IP Library Granted Patent US 10,035,938
Granted Patent B2
US 10,035,938 · App. 15/238,883 · Granted Jul 31, 2018

Heat transfer fluid replacing R-134a

Inventor: Wissam Rached (Chaponost, FR)
Assignee: ARKEMA FRANCE
C09K5/045F25B45/00C09K2205/126C09K2205/22C09K2205/40F25B9/006F25B2400/18
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Quick Facts
Patent No.
US 10,035,938
App. No.
15/238,883
Granted
Jul 31, 2018
Kind
B2
Abstract

A heat transfer method using ternary composition containing 2,3,3,3-tetrafluoropropene, 1,1-difluoroethane and difluoromethane, as a heat transfer fluid in refrigeration systems, to replace R-134a. 1. A method of modifying a heat transfer system containing R-134a comprising removing R-134a and adding a composition comprising a refrigerant consisting essentially of: 70 to 88 wt % of 2,3,3,3-tetrafluoropropene; 4 to 16 wt % of difluoromethane; 8 to 14 wt % of 1,1-difluoroethane; and optionally, a stabilizer.

Claims (27)

1. A method of modifying a heat transfer system containing R-134a comprising removing R-134a and adding a composition comprising a refrigerant consisting essentially of:

70 to 88 wt % of 2,3,3,3-tetrafluoropropene;

4 to 16 wt % of difluoromethane;

8 to 14 wt % of 1,1-difluoroethane; and

optionally, a stabilizer.

2. The method as claimed in claim 1 , wherein the refrigerant consists essentially of 2,3,3,3-tetrafluoropropene, difluoromethan, 1,1-difluoroethane, and the stabilizer.

3. The method as claimed in claim 2 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

4. The method as claimed in claim 2 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.

5. The method as claimed in claim 1 , wherein the heat transfer system is of the compression type.

6. The method as claimed in claim 5 , wherein the heat transfer system operates with exchangers in countercurrent mode or in crossed-current mode with countercurrent tendency.

7. The method as claimed in claim 1 , wherein the composition further comprises a lubricant.

8. The method as claimed in claim 7 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

9. The method as claimed in claim 1 , wherein the refrigerant consists essentially of:

84 to 88 wt % of 2,3,3,3-tetrafluoropropene;

4 to 14 wt % of difluoromethane;

11 to 14 wt % of 1,1-difluoroethane; and

optionally, a stabilizer.

10. The method as claimed in claim 1 , wherein the refrigerant consists of:

84 to 88 wt % of 2,3,3,3-tetrafluoropropene;

4 to 14 wt % of difluoromethane;

11 to 14 wt % of 1,1-difluoroethane; and

optionally, a stabilizer.

11. The method as claimed in claim 1 , wherein the refrigerant consists of:

70 to 88 wt % of 2,3,3,3-tetrafluoropropene;

4 to 16 wt % of difluoromethane;

8 to 14 wt % of 1,1-difluoroethane; and

optionally, a stabilizer.

Assignments (2)
CHANGE OF ADDRESS Recorded Jul 4, 2025
From: ARKEMA FRANCE
To: ARKEMA FRANCE
Reel/Frame 071814/0739 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 17, 2016
From: RACHED, WISSAM
To: ARKEMA FRANCE
Reel/Frame 039463/0639 →
Priority Claims (1)
FR 09 56245 · Sep 11, 2009 · national
Continuity (3)
Continuation In Part 14615741 · Feb 6, 2015
Continuation 13391417
Related Publication 20160355718A1 · Dec 8, 2016
Cited By (4)
US 12,291,666 US 12,292,213 US 12,416,431 US 12,421,436