Heat conductive sheet and method for producing heat conductive sheet
A heat conductive sheet having excellent adhesion between an acrylic resin layer and a supporting sheet is provided. The heat conductive sheet includes a heat conductive resin layer including a heat conductive acrylic resin composition; and a supporting resin layer (supporting sheet) containing a polyvinyl acetal resin and a styrene-vinyl isoprene block copolymer. Crosslinking of the supporting sheet with acrylic monomers of the acrylic heat conductive resin layer enables improvements in adhesion between the heat conductive resin layer and the supporting sheet.
1. A heat conductive sheet comprising:
a heat conductive resin layer comprising a heat conductive acrylic resin composition; and
a supporting resin layer containing a polyvinyl acetal resin and a styrene-vinyl isoprene block copolymer, wherein:
the polyvinyl acetal resin and the styrene-vinyl isoprene block copolymer are blended at a mass ratio from 9:1 to 7:3, and
a degree of acetalization of the polyvinyl acetal resin is in a range of from 50 to 90 mol % wherein the heat conductive resin layer overlays with the supporting resin layer along a thickness direction of the heat conductive sheet, and at least a portion of an edge of the heat conductive resin layer is in contact with at least a portion of an edge of the supporting resin layer.
2. The heat conductive sheet according to claim 1 , wherein the polyvinyl acetal resin is polyvinyl acetal or polyvinyl butyral.
3. The heat conductive sheet according to claim 2 , wherein the polyvinyl acetal resin has a molecular weight from 5×10 4 to 20×10 4 .
4. The heat conductive sheet according to claim 2 , wherein the polyvinyl acetal resin has a glass transition temperature from 50 to 150° C.
5. The heat conductive sheet according to claim 2 , wherein the styrene-vinyl isoprene block copolymer has a glass transition temperature from −40 to +40° C.
6. The heat conductive sheet according to claim 1 , wherein the polyvinyl acetal resin has a molecular weight from 5×10 4 to 20×10 4 .
7. The heat conductive sheet according to claim 6 , wherein the polyvinyl acetal resin has a glass transition temperature from 50 to 150° C.
8. The heat conductive sheet according to claim 6 , wherein the styrene-vinyl isoprene block copolymer has a glass transition temperature from −40 to +40° C.
9. The heat conductive sheet according to claim 1 , wherein the polyvinyl acetal resin has a glass transition temperature from 50 to 150° C.
10. The heat conductive sheet according to claim 9 , wherein the styrene-vinyl isoprene block copolymer has a glass transition temperature from −40 to +40° C.
11. The heat conductive sheet according to claim 1 , wherein the styrene-vinyl isoprene block copolymer has a glass transition temperature from −40 to +40° C.
12. The heat conductive sheet according to claim 1 , wherein the styrene-vinyl isoprene block copolymer has a styrene content from 10% to 30%.
13. The heat conductive sheet according to claim 12 , wherein the polyvinyl acetal resin and the styrene-vinyl isoprene block copolymer are blended at a mass ratio from 8.5:1.5 to 8:2.
14. A method for manufacturing a heat conductive sheet comprising the steps of:
forming a supporting resin layer by mixing and sheet-forming a polyvinyl acetal resin and a styrene-vinyl isoprene block copolymer; and
forming a heat conductive resin layer by curing a heat conductive acrylic resin composition in a state of contact with the supporting resin layer, wherein:
the polyvinyl acetal resin and the styrene-vinyl isoprene block copolymer are blended at a mass ratio from 9:1 to 7:3, and
a degree of acetalization of the polyvinyl acetal resin is in a range of from 50 to 90 mol % wherein the heat conductive resin layer overlays with the supporting resin layer along a thickness direction of the heat conductive sheet, and at least a portion of an edge of the heat conductive resin layer is in contact with at least a portion of an edge of the supporting resin layer.