Method for producing high-strength galvannealed steel sheets
A method for producing high-strength galvannealed steel sheets having excellent workability and fatigue resistance. The method comprises subjecting a steel sheet to an oxidation treatment, the oxidation treatment including heating the steel sheet in an upstream stage at a temperature in the range of 400° C. to 750° C. in an atmosphere having an O 2 concentration of not less than 1000 ppm by volume and a H 2 O concentration of not less than 1000 ppm by volume and a downstream stage at a temperature in the range of 600° C. to 850° C. in an atmosphere having an O 2 concentration of less than 1000 ppm by volume and a H 2 O concentration of not less than 1000 ppm by volume. The method further comprises subjecting the steel sheet to reducing annealing, hot-dip galvanizing treatment and alloying treatment.
1. A method for producing high-strength galvannealed steel sheets, the method comprising:
subjecting a steel sheet to an oxidation treatment, the steel sheet comprising C: not more than 0.3%, by mass %, Si: 0.1 to 2.5%, by mass %, Mn: 0.5 to 3.0%, by mass %, and Fe and incidental impurities, the oxidation treatment including heating the steel sheet in (i) an upstream stage at a temperature in the range of 400° C. to 750° C. in an atmosphere having an O 2 concentration of not less than 1000 ppm by volume and a H 2 O concentration of not less than 1000 ppm by volume and (ii) a downstream stage at a temperature in the range of 600° C. to 850° C. in an atmosphere having an O 2 concentration of less than 1000 ppm by volume and a H 2 O concentration of not less than 1000 ppm by volume;
then subjecting the steel sheet to reducing annealing, the reducing annealing including heating the steel sheet at a temperature in the range of 650° C. to 900° C. in an atmosphere containing 5% to 30% of H 2 , by vol %, 500 ppm to 5000 ppm of H 2 O, by volume, and a balance of N 2 and incidental impurities; and
thereafter subjecting the steel sheet to a hot-dip galvanizing treatment and to an alloying treatment, the alloying treatment including treating the steel sheet at a temperature T (° C.) satisfying the following relationship for 10 to 60 seconds:
−50 log([H 2 O])+650≤T≤−40 log([H 2 O])+680
where [H 2 O] represents the H 2 O concentration by volume ppm during the reducing annealing.
2. The method for producing high-strength galvannealed steel sheets according to claim 1 , wherein the oxidation treatment is performed in a furnace,
the air ratio in the upstream stage is in the range of 1.0 to less than 1.3 and the air ratio in the downstream stage is in the range of 0.7 to less than 0.9, and
the furnace is a direct-fired furnace or a non-oxidation furnace.
3. The method for producing high-strength galvannealed steel sheets according to claim 1 , wherein during the reducing annealing, the difference in H 2 O concentration between an upper portion of a furnace and a lower portion of the furnace is not more than 2000 ppm, by volume.
4. The method for producing high-strength galvannealed steel sheets according to claim 1 , wherein the hot-dip galvanizing treatment is performed in a hot galvanizing bath having a chemical composition including Al in a concentration in the range of 0.095 to 0.115, by mass %, and a balance of Zn and inevitable impurities.
5. The method for producing high-strength galvannealed steel sheets according to claim 2 , wherein during the reducing annealing, the difference in H 2 O concentration between an upper portion of the furnace and a lower portion of the furnace is not more than 2000 ppm, by volume.
6. The method for producing high-strength galvannealed steel sheets according to claim 2 , wherein the hot-dip galvanizing treatment is performed in a hot galvanizing bath having a chemical composition including Al in a concentration in the range of 0.095 to 0.115, by mass %, and a balance of Zn and inevitable impurities.
7. The method for producing high-strength galvannealed steel sheets according to claim 3 , wherein the hot-dip galvanizing treatment is performed in a hot galvanizing bath having a chemical composition including Al in a concentration in the range of 0.095 to 0.115, by mass %, and a balance of Zn and inevitable impurities.
8. The method for producing high-strength galvannealed steel sheets according to claim 5 , wherein the hot-dip galvanizing treatment is performed in a hot galvanizing bath having a chemical composition including Al in a concentration in the range of 0.095 to 0.115, by mass %, and a balance of Zn and inevitable impurities.
9. The method for producing high-strength galvannealed steel sheets according to claim 1 , wherein the steel sheet further comprises at least one selected from the group consisting of Al: 0.01 to 0.1%, by mass %, Mo: 0.05 to 1.0%, by mass %, Nb: 0.005 to 0.05%, by mass %, Ti: 0.005 to 0.05%, by mass %, Cu: 0.05 to 1.0%, by mass %, Ni: 0.05 to 1.0%, by mass %, Cr: 0.01 to 0.8%, by mass %, and B: 0.0005 to 0.005%, by mass %.