Light-emitting element, light-emitting device, electronic device, lighting device, and lighting system
A light-emitting element that contains a fluorescent compound, which has high efficiency is provided. A light-emitting element in which the proportion of delayed fluorescence to the total light emitted from the light-emitting element is higher than that in a conventional light-emitting element is provided. Emission efficiency of the light-emitting element containing a fluorescent compound can be improved by increasing the probability of TTA caused by an organic compound in an EL layer, converting energy of triplet excitons, which does not contribute to light emission, into energy of singlet excitons, and making the fluorescent compound emit light by energy transfer of the singlet excitons.
1. A light-emitting element comprising:
an EL layer between an anode and a cathode,
wherein the EL layer includes a light-emitting layer,
wherein the light-emitting layer includes a first organic compound,
wherein a difference between a T 1 level of the first organic compound and one or more of T n levels of the first organic compound is less than the sum of the T 1 level and 0.6 eV,
wherein the first organic compound has a structure represented by General Formula (G1)
wherein α 1 represents a substituted or unsubstituted phenylene group,
wherein n represents 1 or 2,
wherein one of A 1 and A 2 is a first substituent represented by General Formula (G1-1)
wherein α 2 represents a substituted or unsubstituted phenylene group,
wherein m represents 1 or 2, and
wherein the other of A 1 and A 2 is hydrogen or a second substituent different from the first substituent.
2. The light-emitting element according to claim 1 , wherein an energy difference between the one or more of T n levels of the first organic compound and any one of an S 1 level and S n levels of the first organic compound is 1 eV or less.
3. The light-emitting element according to claim 1 , wherein an oscillator strength for excitation from the T 1 level of the first organic compound to the one or more of T n levels of the first organic compound is 0.0015 or more.
4. The light-emitting element according to claim 1 , wherein the first organic compound has Structural Formula (100) or Structural Formula (110).
5. The light-emitting element according to claim 1 ,
wherein light emission from the light-emitting element includes a delayed fluorescence component, and
wherein an emission intensity of the delayed fluorescence component is 5% or more to that of a total amount of the light emission.
6. The light-emitting element according to claim 5 ,
wherein the light-emitting layer further includes a second organic compound,
wherein an S 1 level of the first organic compound is higher an S 1 level of the second organic compound, and
wherein the light emission from the light-emitting element is derived from the second organic compound.
7. The light-emitting element according to claim 6 , wherein the second organic compound includes a pyrene skeleton.
8. The light-emitting element according to claim 6 , wherein a T 1 level of the second organic compound is higher than the T 1 level of the first organic compound.
9. The light-emitting element according to claim 6 ,
wherein the EL layer further includes a hole-transport layer including a third organic compound,
wherein the hole-transport layer is located between the anode and the light-emitting layer and in contact with the light-emitting layer, and
wherein a T 1 level of the third organic compound included in the hole-transport layer is higher than the T 1 level of the first organic compound.
10. The light-emitting element according to claim 9 ,
wherein the EL layer further includes an electron-transport layer including a fourth organic compound,
wherein the electron-transport layer is located between the cathode and the light-emitting layer and in contact with the light-emitting layer, and
wherein a T 1 level of the fourth organic compound included in the electron-transport layer is higher than the T 1 level of the first organic compound.
11. A light-emitting device comprising:
the light-emitting element according to claim 1 , and
one of a transistor and a substrate.
12. An electronic device comprising:
the light-emitting device according to claim 11 , and
any one of microphone, a camera, an operation button, an external connection portion, and a speaker.
13. An electronic device comprising:
the light-emitting device according to claim 11 , and
one of a housing and a touch sensor.
14. A lighting device comprising:
the light-emitting device according to claim 11 , and
any one of a housing, a cover, and a support.
15. A lighting system comprising:
a sensor;
a control unit electrically connected to the sensor; and
a light-emitting element electrically connected to the control unit,
wherein information acquired by the sensor is input to the control unit,
wherein the control unit is configured to drive the light-emitting element based on the information,
wherein the light-emitting element includes an EL layer between an anode and a cathode,
wherein the EL layer includes a light-emitting layer,
wherein the light-emitting layer includes a first organic compound,
wherein a difference between a T 1 level of the first organic compound and one or more of T n levels of the first organic compound is less than the sum of the T 1 level and 0.6 eV,
wherein the first organic compound has a structure represented by General Formula (G1)
wherein α 1 represents a substituted or unsubstituted phenylene group,
wherein n represents 1 or 2,
wherein one of A 1 and A 2 is a first substituent represented by General Formula (G1-1)
wherein α 2 represents a substituted or unsubstituted phenylene group,
wherein m represents 1 or 2, and
wherein the other of A 1 and A 2 is hydrogen or a second substituent different from the first substituent.
16. The lighting system according to claim 15 , wherein an energy difference between the one or more of T n levels of the first organic compound and any one of an S 1 level and S n levels of the first organic compound is 1 eV or less.
17. A lighting system comprising:
a sensor;
a control unit; and
a light-emitting element,
wherein the control unit includes a communication unit, a CPU, and a memory,
wherein the memory includes a program for driving the light-emitting element based on exterior information,
wherein the communication unit is configured to send the exterior information acquired by the sensor to the CPU,
wherein the CPU is configured to drive the light-emitting element by reading out the program from the memory and executing the program,
wherein the light-emitting element includes an EL layer between an anode and a cathode,
wherein the EL layer includes a light-emitting layer,
wherein the light-emitting layer includes a first organic compound,
wherein a difference between a T 1 level of the first organic compound and one or more of T n levels of the first organic compound is less than the sum of the T 1 level and 0.6 eV,
wherein the first organic compound has a structure represented by General Formula (G1)
wherein α 1 represents a substituted or unsubstituted phenylene group,
wherein n represents 1 or 2,
wherein one of A 1 and A 2 is a first substituent represented by General Formula (G1-1)
wherein α 2 represents a substituted or unsubstituted phenylene group,
wherein m represents 1 or 2, and
wherein the other of A 1 and A 2 is hydrogen or a second substituent different from the first substituent.
18. The lighting system according to claim 17 , wherein an energy difference between the one or more of T n levels of the first organic compound and any one of an S 1 level and S n levels of the first organic compound is 1 eV or less.
19. The light-emitting element according to claim 1 , wherein the second substituent includes at least one of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 1 to 6 carbon atoms, an alkylphenyl group, and a phenyl group.
20. The light-emitting element according to claim 1 , wherein, in General Formula (G1), A 1 is the first substituent represented by General Formula (G1-1) and A 2 is hydrogen or the second substituent.
21. The lighting system according to claim 15 , wherein the second substituent includes at least one of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 1 to 6 carbon atoms, an alkylphenyl group, and a phenyl group.
22. The lighting system according to claim 15 , wherein, in General Formula (G1), A 1 is the first substituent represented by General Formula (G1-1) and A 2 is hydrogen or the second substituent.
23. The lighting system according to claim 17 , wherein the second substituent includes at least one of an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 1 to 6 carbon atoms, an alkylphenyl group, and a phenyl group.
24. The lighting system according to claim 17 , wherein, in General Formula (G1), A 1 is the first substituent represented by General Formula (G1-1) and A 2 is hydrogen or the second substituent.