Processes for preparing alumina and various other products
There are provided processes for preparing alumina. These processes can comprise leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate; reacting said leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 , and separating said precipitate from said liquid; and heating said precipitate under conditions effective for converting AlCl 3 into Al 2 O 3 and optionally recovering gaseous HCl so-produced. These processes can also be used for preparing various other products such as hematite, MgO, silica and oxides of various metals, sulphates and chlorides of various metals, as well as rare earth elements, rare metals and aluminum.
1. A process for preparing alumina, said process comprising:
leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate to obtain a solid-depleted leachate and a separated solid;
reacting said solid-depleted leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl 3 .6H 2 O, and separating said precipitate from said liquid to obtain a liquid-depleted precipitate;
heating said liquid-depleted precipitate under conditions effective for converting AlCl 3 .6H 2 O into Al 2 O 3 and producing HCl; and
leaching said separated solid with HCl at a concentration of less than 20% by weight, at a temperature of less than 85° C., in the presence of MgCl to solubilise TiO 2 and to obtain a silica-depleted leachate and a titanium-depleted solid, separating said silica-depleted leachate from said titanium-depleted solid and recovering SiO 2 and TiO 2 .
2. The process of process of claim 1 , wherein said process comprises converting AlCl 3 .6H 2 O into Al 2 O 3 by carrying out a calcination of AlCl 3 .6H 2 O, said calcination comprising steam injection.
3. The process of claim 1 , wherein said aluminum-containing material is chosen from aluminosilicate minerals.
4. The process of claim 1 , wherein said aluminum-containing material is selected from the group consisting of argillite, bauxite, kaolin, nepheline, aluminosilicate materials, red mud, slag, fly ashes, and industrial refractory materials.
5. The process of claim 1 , wherein said aluminum-containing material is selected from the group consisting of aluminosillicate minerals, clays, argillite, nepheline, mudstone, beryl, cryolite, garnet, spinel, bauxite, kaolin, slag, red mud and fly ashes.
6. The process of claim 1 , wherein said aluminum-containing material is leached with HCl having a concentration of about 10 to about 50 weight %.
7. The process of claim 1 , wherein said aluminum-containing material is leached with HCl having a concentration of about 25 to about 45 weight %.
8. The process of claim 1 , wherein said aluminum-containing material is leached at a temperature of about 125 to about 225° C.
9. The process of claim 6 , wherein said aluminum-containing material is leached at a temperature of about 125 to about 225° C.
10. The process of claim 1 , wherein said aluminum-containing material is leached at a temperature of about 150 to about 200° C.
11. The process of claim 1 , wherein said aluminum-containing material is leached at a pressure of about 4 to about 10 barg.
12. The process of claim 9 , wherein said aluminum-containing material is leached at a pressure of about 4 to about 10 barg.