IP Library Granted Patent US 9,914,838
Granted Patent B2
US 9,914,838 · App. 15/157,453 · Granted Mar 13, 2018

Surface treatment solutions for gold and gold alloys

Inventors: Yoko Mizuno (Shibata, JP); Makoto Kondo (Niigata, JP); Koichi Yomogida (Niigata, JP); Toshiyuki Morinaga (Niigata, JP)
Assignee: Rohm and Haas Electronic Materials LLC
C09D5/08C07D233/02C07D333/04C08G73/0616C08K5/3462C09D7/1216C09D179/04C23C26/00C25D3/38C25D5/48C25D11/246H01L21/288H05K1/0346H05K3/00C07D233/00C08G59/00C08K3/32C08K5/00C08K2003/324C25D5/12H05K1/00
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Quick Facts
Patent No.
US 9,914,838
App. No.
15/157,453
Granted
Mar 13, 2018
Kind
B2
Abstract

A composition containing a cationic polymer obtained from a reaction product of nitrogen-containing heterocyclic compound and epihalohydrin; and a phosphorus compound. The composition can be used as a surface treatment for gold or gold alloy. The composition can seal pinholes on the surface of the gold or gold alloy.

Claims (10)

1. A surface treatment method for gold or gold alloy comprising: a) providing a copper or copper alloy-made electronic component, b) nickel plating the copper or copper alloy-made electronic component, c) gold or gold alloy plating the nickel, and d) contacting a surface of the gold or the gold alloy with an aqueous solution consisting of a cationic polymer, wherein the cationic polymer comprises a reaction product of a nitrogen-containing heterocyclic compound and epihalohydrin, a phosphorus compound, water, and optionally a pH adjuster and a wetting agent, to seal pinholes in the gold or gold alloy.

2. The surface treatment method of claim 1 , wherein the phosphorus compound is selected from the group consisting of phosphoric acids, polyphosphoric acids and salts thereof and phosphate esters.

3. The surface treatment method of claim 1 , wherein the cationic polymer is in amounts of 0.01 to 70 g/L, and the phosphorus compound is in amounts of 0.01 to 50 g/L.

4. The surface treatment method of claim 3 , wherein the cationic polymer is in amounts of 1 to 20 g/L.

5. The surface treatment method of claim 3 , wherein the phosphorus compound is in amounts of 10 to 30 g/L.

6. The surface treatment method of claim 1 , wherein a pH of the aqueous solution is from 6-12.

7. The surface treatment method of claim 6 , wherein the pH of the aqueous solution is from 8-12.

8. The surface treatment method of claim 1 , wherein the nitrogen-containing heterocyclic compound is chosen from imidazole or pyridine.

9. The surface treatment method of claim 1 , wherein the epihalohydrin is chosen from epihalohydrin or epibromohydrin.

10. The surface treatment method of claim 1 , wherein the surface treatment with the aqueous solution is done without performing electrolysis.

Assignments (5)
SECURITY INTEREST Recorded Nov 3, 2025
From: QNITY ELECTRONICS, INC.
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 073517/0298 →
SECURITY INTEREST Recorded Nov 3, 2025
From: QNITY ELECTRONICS, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 073515/0243 →
CHANGE OF NAME Recorded Oct 29, 2024
From: ROHM & HAAS ELECTRONIC MATERIALS LLC
To: DUPONT ELECTRONIC MATERIALS INTERNATIONAL, LLC
Reel/Frame 069272/0383 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2018
From: MIZUNO, YOKO; KONDO, MAKOTO; YOMOGIDA, KOICHI; MORINAGA, TOSHIYUKI
To: ROHM AND HAAS ELECTRONIC MATERIALS KK
Reel/Frame 044734/0537 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2018
From: ROHM AND HAAS ELECTRONIC MATERIALS K.K.
To: ROHM AND HAAS ELECTRONIC MATERIALS LLC
Reel/Frame 044734/0548 →
Priority Claims (1)
JP 2015-131719 · Jun 30, 2015 · national
Continuity (1)
Related Publication 20170002211A1 · Jan 5, 2017