IP Library Granted Patent US 10,006,133
Granted Patent B2
US 10,006,133 · App. 14/940,548 · Granted Jun 26, 2018

Systems and methods for improved metal recovery using ammonia leaching

Inventors: Joanna M Robertson (Thatcher, AZ); Thomas R Bolles (Tucson, AZ); Dennis D Gertenbach (Lakewood, CO)
Assignee: FREEPORT MINERALS CORPORATION
C25C1/12C22B3/14C22B3/44C22B15/0008C22B15/0078C22B15/0089C22B15/0093C22B23/0446C22B23/0461Y02P10/236
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Quick Facts
Patent No.
US 10,006,133
App. No.
14/940,548
Granted
Jun 26, 2018
Kind
B2
Abstract

Systems and methods for basic leaching are provided. In various embodiments, a method is provided comprising leaching a slurry comprising a copper bearing material and an ammonia leach medium, adding copper powder to the slurry, separating the slurry into a pregnant leach solution and solids, and performing a solvent extraction on the pregnant leach solution to produce a loaded aqueous stream.

Claims (19)

1. A method comprising:

leaching a slurry comprising a copper bearing material and an ammonia leach medium;

adding to the slurry copper powder comprising greater than ninety percent copper;

separating the slurry into a pregnant leach solution and solids; and

performing a solvent extraction on the pregnant leach solution to produce a loaded aqueous stream; wherein the leaching is performed in an anoxic environment.

2. The method of claim 1 , wherein the copper powder comprises at least one of dendritic copper powder and molten sprayed copper powder.

3. The method of claim 1 , further comprising:

producing a cobalt precipitate from a raffinate produced by solvent extraction; and

subjecting the cobalt precipitate to a metal recovery process.

4. The method of claim 3 , further comprising adding ammonium hydrosulfide to the raffinate produced by solvent extraction.

5. The process of claim 4 , subjecting the loaded aqueous stream to electrowinning.

6. The method of claim 1 , further comprising wet grinding the copper bearing material prior to the leaching.

7. The method of claim 1 , further comprising adding sulfur dioxide gas to the slurry.

8. The method of claim 7 , further comprising adding air to the slurry.

9. The method of claim 1 , subjecting the loaded aqueous stream to electrowinning to yield copper metal at a cathode.

10. The method of claim 1 , wherein the solvent extraction comprises subjecting the pregnant leach solution to a copper-specific extracting reagent.

11. The process of claim 1 , wherein the solvent extraction comprises scrubbing an organic phase with a weak acid.

12. The process of claim 11 , wherein the weak acid is carbonic acid.

13. The process of claim 12 , wherein the carbonic acid is added through dissolving carbon dioxide in water.

Assignments (3)
CHANGE OF NAME Recorded Nov 17, 2015
From: FREEPORT-MCMORAN CORPORATION
To: FREEPORT MINERALS CORPORATION
Reel/Frame 037124/0367 →
MERGER Recorded Nov 16, 2015
From: FREEPORT-MCMORAN CORPORATION
To: FREEPORT-MCMORAN CORPORATION
Reel/Frame 037045/0632 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 13, 2015
From: ROBERTSON, JOANNA M; BOLLES, THOMAS R; GERTENBACH, DENNIS D
To: FREEPORT-MCMORAN CORPORATION
Reel/Frame 037036/0782 →
Continuity (2)
Continuation 13804009 · Mar 14, 2013
Related Publication 20160068977A1 · Mar 10, 2016