anchoring compound is attached to a nanoparticle, and a first plurality of first monomers are polymerized on the first anchoring compound to form a first polymeric chain covalently bonded to the nanoparticle via the first anchoring compound. In another embodiment, a first polymeric chain can be attached to the nanoparticle, where the first polymeric chain has been polymerized prior to attachment to the nanoparticle. Thereafter, a second anchoring compound is attached to the nanoparticle, and a second plurality of second monomers are polymerized on the second anchoring compound to form a second polymeric chain covalently bonded to the nanoparticle via the second anchoring compound. Nanoparticles are also generally provided having multiple polymeric assemblies.
1. A nanoparticle with multiple polymeric assemblies, comprising:
an inorganic nanoparticle defining a surface;
a first polymeric chain covalently bonded to the surface of the nanoparticle; and
a second polymeric chain covalently bonded to the surface of the nanoparticle, wherein the first polymeric chain is different than the second polymeric chain, wherein the first polymeric chain has a different polydispersity index than the second polymeric chain.
2. The nanoparticle as in claim 1 , wherein the first polymeric chain is covalently bonded to the nanoparticle via a first anchoring compound, and wherein the second polymeric chain is covalently bonded to the nanoparticle via a second anchoring compound.
3. The nanoparticle as in claim 1 , wherein the first polymeric chain has a molecular weight up to about 50,000.
4. The nanoparticle as in claim 1 , wherein the second polymeric chain has a molecular weight of about 50,000 or more.
5. The nanoparticle as in claim 1 , wherein the first polymeric chain comprises a single type of monomer.
6. The nanoparticle as in claim 1 , wherein the first polymeric chain comprises a mixture of different types of monomers.
7. The nanoparticle as in claim 1 , wherein the second polymeric chain comprises a single type of monomer.
8. The nanoparticle as in claim 1 , wherein the second polymeric chain comprises a mixture of different types of monomers.
9. The nanoparticle as in claim 1 , further comprising:
a third polymeric chain covalently bonded to the surface of the nanoparticle, wherein the third polymeric chain is different than the first polymeric chain and the second polymeric chain.
10. The nanoparticle as in claim 9 , further comprising:
a fourth polymeric chain covalently bonded to the surface of the nanoparticle, wherein the fourth polymeric chain is different than the first polymeric chain, the second polymeric chain, and the third polymeric chain.
11. The nanoparticle as in claim 1 , wherein the nanoparticle comprises a natural or synthetic nanoclay.
12. The nanoparticle as in claim 1 , wherein the nanoparticle comprises an inorganic metal oxide.
13. The nanoparticle as in claim 1 , wherein the inorganic nanoparticle comprises silica, alumina, titania, indium tin oxide, CdSe, or mixtures thereof.